Methyl 4,6-O-benzylidene-α-D-glucopyranoside

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Names

[ CAS No. ]:
3162-96-7

[ Name ]:
Methyl 4,6-O-benzylidene-α-D-glucopyranoside

[Synonym ]:
(4aR,6S,7R,8R,8aS)-6-Methoxy-2-phenylhexahydropyrano[3,2-d][1,3]dioxine-7,8-diol
Methyl 4,6-O-benzylidene-D-glucopyranoside
MFCD00006819
Methyl 4,6-O-benzylidene-α-D-glucopyranoside
α-D-Glucopyranoside, methyl 4,6-O-(phenylmethylene)-
METHYL 4,6-O-BENZILIDINE-D-GLUCOPYRANOSIDE
Methyl 4,6-O-Benzylidene-Alpha-D-Glucopyranoside
EINECS 221-615-2
2,3-Dibenzyl-4,6-Ethylidine Glucopyranose
METHYL 4,6-O-BENZYLIDENE-A-D-GLUCOPYRANOSIDE
(+)-(4,6-O-Benzylidene)methyl-a-D-glucopyranoside
4,6-BENZYLIDENE-A-METHYL-D-GLUCOSIDE
Methyl-4,6-O-benzylidene-α-D-glucopyranoside

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
473.0±45.0 °C at 760 mmHg

[ Melting Point ]:
164-167 °C

[ Molecular Formula ]:
C14H18O6

[ Molecular Weight ]:
282.289

[ Flash Point ]:
239.8±28.7 °C

[ Exact Mass ]:
282.110352

[ PSA ]:
77.38000

[ LogP ]:
0.89

[ Vapour Pressure ]:
0.0±1.2 mmHg at 25°C

[ Index of Refraction ]:
1.586

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Hazard Codes ]:
C

[ Risk Phrases ]:
R20/21/22

[ Safety Phrases ]:
S22-S24/25

[ WGK Germany ]:
3

[ HS Code ]:
2932999099

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Benzaldehyde dimethyl acetal
  • alpha-D-Methylglucoside
  • Benzaldehyde
  • Triethylsilane
  • methyl (2S,4R)-2,3:4,6-di-O-benzylidene-α-D-glucopyranoside
  • (2R,4aR,6S,7R,8S,8aR)-7,8-bis(allyloxy)-6-methoxy-2-phenylhexahydropyrano[3,2-d][1,3]dioxine
  • methyl 2,3-di-O-benzyl-4,6-O-(R)-benzylidene-α-D-glucopyranoside
  • Benzene,(diethoxymethyl)-
  • alpha-D-Glucopyranoside, methyl 2,3,4,6-tetrakis-O-(trimethylsilyl)-
  • Methanol

DownStream

  • Methyl2,3-di-O-methyl-6-O-(phenylmethyl)-a-D-glucopyranoside
  • alpha-D-Methylglucoside
  • 1,3-Dioxolane,2,4-diphenyl-
  • a-D-Glucopyranoside, methyl,2,3,4,6-tetraacetate
  • methyl 4,6-O-benzylidene-2,3-di-O-diphenylmethyl-α-D-glucopyranoside
  • Benzophenone, azine
  • Methyl 2-O-Benzoyl-4,6-di-O-benzylidene-a-D-glucopyranoside
  • METHYL-3-O-BENZOYL-4,6-O-BENZYLIDENE-ALPHA-D-GLUCOPYRANOSIDE
  • Methyl-4,6-di-O-benzylidene-2,3-di-O-benzoyl-α-D-mannopyranoside

Customs

[ HS Code ]: 2932999099

[ Summary ]:
2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Related Compounds

  • methyl-4,6-O-benzylidene-α-D-mannopyranoside
  • Methyl 4,6-O-benzylidene-alpha-D-galactopyranoside
  • methyl-4,6-O-benzylidene-α-D-mannopyranoside
  • methyl 4,6-O-benzylidene-2,3-di-O-diphenylmethyl-α-D-glucopyranoside
  • methyl 4,6-O-benzylidene-2,3-di-O-methyl-α,D-glucopyranoside
  • methyl 4,6-O-benzylidene-2,3-di-O-methanesulfonyl-α-D-glucopyranoside
  • 3,4-dichloro-N-((1-nicotinoylpiperidin-4-yl)methyl)benzamide
  • 3-(phenylthio)-N-((1-(pyrazin-2-yl)piperidin-4-yl)methyl)propanamide
  • 2-(6-Quinolinylmethylene)hydrazinecarboxamide
  • N-[1-cyano-2-(3,4-difluorophenoxy)-1-methylethyl]bicyclo[3.1.0]hexane-6-carboxamide
  • 3-(3,5-dimethyl-1H-pyrazol-4-yl)-N-[4-hydroxy-2-methyl-5-(propan-2-yl)phenyl]-2-methylpropanamide
  • 6-bromo-4-fluoro-2-methyl-2,3-dihydro-1H-inden-1-one
  • N-[1-(aminomethyl)cyclopentyl]-2-(4-methylphenyl)ethene-1-sulfonamide
  • 2-[4-(2-methyl-1,3-dioxolan-2-yl)piperidin-1-yl]-N-(2,2,2-trifluoroethyl)propanamide
  • (dicyclopropyl-4H-1,2,4-triazol-3-yl)methanol
  • tert-butyl N-[2-(2,6-difluorophenyl)-2-hydroxyethyl]carbamate
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