1-Methyl-4-(methylsulfonyl)benzene

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Names

[ CAS No. ]:
3185-99-7

[ Name ]:
1-Methyl-4-(methylsulfonyl)benzene

[Synonym ]:
1-Methanesulfonyl-4-methyl-benzene
tosyl chloride
Benzene, 1-methyl-4-(methylsulfonyl)-
Sulfone, methyl p-tolyl
Sulfone,methyl p-tolyl
Benzene, 1-methyl-4- (methylsulfonyl)-
p-Tolyl methyl sulfone
methyl-(4-methylphenyl)sulphone
Methyl 4-methylphenyl sulfone
MFCD00014742
Benzene,1-methyl-4-(methylsulfonyl)
Methyl p-Tolyl Sulfone
Sulfone, methyl p-tolyl (8CI)
4-(methylsulphonyl)toluene
p-Me(C6H4)SO2Me
EINECS 221-682-8
4-(Methylsulfonyl)toluene
P-METHYLSULFONYLTOLUENE
1-Methyl-4-(methylsulfonyl)benzene

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
311.7±25.0 °C at 760 mmHg

[ Melting Point ]:
85-89 °C(lit.)

[ Molecular Formula ]:
C8H10O2S

[ Molecular Weight ]:
170.229

[ Flash Point ]:
173.4±15.8 °C

[ Exact Mass ]:
170.040146

[ PSA ]:
42.52000

[ LogP ]:
0.96

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.520

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302-H315-H318-H335

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn:Harmful

[ Risk Phrases ]:
R22;R37/38;R41

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
1

[ HS Code ]:
2904100000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 4-methylthioanisole
  • Sodium toluene-4-sulphinate
  • methyl iodide
  • 4-Iodotoluene
  • Sodium methanesulfinate
  • Dibromomethane
  • Tosyl chloride
  • 4-Bromotoluene
  • isopropylidene 5-tosyloxymalonate

DownStream

  • 4-(Methylsulfonyl)benzylchloride
  • 4-Methylsulfonyl benzoic acid
  • 4-(Methylsulfonyl)benzylamine
  • 2-methyl-5-methylsulfonylbenzenesulfonyl chloride
  • 4-Methylbenzenesulfinic acid
  • p-Cresol
  • ethene
  • Toluene
  • Benzene,1-[(2,4-diphenyl-1,3-butadien-1-yl)sulfonyl]-4-methyl-
  • Benzenemethanol, a-[[(4-methylphenyl)sulfonyl]methyl]-a-(2-phenylethenyl)-

Customs

[ HS Code ]: 2904100000

[ Summary ]:
2904100000 derivatives containing only sulpho groups, their salts and ethyl esters。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Related Compounds

  • 2-iodo-1-methyl-4-(methylsulfonyl)benzene
  • 2-Bromo-1-methyl-4-(methylsulfonyl)benzene
  • 2-Chloro-1-methyl-4-(methylsulfonyl)benzene
  • 2-FLUORO-1-METHYL-4-(METHYLSULFONYL)BENZENE
  • 1-methyl-4-[(methyldisulfanyl)methylsulfonyl]benzene
  • 1-methyl-4-[(4-methylphenyl)methylsulfonyl]benzene
  • tert-butyl N-{2-chloro-4-[(1R)-1-hydroxyethyl]phenyl}carbamate
  • 3-[(2S)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)hexanamido]benzoic acid
  • 7-[(2S)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)hexanoyl]-7-azabicyclo[2.2.1]heptane-2-carboxylic acid
  • 3-[3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-5,5-dimethylhexanamido]-2-methoxypropanoic acid
  • 1-[3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-2-methoxypropanoyl]-3-propylpyrrolidine-3-carboxylic acid
  • 3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-3-({[3-(hydroxymethyl)phenyl]methyl}carbamoyl)propanoic acid
  • 2-{[4-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-2-methoxyphenyl]formamido}-2-methylpropanoic acid
  • 1-[2-(1-ethynylcyclopropyl)ethyl]-1H-1,2,4-triazole
  • 2-[3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-2-methoxypropanamido]-1-methylcyclohexane-1-carboxylic acid
  • 4-[3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-2-methoxy-N-methylpropanamido]benzoic acid
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