Tetrachloro-bis-(tetrahydrofuran)titanium(IV)

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Names

[ CAS No. ]:
31011-57-1

[ Name ]:
Tetrachloro-bis-(tetrahydrofuran)titanium(IV)

[Synonym ]:
MFCD00077884
titanium tetrachloride tetrahydrofuran complex

Chemical & Physical Properties

[ Boiling Point ]:
68.3ºC at 760mmHg

[ Melting Point ]:
126-128ºC(lit.)

[ Molecular Formula ]:
C8H16Cl4O2Ti

[ Molecular Weight ]:
333.89000

[ Flash Point ]:
1 °F

[ Exact Mass ]:
331.93800

[ PSA ]:
18.46000

[ LogP ]:
4.35160

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H228-H314

[ Supplemental HS ]:
Reacts violently with water.

[ Precautionary Statements ]:
P210-P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C: Corrosive;

[ Risk Phrases ]:
R14

[ Safety Phrases ]:
26-36/37/39-45

[ RIDADR ]:
UN 2925 4.1/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Titanium tetrachloride
  • thf
  • TiCl3(NMe2)
  • [Ti(3-Bu(t)-2-(O)C6H3CH=N(2,6-Pr(i)2C6H3))Cl(μ-Cl3)TiCl3]
  • [Ti(2,6-bis[1-(2,6-diisopropylphenylimino)ethyl]pyridine)Cl4]

DownStream

  • Titanium(4+) tetrakis(diethylazanide)

Related Compounds

  • diisopropoxy-bis(N,N-diethylamine-N-carbodithioato)titanium(IV)
  • Dihydroxybis-(ammonium lactato)titanium (IV)
  • ethylenebis(1-indenyl)titanium(iv) dichloride
  • Dimethylbis(t-butylcyclopentadienyl)titanium (IV)
  • acetylchlorobis(η-cyclopentadienyl)titanium(IV)
  • Pentamethylcyclopentadienyltitanium trichloride
  • 3-Fluoro-3-(fluoromethyl)pyrrolidine
  • 6-(1-Phenylethyl)pyrimidin-4-amine
  • 3-Fluoro-4-(propan-2-yl)pyrrolidine hydrochloride
  • 2-Fluoropent-4-en-1-amine hydrochloride
  • 2-(3-Fluoroazetidin-3-yl)acetonitrile hydrochloride
  • Ethyl 6-bromo-7-methoxy-3-quinolinecarboxylate
  • Ethyl 5-bromo-2-cyano-4-iodobenzoate
  • 4-Bromo-2-(2-methoxyethoxy)-6-methylpyridine
  • 3-Hydroxy-4-thiophen-3-ylpyrrole-2,5-dione
  • 3-(4-(3-(Benzyloxy)propoxy)butoxy)propan-1-ol
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