2-Bromothiazole

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Names

[ CAS No. ]:
3034-53-5

[ Name ]:
2-Bromothiazole

[Synonym ]:
2-Bromothiazole
2-bromo-thiazole
2-Bromo-1,3-thiazole
bromothiazole
MFCD00005316
2-Bromo thiazole
EINECS 221-229-4
2-Thiazolyl Bromide
2-bromothioazole
Thiazole, 2-bromo-
Thiazole,2-bromo

Chemical & Physical Properties

[ Density]:
1.9±0.1 g/cm3

[ Boiling Point ]:
171.0±9.0 °C at 760 mmHg

[ Melting Point ]:
171ºC

[ Molecular Formula ]:
C3H2BrNS

[ Molecular Weight ]:
164.02

[ Flash Point ]:
63.3±0.0 °C

[ Exact Mass ]:
162.909119

[ PSA ]:
41.13000

[ LogP ]:
1.93

[ Vapour Pressure ]:
1.9±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.605

[ Storage condition ]:
2-8°C

[ Water Solubility ]:
insoluble

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ Hazard Codes ]:
Xi: Irritant;F: Flammable;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S23-S24/25

[ RIDADR ]:
1993

[ WGK Germany ]:
3

[ HS Code ]:
29341000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2-Aminothiazole
  • Thiazole

DownStream

  • [4-(1,3-Thiazol-2-yl)phenyl]methanol
  • 1-(1,3-Thiazol-2-yl)piperazine
  • 2-PROPIONYLTHIAZOLE
  • 2-Methyl thiazole
  • 2-Bromo-1-thiazol-2-yl-ethanone
  • 2-ethylsulfanyl-1,3-thiazole
  • 2,5-Dibromothiazole
  • Ethyl 2-bromothiazole-5-carboxylate
  • 4-(1,3-Thiazol-2-yl)morpholine
  • Thiazole

Customs

[ HS Code ]: 2934100090

[ Summary ]:
2934100090 other compounds containing an unfused thiazole ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

Articles

Synthesis and characterization of fused pyrrolo[3,2-d:4,5-d']bisthiazole-containing polymers.

Org. Lett. 12(23) , 5478-81, (2010)

The synthesis of a novel electron-deficient fused pyrrolo[3,2-d:4,5-d']bisthiazole is reported from 2-bromothiazole. This was copolymerized with thiophene, selenophene, thienothiophene, and bithiophen...

Regioselective functionalization of the thiazole scaffold using TMPMgCl·LiCl and TMP2Zn·2MgCl2·2LiCl.

J. Org. Chem. 76(16) , 6972-8, (2011)

A general method for the synthesis of 2,4,5-trisubstituted thiazoles has been developed. Starting from commercially available 2-bromothiazole, successive metalations using TMPMgCl·LiCl or TMP(2)Zn·2Mg...

Tetrahedron Lett. 48 , 4831, (2007)


More Articles

Related Compounds

  • 2-bromothiazole
  • 4-Amino-2-bromothiazole
  • 5-Nitro-2-bromothiazole
  • 4-BENZYL-2-BROMOTHIAZOLE
  • 2-Bromothiazole-4-methanol
  • 2-Bromothiazole-5-methanol
  • Tert-butyl 2-{[(tert-butoxy)carbonyl](2-hydroxyethyl)amino}acetate
  • tert-butyl 4-(1-{[(tert-butoxy)carbonyl]amino}-2-oxoethyl)-1H-imidazole-1-carboxylate
  • 3',5,5'-Tri-tert-butyl-N-(4-(tert-butyl)phenyl)-[1,1'-biphenyl]-2-amine
  • 2-Azido-2-[3-(trifluoromethyl)phenyl]ethan-1-ol
  • 2-Chloro-1-(2-methylquinolin-6-yl)ethan-1-one
  • 2-Chloro-7-methyl-6,7-dihydro-5H-cyclopenta[b]pyridin-7-ol
  • 1-Fluoro-4-(trifluoromethyl)cyclohexane-1-carbaldehyde
  • benzyl ((S)-3-((1R,3R,5S)-3-(3-isopropyl-5-methyl-4H-1,2,4-triazol-4-yl)-8-azabicyclo[3.2.1]octan-8-yl)-1-phenylpropyl)carbamate
  • 5-Bromo-4-chloro-2-(1-piperidinyl)benzenamine
  • 5-Bromo-N-(4,5-dihydro-1H-imidazol-2-yl)-7-methyl-1H-indol-4-amine
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