3,3-Diethoxy-1-propene

Suppliers

Names

[ Name ]:
3,3-Diethoxy-1-propene

[Synonym ]:
MFCD00009239
3,3-diethoxyprop-1-ene
Acrolein diethylacetal
EINECS 221-276-0
1-PROPENE,3,3-DIETHOXY
(EtO)2CHCH=CH2
3,3-Diethoxy-1-propene
Acrolein diethyl acetal
1-Propene, 3,3-diethoxy-
Acrolein acetal
3,3-Diethoxypropene
1,1-Diethoxy-2-propene

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
123.5±0.0 °C at 760 mmHg

[ Melting Point ]:
120-125ºC

[ Molecular Formula ]:
C₇H₁₄O₂

[ Molecular Weight ]:
130.185

[ Flash Point ]:
4.4±0.0 °C

[ Exact Mass ]:
130.099380

[ PSA ]:
18.46000

[ LogP ]:
1.72

[ Vapour Pressure ]:
16.0±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.409

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: AS1370000

CHEMICAL NAME :: Acrolein, diethylacetal

CAS REGISTRY NUMBER :: 3054-95-3

BEILSTEIN REFERENCE NO. :: 1701567

LAST UPDATED :: 199612

DATA ITEMS CITED :: 1

MOLECULAR FORMULA :: C7-H14-O2

MOLECULAR WEIGHT :: 130.21

WISWESSER LINE NOTATION :: 2OYO2&1U1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :: Mutation in microorganisms

TEST SYSTEM :: Bacteria - Salmonella typhimurium

DOSE/DURATION :: 5 ug/plate

REFERENCE :: TCMUD8 Teratogenesis, Carcinogenesis, and Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.1- 1980- Volume(issue)/page/year: 1,259,1980

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H319

[ Precautionary Statements ]:
P210-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F:Flammable;Xi:Irritant;

[ Risk Phrases ]:
R11;R36

[ Safety Phrases ]:
S9-S16-S26-S33

[ RIDADR ]:
UN 2374 3/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
AS1370000

[ Packaging Group ]:
III

[ Hazard Class ]:
3

[ HS Code ]:
2911000000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Triethyl orthoformate
acrolein
3-Chloro-1,1-diethoxypropane
2-Bromopriopionaldehyde diethyl acetyl
1,1,3-TRIETHOXYPROPANE
Propionaldehyde diethyl acetal
Ethanol
(1R,2R)-1-bromo-2-ethoxycyclopropane
Sulfuric acid
leucoline

DownStream

methyl 2-(3-ethoxy-3-oxopropyl)benzoate
(2E)-3-(9-Anthryl)acrylaldehyde
3-(9-Anthryl)propionic Acid Ethyl Ester
Anthracene
ETHYL 3-(O-TOLYL)PROPANOATE
(E)-4-Nitrocinnamaldehyde
Ethyl 3-(4-bromophenyl)propanoate
1-Ethoxy-1-hexene
7,7-diethoxy-4-methylheptan-3-one
5,5-Diethoxy-2-pentanone

Customs

[ HS Code ]: 2911000000

[ Summary ]:
2911000000 acetals and hemiacetals, whether or not with other oxygen function, and their halogenated, sulphonated, nitrated or nitrosated derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Articles

Chronic carcinogenesis studies of acrolein and related compounds.

Toxicol. Ind. Health 3(3) , 337-45, (1987)

Acrolein and two of its more stable derivatives, the oxime and the diethylacetal, and the related allyl alcohol were given in drinking water to groups of 20 male and 20 female F344 rats at doses close...