Methyl phenyl sulfone

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Names

[ CAS No. ]:
3112-85-4

[ Name ]:
Methyl phenyl sulfone

[Synonym ]:
Sulfone,methyl phenyl
methyl phenyl
Benzene, (methylsulfonyl)-
methylphenylsulphone
EINECS 221-476-8
MFCD00014741
phenyl methyl sulphone
MeSO2Ph
(Methylsulfonyl)benzene
1-(methylsulfonyl)benzene
Methyl phenyl sulfone
phenyl methyl sulfone
thioanisole sulfone

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
302.6±15.0 °C at 760 mmHg

[ Melting Point ]:
85-87 °C

[ Molecular Formula ]:
C7H8O2S

[ Molecular Weight ]:
156.202

[ Flash Point ]:
171.4±13.1 °C

[ Exact Mass ]:
156.024506

[ PSA ]:
42.52000

[ LogP ]:
0.50

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.525

[ Water Solubility ]:
insoluble

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
WR6800000
CHEMICAL NAME :
Sulfone, methyl phenyl
CAS REGISTRY NUMBER :
3112-85-4
BEILSTEIN REFERENCE NO. :
1906914
LAST UPDATED :
199710
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C7-H8-O2-S
MOLECULAR WEIGHT :
156.21
WISWESSER LINE NOTATION :
WS1&R

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1470 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PCBPBS Pesticide Biochemistry and Physiology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1971- Volume(issue)/page/year: 1,356,1971

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R22

[ Safety Phrases ]:
S22-S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
WR6800000

[ HS Code ]:
2904100000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Thioanisole
  • Sodium methanesulfinate
  • Phenylboronic acid
  • benzene
  • 4-Methylsulfonyl benzoic acid
  • 4,4,5,5-Tetramethyl-2-phenyl-1,3,2-dioxaborolane
  • 4-(methylsulfonyl)benzoic acid 2-pyridinylmethyl ester
  • Hydrogen peroxide
  • methyl phenyl sulfoxide

DownStream

  • 9-(benzenesulfonyl)nonan-1-ol
  • 4-Bromophenyl methyl sulfone
  • 1-Methyl-4-phenylpiperazine
  • Methyl bromide
  • Bromobenzene
  • 1,2-Dibromobenzene
  • (Phenylsulfonyl)acetic acid
  • Phenylsulfonylacetone
  • Phenylsulfinic acid
  • Thioanisole

Customs

[ HS Code ]: 2904100000

[ Summary ]:
2904100000 derivatives containing only sulpho groups, their salts and ethyl esters。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Articles

M. Julia, D. Deprez

Tetrahedron Lett. , 277, (1976)

P.A. Bartlett et al.

J. Am. Chem. Soc. 100 , 4852, (1978)

M. Julia et al.

J. Chem. Soc. Perkin Trans. I , 1646, (1978)


More Articles

Related Compounds

  • METHYL PHENYL SULFONE
  • 13C-methyl phenyl sulfone
  • benzyloxymethyl phenyl sulfone
  • phenylthiomethyl phenyl sulfone
  • methylthiomethyl phenyl sulfone
  • Difluoroiodomethyl phenyl sulfone
  • 3-(2,6-Dichlorophenyl)azetidine
  • 4-(Azetidin-3-yl)-2-bromophenol
  • 3-[3-Fluoro-5-(trifluoromethyl)phenyl]azetidine
  • 1-(4-Hydroxy-3-nitrophenyl)cyclopropane-1-carbonitrile
  • 3-(3-Chloro-2,6-difluorophenyl)azetidine
  • 5-(Azetidin-3-yl)-2-bromopyridine
  • 1-(5-Bromo-3-fluoro-2-hydroxyphenyl)cyclopropane-1-carbonitrile
  • Cyclopropanecarbonitrile, 1-(4-bromo-3-fluoro-2-hydroxyphenyl)-
  • 3-(Azetidin-3-yl)-2-bromo-6-methoxyphenol
  • 4-(1-Cyanocyclopropyl)-3-fluorobenzoic acid