Paraformaldehyde

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Names

[ CAS No. ]:
30525-89-4

[ Name ]:
Paraformaldehyde

[Synonym ]:
Paraformaldehyde
Polyoxymethylene
EINECS 200-001-8
MFCD00133991

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
82.5±8.0 °C at 760 mmHg

[ Melting Point ]:
120-170ºC

[ Molecular Formula ]:
C2H6O2

[ Molecular Weight ]:
62.068

[ Flash Point ]:
39.9±6.3 °C

[ Exact Mass ]:
62.036777

[ PSA ]:
17.07000

[ LogP ]:
-0.88

[ Vapour density ]:
1.03 (vs air)

[ Vapour Pressure ]:
51.0±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.364

[ Stability ]:
Stable. Incompatible with strong acids, organic acids, strong oxidizing agents, oxides, alkalies, strong bases, amines. Combustible. Dust may form an explosive mixture with air. Liberates poisonous gases on combustion.

[ Water Solubility ]:
chlorophenol above 70°C: soluble | sparingly soluble

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
RV0540000
CHEMICAL NAME :
Paraformaldehyde
CAS REGISTRY NUMBER :
30525-89-4
LAST UPDATED :
199806
DATA ITEMS CITED :
16
WISWESSER LINE NOTATION :
/*VH*/ X

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
BIOFX* BIOFAX Industrial Bio-Test Laboratories, Inc., Data Sheets. (1810 Frontage Rd., Northbrook, IL 60062)
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
BIOFX* BIOFAX Industrial Bio-Test Laboratories, Inc., Data Sheets. (1810 Frontage Rd., Northbrook, IL 60062) ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
800 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1070 mg/m3/4H
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - lacrimation Lungs, Thorax, or Respiration - dyspnea Gastrointestinal - changes in structure or function of salivary glands
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
10000 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Skin and Appendages - corrosive (after topical exposure) Nutritional and Gross Metabolic - body temperature decrease
REFERENCE :
BIOFX* BIOFAX Industrial Bio-Test Laboratories, Inc., Data Sheets. (1810 Frontage Rd., Northbrook, IL 60062) ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
9 gm/kg/90D-C
TOXIC EFFECTS :
Behavioral - fluid intake Nutritional and Gross Metabolic - weight loss or decreased weight gain
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
365 mL/kg/2Y-C
TOXIC EFFECTS :
Gastrointestinal - other changes Blood - changes in serum composition (e.g. TP, bilirubin, cholesterol) Nutritional and Gross Metabolic - weight loss or decreased weight gain
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Mammal - dog
DOSE/DURATION :
9 gm/kg/90D-C
TOXIC EFFECTS :
Behavioral - food intake (animal) Nutritional and Gross Metabolic - weight loss or decreased weight gain

MUTATION DATA

TYPE OF TEST :
Morphological transformation
TEST SYSTEM :
Rodent - rat Embryo
DOSE/DURATION :
2200 ng/plate
REFERENCE :
JJATDK JAT, Journal of Applied Toxicology. (John Wiley & Sons Ltd., Baffins Lane, Chichester, W. Sussex PO19 1UD, UK) V.1- 1981- Volume(issue)/page/year: 1,190,1981 *** REVIEWS *** TOXICOLOGY REVIEW 27ZTAP "Clinical Toxicology of Commercial Products--Acute Poisoning," 3rd ed., Gleason, M.N., et al., eds., Baltimore, Williams and Wilkins, 1969 Volume(issue)/page/year: 3,108,1969 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M1528 No. of Facilities: 236 (estimated) No. of Industries: 5 No. of Occupations: 19 No. of Employees: 1872 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M1528 No. of Facilities: 8271 (estimated) No. of Industries: 54 No. of Occupations: 65 No. of Employees: 146532 (estimated) No. of Female Employees: 20414 (estimated)

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS07, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H228-H302 + H332-H315-H317-H318-H335-H351

[ Precautionary Statements ]:
P210-P261-P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
Xn:Harmful

[ Risk Phrases ]:
R20/22;R36/37/38;R40;R43

[ Safety Phrases ]:
S24-S26-S36/37/39-S45

[ RIDADR ]:
UN 2213

[ WGK Germany ]:
3

[ RTECS ]:
RV0540000

[ Packaging Group ]:
III

[ Hazard Class ]:
4.1

[ HS Code ]:
2912600000

Customs

[ HS Code ]: 2912600000

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