METHYL 2,3-ANHYDRO-4,6-O-BENZYLIDENE-α-D-ALLOPYRANOSIDE

Suppliers

Names

[ Name ]:
METHYL 2,3-ANHYDRO-4,6-O-BENZYLIDENE-α-D-ALLOPYRANOSIDE

[Synonym ]:
MFCD00135407
Einecs 221-582-4
METHYL-2,3-ANHYDRO-4,6-O-BENZYLIDENE-A-D-ALLOPYRANOSIDE
methyl-2-3-anhydro-4-6-O-benzylidene*A-D-allopyra
METHYL-2-3-ANHYDRO-4-6-O-BENZYLIDENE*A-D-ALLOPYRANO
Methyl2,3-anhydro-4,6-O-benzylidene-a-D-allopyranose
(1aR,2S,3aR,7aR,7bR)-2-Methoxy-6-phenylhexahydrooxireno[2',3':4,5]pyrano[3,2-d][1,3]dioxine

Chemical & Physical Properties

[ Density]:
1.32g/cm3

[ Boiling Point ]:
391ºC at 760mmHg

[ Molecular Formula ]:
C₁₄H₁₆O₅

[ Molecular Weight ]:
264.27

[ Flash Point ]:
165.4ºC

[ Exact Mass ]:
264.10000

[ PSA ]:
49.45000

[ LogP ]:
1.23930

[ Index of Refraction ]:
1.577

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ RIDADR ]:
NONH for all modes of transport

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Methyl 4,6-O-benzylidene-2-O-[(4-methylphenyl)sulfonyl]-α-D-gluco pyranoside
Methyl 4,6-O-benzylidene-α-D-glucopyranoside
methyl-4,6-O-benzylidene-α-D-mannopyranoside
methyl 4,6-O-benzylidene-2,3-di-O-methanesulfonyl-α-D-glucopyranoside
alpha-D-Methylglucoside
methyl-[O2-benzoyl-O4,O6-((R)-benzylidene)-O3-methanesulfonyl-α-D-altropyranoside]
(2R,4aR,6S,7R,8S,8aR)-8-hydroxy-6-methoxy-2-phenyl-7-phenylcarbonyloxyperhydropyrano[3,2-d][1,3]dioxine
Benzaldehyde dimethyl acetal
(2R,4aR,6S,8aS)-(+)-6-methoxy-2-phenyl-4,4a,6,8a-tetrahydropyrano[3,2-d][1,3]dioxine

DownStream

a-D-Glucopyranoside, methyl,2,3,4,6-tetraacetate
a-D-Glucopyranoside, methyl3-(acetylamino)-3-deoxy-4,6-O-(phenylmethylene)-, 2-acetate
Methyl-[O3-aethyl-O4,O6-benzyliden-α-D-glucopyranosid]
Methyl 4,6-O-benzylidene-α-D-glucopyranoside
Eldecalcitol

Articles

An alternative synthesis of methyl 2,3-anhydro-4,6-O-benzylidene-α-D-allopyranoside using carbonate esters Raaijmakers, H., et al.

Carbohydr. Res. 238 , 185-92, (1993)

Neighboring-group participation in benzylidene acetal ring-opening of a 2-cyano-2-deoxypyranoside derivative by diethylaluminum cyanide.

Carbohydr. Res. 338 , 2177-83, (2003)

The oxirane ring-opening of an anhydro sugar with diethylaluminum cyanide (Et(2)AlCN) is a direct approach for obtaining a cyano derivative. Methyl 2,3-anhydro-4,6-O-benzylidene-alpha-D-allopyranoside...

Reaction of methyl 2,3-anhydro-4,6-O-benzylidene-α-D-allopyranoside with ethanolamine and 1,4,7,10-tetraoxa-13-azacyclopentadecane Tóth, G., et al.

Carbohydr. Res. 168 , 141-5, (1987)

N'-(4-tert-butyl-benzyl)-N-(4-chloro-phenyl)-N-methyl-ethane-1,2-diamine
(1R*,4S*,6R*)-2-(tert-Butoxycarbonyl)-2-azabicyclo[2.2.2]octane-6-carboxylic Acid
2-(aminomethyl)-N-(1-phenylethyl)butanamide
Methyl 3-phenylpiperidine-3-carboxylate
(((2-(Trifluoromethyl)phenyl)carbonyl)amino)methyl acetate
4-Bromomethyl-2-(4-methoxy-phenyl)-thiazole-5-carboxylic acid ethyl ester
Ethyl 4-(1,1-difluoro-2-hydroxyethyl)benzoate
4-Chloro-6-(methyloxy)-1,5-naphthyridine-3-carbonitrile
(2S)-1-(tert-butoxycarbonyl)-2-morpholinocarbonylpyrrolidine
Tert-butyl 4-(4-cyclopropylmethyl-piperazin-1-yl)-piperidine-1-carboxylate

The content on this webpage is sourced from various professional data sources. If you have any questions or concerns regarding the content, please feel free to contact service1@chemsrc.com.