Tetra-tert-butyl orthotitanate

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Names

[ CAS No. ]:
3087-39-6

[ Name ]:
Tetra-tert-butyl orthotitanate

[Synonym ]:
EINECS 221-412-9
tetra-sec-butoxotitanium
sec-butyl orthotitanate
Titanium(IV) tert-butoxide
titanium tetra-s-butoxide
titanium sec-butoxide
titanium tetra-tert-butoxide
Orthotitansaeure-tetra-tert-butylester
orthotitanic acid tetra-tert-butyl ester
MFCD00040554

Chemical & Physical Properties

[ Density]:
0.881 g/mL at 25 °C(lit.)

[ Boiling Point ]:
70ºC (2 mmHg) ,84.6ºC at 760 mmHg

[ Molecular Formula ]:
C16H36O4Ti

[ Molecular Weight ]:
340.32200

[ Flash Point ]:
11.7ºC

[ Exact Mass ]:
340.20900

[ PSA ]:
36.92000

[ LogP ]:
5.06320

[ Appearance of Characters ]:
Liquid | Clear colorless

[ Index of Refraction ]:
n20/D 1.438

[ Storage condition ]:
Store below +30°C.

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H319

[ Precautionary Statements ]:
P210-P305 + P351 + P338-P370 + P378

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R10

[ Safety Phrases ]:
16-26-36

[ RIDADR ]:
UN 1993 3

[ WGK Germany ]:
3

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Titanium tetrachloride
  • tert-Butanol
  • nitridomolybdenum(VI) tris(tert-butoxide)
  • Titanium(IV) dimethylamide
  • Ethanolate, titanium salt (4:1)

DownStream

  • Di-tert-butyl peroxide
  • Acetone
  • tert-Butanol

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Toward coordinated colloids: site-selective growth of titania on patchy silica particles.

Sci. Rep. 5 , 9339, (2015)

Rational synthesis of coordinated spherical colloids is reported by site-selective growth of secondary hemispherical patches on primary spherical particles with quasi-defined coordination numbers and ...


More Articles

Related Compounds

  • tetra-tert-butyl 2,2',2'',2'''-((((2-(tert-butoxy)-2-oxoethyl)azanediyl)bis(ethane-2,1-diyl))bis(azanetriyl))tetraacetate
  • tetra-tert-butyl 1,4-dimethyl-butane-1,1,4,4-tetrayl tetrakis-peroxide
  • tetraperoxosilicic acid tetra-tert-butyl ester
  • Thiosilicic acid (H4SiS4), tetra-tert-butyl ester
  • 3,3',5,5'-Tetra-tert-butyl-2,2'-biphenyldiol
  • 2,4,6,7-tetra-tert-butyl-3-phenyl-2,4,6,7-tetraaza-1,5-diphospha-3-borabicyclo{3.1.1}heptane
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide
  • N-[3-(Aminooxy)propyl]-N-butyl-1-butanamine