METHYL 2,3-ANHYDRO-4,6-O-BENZYLIDENE-α-D-ALLOPYRANOSIDE

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Names

[ Name ]:
METHYL 2,3-ANHYDRO-4,6-O-BENZYLIDENE-α-D-ALLOPYRANOSIDE

[Synonym ]:
MFCD00135407
Einecs 221-582-4
METHYL-2,3-ANHYDRO-4,6-O-BENZYLIDENE-A-D-ALLOPYRANOSIDE
methyl-2-3-anhydro-4-6-O-benzylidene*A-D-allopyra
METHYL-2-3-ANHYDRO-4-6-O-BENZYLIDENE*A-D-ALLOPYRANO
Methyl2,3-anhydro-4,6-O-benzylidene-a-D-allopyranose
(1aR,2S,3aR,7aR,7bR)-2-Methoxy-6-phenylhexahydrooxireno[2',3':4,5]pyrano[3,2-d][1,3]dioxine

Chemical & Physical Properties

[ Density]:
1.32g/cm3

[ Boiling Point ]:
391ºC at 760mmHg

[ Molecular Formula ]:
C₁₄H₁₆O₅

[ Molecular Weight ]:
264.27

[ Flash Point ]:
165.4ºC

[ Exact Mass ]:
264.10000

[ PSA ]:
49.45000

[ LogP ]:
1.23930

[ Index of Refraction ]:
1.577

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ RIDADR ]:
NONH for all modes of transport

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Methyl 4,6-O-benzylidene-2-O-[(4-methylphenyl)sulfonyl]-α-D-gluco pyranoside
Methyl 4,6-O-benzylidene-α-D-glucopyranoside
methyl-4,6-O-benzylidene-α-D-mannopyranoside
methyl 4,6-O-benzylidene-2,3-di-O-methanesulfonyl-α-D-glucopyranoside
alpha-D-Methylglucoside
methyl-[O2-benzoyl-O4,O6-((R)-benzylidene)-O3-methanesulfonyl-α-D-altropyranoside]
(2R,4aR,6S,7R,8S,8aR)-8-hydroxy-6-methoxy-2-phenyl-7-phenylcarbonyloxyperhydropyrano[3,2-d][1,3]dioxine
Benzaldehyde dimethyl acetal
(2R,4aR,6S,8aS)-(+)-6-methoxy-2-phenyl-4,4a,6,8a-tetrahydropyrano[3,2-d][1,3]dioxine

DownStream

a-D-Glucopyranoside, methyl,2,3,4,6-tetraacetate
a-D-Glucopyranoside, methyl3-(acetylamino)-3-deoxy-4,6-O-(phenylmethylene)-, 2-acetate
Methyl-[O3-aethyl-O4,O6-benzyliden-α-D-glucopyranosid]
Methyl 4,6-O-benzylidene-α-D-glucopyranoside
Eldecalcitol

Articles

An alternative synthesis of methyl 2,3-anhydro-4,6-O-benzylidene-α-D-allopyranoside using carbonate esters Raaijmakers, H., et al.

Carbohydr. Res. 238 , 185-92, (1993)

Neighboring-group participation in benzylidene acetal ring-opening of a 2-cyano-2-deoxypyranoside derivative by diethylaluminum cyanide.

Carbohydr. Res. 338 , 2177-83, (2003)

The oxirane ring-opening of an anhydro sugar with diethylaluminum cyanide (Et(2)AlCN) is a direct approach for obtaining a cyano derivative. Methyl 2,3-anhydro-4,6-O-benzylidene-alpha-D-allopyranoside...

Reaction of methyl 2,3-anhydro-4,6-O-benzylidene-α-D-allopyranoside with ethanolamine and 1,4,7,10-tetraoxa-13-azacyclopentadecane Tóth, G., et al.

Carbohydr. Res. 168 , 141-5, (1987)

2-{[1-methyl-3-(oxan-4-yl)-1H-pyrazol-4-yl]oxy}acetic acid
3-(3-cyclopropylphenyl)-1-methyl-1H-pyrazol-5-amine
1-[2-(1H-pyrazol-1-yl)ethyl]cyclopropane-1-carbaldehyde
3-Amino-3-[4-(propan-2-yl)cyclohexyl]cyclobutan-1-ol
5-(2,3-dihydro-1H-inden-1-yl)-1-methyl-1H-pyrazol-4-amine
2-Amino-2-[1-(4-cyclopropyl-1,3-thiazol-5-yl)cyclopropyl]acetic acid
3-(2-isocyanatopropan-2-yl)-1,5-dimethyl-1H-pyrazole
2-(1-{Pyrazolo[1,5-a]pyrimidin-2-yl}cyclobutyl)ethan-1-amine
2-(1-methyl-1H-indol-7-yl)propanenitrile
5-(heptan-4-yl)-1-methyl-1H-pyrazol-4-amine

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