Methyl 4,6-O-benzylidene-α-D-glucopyranoside

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Names

[ CAS No. ]:
3162-96-7

[ Name ]:
Methyl 4,6-O-benzylidene-α-D-glucopyranoside

[Synonym ]:
(4aR,6S,7R,8R,8aS)-6-Methoxy-2-phenylhexahydropyrano[3,2-d][1,3]dioxine-7,8-diol
Methyl 4,6-O-benzylidene-D-glucopyranoside
MFCD00006819
Methyl 4,6-O-benzylidene-α-D-glucopyranoside
α-D-Glucopyranoside, methyl 4,6-O-(phenylmethylene)-
METHYL 4,6-O-BENZILIDINE-D-GLUCOPYRANOSIDE
Methyl 4,6-O-Benzylidene-Alpha-D-Glucopyranoside
EINECS 221-615-2
2,3-Dibenzyl-4,6-Ethylidine Glucopyranose
METHYL 4,6-O-BENZYLIDENE-A-D-GLUCOPYRANOSIDE
(+)-(4,6-O-Benzylidene)methyl-a-D-glucopyranoside
4,6-BENZYLIDENE-A-METHYL-D-GLUCOSIDE
Methyl-4,6-O-benzylidene-α-D-glucopyranoside

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
473.0±45.0 °C at 760 mmHg

[ Melting Point ]:
164-167 °C

[ Molecular Formula ]:
C14H18O6

[ Molecular Weight ]:
282.289

[ Flash Point ]:
239.8±28.7 °C

[ Exact Mass ]:
282.110352

[ PSA ]:
77.38000

[ LogP ]:
0.89

[ Vapour Pressure ]:
0.0±1.2 mmHg at 25°C

[ Index of Refraction ]:
1.586

[ Storage condition ]:
2-8°C

MSDS

Safety Information

[ Hazard Codes ]:
C

[ Risk Phrases ]:
R20/21/22

[ Safety Phrases ]:
S22-S24/25

[ WGK Germany ]:
3

[ HS Code ]:
2932999099

Synthetic Route

Precursor & DownStream

Precursor

  • Benzaldehyde dimethyl acetal
  • alpha-D-Methylglucoside
  • Benzaldehyde
  • Triethylsilane
  • methyl (2S,4R)-2,3:4,6-di-O-benzylidene-α-D-glucopyranoside
  • (2R,4aR,6S,7R,8S,8aR)-7,8-bis(allyloxy)-6-methoxy-2-phenylhexahydropyrano[3,2-d][1,3]dioxine
  • methyl 2,3-di-O-benzyl-4,6-O-(R)-benzylidene-α-D-glucopyranoside
  • Benzene,(diethoxymethyl)-
  • alpha-D-Glucopyranoside, methyl 2,3,4,6-tetrakis-O-(trimethylsilyl)-
  • Methanol

DownStream

  • Methyl2,3-di-O-methyl-6-O-(phenylmethyl)-a-D-glucopyranoside
  • alpha-D-Methylglucoside
  • 1,3-Dioxolane,2,4-diphenyl-
  • a-D-Glucopyranoside, methyl,2,3,4,6-tetraacetate
  • methyl 4,6-O-benzylidene-2,3-di-O-diphenylmethyl-α-D-glucopyranoside
  • Benzophenone, azine
  • Methyl 2-O-Benzoyl-4,6-di-O-benzylidene-a-D-glucopyranoside
  • METHYL-3-O-BENZOYL-4,6-O-BENZYLIDENE-ALPHA-D-GLUCOPYRANOSIDE
  • Methyl-4,6-di-O-benzylidene-2,3-di-O-benzoyl-α-D-mannopyranoside

Customs

[ HS Code ]: 2932999099

[ Summary ]:
2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%


Related Compounds

  • methyl-4,6-O-benzylidene-α-D-mannopyranoside
  • Methyl 4,6-O-benzylidene-alpha-D-galactopyranoside
  • methyl-4,6-O-benzylidene-α-D-mannopyranoside
  • methyl 4,6-O-benzylidene-2,3-di-O-diphenylmethyl-α-D-glucopyranoside
  • methyl 4,6-O-benzylidene-2,3-di-O-methyl-α,D-glucopyranoside
  • methyl 4,6-O-benzylidene-2,3-di-O-methanesulfonyl-α-D-glucopyranoside
  • 1-(5-(Methylamino)pyridin-3-yl)pyrrolidine-3,4-diol
  • 4-Chloro-6-fluoroquinoline-3-sulfonyl chloride
  • 5-((Trifluoromethyl)thio)pyridin-3-amine
  • 3-(6-Methylpiperidin-2-yl)phenol
  • 5-((4-Phenylpiperidin-1-yl)methyl)thiazol-2-amine hydrochloride
  • N-(Cyanomethyl)-Na(2)-methylsulfamide
  • 3-(5-Bromopyridin-3-yl)prop-2-en-1-amine
  • 3-(5-Bromo-3-pyridyl)-5-methylisoxazole-4-carboxylic Acid
  • 3-(5-Bromopyridin-3-yl)-5-ethyl-1,2-oxazole-4-carboxylic acid
  • 4-(5-Bromopyridin-3-yl)-1,3-oxazolidin-2-one
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