(R)-C3-TUNAPHOS

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Names

[ CAS No. ]:
301847-89-2

[ Name ]:
(R)-C3-TUNAPHOS

[Synonym ]:
(R)-C3-TunaPhos
MFCD06658115

Chemical & Physical Properties

[ Boiling Point ]:
709.9±60.0 ℃(Predicted)

[ Melting Point ]:
153-161ºC(lit.)

[ Molecular Formula ]:
C39H32O2P2

[ Molecular Weight ]:
594.61800

[ Exact Mass ]:
594.18800

[ PSA ]:
45.64000

[ LogP ]:
7.03130

MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Articles

Synthesis of chiral bisphosphines with tunable bite angles and their applications in asymmetric hydrogenation of beta-ketoesters.

J. Org. Chem. 65 , 6223, (2000)

Enantioselective hydrogenation of tetrasubstituted olefins of cyclic beta-(acylamino)acrylates.

J. Am. Chem. Soc. 125 , 9570, (2003)

Hydrogenation of a series of cyclic beta-(acylamino)acrylates with tetrasubstituted olefins has been accomplished successfully with the use of Ru catalysts with chiral biaryl ligands such as C3-TunaPh...

Highly enantioselective asymmetric hydrogenation of alpha-phthalimide ketone: an efficient entry to enantiomerically pure amino alcohols.

J. Am. Chem. Soc. 126 , 1626, (2004)

A new type of alpha-phthalimide ketones was hydrogenated in excellent enantioselectivity by using a Ru-(C3-TunePhos) complex as the catalyst. Up to 10 000 turnovers have been achieved in more than 99%...


More Articles


Related Compounds

  • [Chloro(R)-C3-TunePhos)(p-cymene)ruthenium(II)] chloride
  • (R)-1-(4-METHOXYPHENYL)ETHANOL
  • (R)-tert-butyl 6-hydroxy-1,4-oxazepane-4-carboxylate
  • [R-(R*,S*)]-(2-hydroxy-1-methyl-2-phenylethyl)dimethylammonium (1S)-2-oxobornane-10-sulphonate
  • (R-(R*,R*))-N-(2-Hydroxy-1-(hydroxymethyl)-2-(4-nitrophenyl)ethyl)-2-o xoacetamide
  • (R)-2-(3-bromophenyl)piperidine hydrochloride