Methylhydrazine sulfate

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Names

[ CAS No. ]:
302-15-8

[ Name ]:
Methylhydrazine sulfate

[Synonym ]:
EINECS 206-115-4
methylhydrazine sulfate salt
methyl-hydrazinsulfate
Methylaminoazanium hydrogen sulfate
Hydrazine, methyl-, sulfate (1:1)
Methylhydrazine Sulfate
METHYLHYDRAZINE SULPHATE
Methylhydrazine sulfate (1:1)
methylhydraziniumsulphate
MeNHNH2 sulfate
methylhydrazine hydrosulfate
MFCD00035423
Methyldiazanium hydrogen sulfate
methyl hydrazine sulfate
methyl-hydrazinsulfate(1:1)
methylhydrazine sulfuric acid
1-methylhydrazinium hydrosulfate
methylhydrazinesulfate(1:1)
MeNHNH2*H2SO4

Chemical & Physical Properties

[ Density]:
0.8g/cm3

[ Boiling Point ]:
87.5ºC at 760mmHg

[ Melting Point ]:
143°C

[ Molecular Formula ]:
CH8N2O4S

[ Molecular Weight ]:
144.150

[ Flash Point ]:
21.1ºC

[ Exact Mass ]:
144.020477

[ PSA ]:
121.03000

[ LogP ]:
0.59870

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
MV7750000
CHEMICAL NAME :
Hydrazine, methyl-, sulfate
CAS REGISTRY NUMBER :
302-15-8
LAST UPDATED :
199806
DATA ITEMS CITED :
5
MOLECULAR FORMULA :
C-H6-N2.H2-O4-S
MOLECULAR WEIGHT :
144.17
WISWESSER LINE NOTATION :
ZM1 &WSQQ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
160 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
2092 mg/kg/83W-C
TOXIC EFFECTS :
Tumorigenic - neoplastic by RTECS criteria Lungs, Thorax, or Respiration - tumors Blood - lymphoma, including Hodgkin's disease

MUTATION DATA

TYPE OF TEST :
DNA repair
TEST SYSTEM :
Rodent - mouse Liver
DOSE/DURATION :
100 umol/L
REFERENCE :
JJCREP Japanese Journal of Cancer Research. (Elsevier Science Pub. BV, POB 211, 1000 AE Amsterdam, Netherlands) V.76- 1985- Volume(issue)/page/year: 79,204,1988

Safety Information

[ Hazard Codes ]:
T+

[ Risk Phrases ]:
R23/24/25;R40

[ Safety Phrases ]:
S26-S36/37/39

[ RIDADR ]:
2811

[ RTECS ]:
MV7750000

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1

[ HS Code ]:
2928000090

Synthetic Route

Precursor & DownStream

Precursor

  • monomethylhydrazine
  • Dimethyl sulfate
  • benzaldehyde azine
  • benzene

DownStream

  • ETHYL 1,3,5-TRIMETHYL-1H-PYRAZOLE-4-CARBOXYLATE
  • 1,3-Dimethyl-1H-pyrazol-5-amine
  • 1-methyl-6-oxo-1,4,5,6-tetrahydropyridazine-3-carboxylic acid
  • Methyl 5-amino-1-methyl-1H-pyrazole-3-carboxylate
  • Hydrazinecarboxamide,1-methyl-
  • 1-(carbamoylamino)-1-methyl-urea
  • 4,5-Dichloro-2-methyl-2H-pyridazin-3-one
  • 1,3-Dimethyl-5-pyrazolone
  • tert-Butyl 2-methylcarbazate
  • 5-amino-4-cyano-1-methyl-1,2-pyrazole

Customs

[ HS Code ]: 2928000090

[ Summary ]:
2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%


Related Compounds

  • methylhydrazine sulfate
  • methylhydrazine,oxalic acid
  • METHYLHYDRAZINE NITRATE
  • methylhydrazine
  • methylhydrazine,nitric acid
  • hydrogen sulfate,3-methoxy-4-methoxycarbonylbenzenediazonium
  • [2-Amino-1-(1-benzothiophen-3-yl)ethyl]dimethylamine
  • CID 62698144
  • 2-(Benzo[b]thiophen-3-yl)-4-chloropyrimidine
  • 2-(Furan-2-yl)-4-methylpyrimidine-5-carboxylic acid
  • 4-Ethyl-2-(furan-2-yl)pyrimidine-5-carboxylic acid
  • Methyl [(cyclopropylcarbamoyl)amino](phenyl)acetate
  • 3-Fluoro-4-(hydrazinylmethyl)pyridine
  • 5-Amino-3-(3-fluoro-4-pyridyl)-1H-1,2,4-triazole
  • 5-(3-Fluoropyridin-4-yl)-1,3,4-oxadiazol-2-amine
  • [(3-Fluoropyridin-4-yl)methyl](methyl)amine
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