4-Iodo-1,2-dimethylbenzene

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Names

[ Name ]:
4-Iodo-1,2-dimethylbenzene

[Synonym ]:
3,4-dimethylphenyl iodide
3,4-Dimethyliodobenzene
4-Iodo-o-xylene
Benzene, 4-iodo-1,2-dimethyl-
1-iodo-3,4-dimethylbenzene
iodo-3,4-dimethylbenzene
3,4-dimethyl-1-iodobenzene
MFCD00040989
4-Iodo-1,2-dimethylbenzene
1,2-Dimethyl-4-iodobenzene
4-iodo-ortho-xylene
Benzene,4-iodo-1,2-dimethyl

Chemical & Physical Properties

[ Density]:
1.6±0.1 g/cm3

[ Boiling Point ]:
232.1±9.0 °C at 760 mmHg

[ Molecular Formula ]:
C₈H₉I

[ Molecular Weight ]:
232.061

[ Flash Point ]:
100.5±7.7 °C

[ Exact Mass ]:
231.974884

[ LogP ]:
4.17

[ Vapour Pressure ]:
0.1±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.593

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2903999090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

3,3',4,4'-TETRAMETHYLBIPHENYL
1,1'-Biphenyl,3,3',4,4'-tetramethoxy-
3,4-dimethoxy-3',4'-dimethylbiphenyl
1-(3,4-dimethylphenyl)-2,3-dimethylbenzene
4',5'-dimethoxy-3,3'',4,4''-tetramethyl-1,1':2',1''-terphenyl
4',4'',5',5''-tetramethoxy-3,3'',4,4''-tetramethyl-1,1':1'',2'',1'''-quaterphenyl
3,4-Dimethylbenzaldehyde
1,2-Dimethyl-4-(phenylsulfanyl)benzene
1,2-dimethyl-4-(4-methylphenyl)sulfonylbenzene
1,2-Dimethyl-4-(trifluoromethyl)benzene

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Auxiliary-assisted palladium-catalyzed arylation and alkylation of sp2 and sp3 carbon-hydrogen bonds.

J. Am. Chem. Soc. 132(11) , 3965-72, (2010)

We have developed a method for auxiliary-directed, palladium-catalyzed beta-arylation and alkylation of sp(3) and sp(2) C-H bonds in carboxylic acid derivatives. The method employs a carboxylic acid 2...

Two-step route to indoles and analogues from haloarenes: a variation on the Fischer indole synthesis.

J. Org. Chem. 77(3) , 1217-32, (2012)

In a new variation on the Fischer indole synthesis, readily available haloarenes are converted into a wide range of indoles in just two steps by halogen-magnesium exchange and quenching with di-tert-b...

Efficient and direct iodination of alkyl benzenes using polymer/HIO₄ and I₂ under mild condition. Pourali AR, et al.

Bull. Chem. Soc. Ethiop. 28(2) , 305-308, (2014)