2-PROPENOIC ACID, 3-BROMO-, ETHYL ESTER, (2Z)-

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Names

[ CAS No. ]:
31930-34-4

[ Name ]:
2-PROPENOIC ACID, 3-BROMO-, ETHYL ESTER, (2Z)-

[Synonym ]:
(Z)-3-Bromopropenoic acid ethyl ester
(Z)-ethyl 3-bromopropenate
cis-3-Bromoacrylic Acid Ethyl Ester
(Z)-3-Bromoacrylic acid ethyl ester
(2Z)-3-Bromopropenoic acid ethyl ester
Ethyl cis-3-BroMoacrylate
3-bromo-acrylic acid ethyl ester
ethyl (Z)-3-bromopropenoate
ethyl (Z)-3-bromoacrylate
Ethyl (Z)-3-bromo-2-propenoate
CIS-3-BROMOACRYLIC ACID ETHYL ESTER
(2Z)-3-Bromoacrylic acid ethyl ester
Ethyl (2Z)-3-bromoprop-2-enoate
ethyl 3-bromo-2Z-propenoate
(Z) Ethyl 3-bromoacrylate

Chemical & Physical Properties

[ Density]:
1.475g/cm3

[ Boiling Point ]:
173.7ºC at 760mmHg

[ Molecular Formula ]:
C₅H₇BrO₂

[ Molecular Weight ]:
179.01200

[ Flash Point ]:
58.9ºC

[ Exact Mass ]:
177.96300

[ PSA ]:
26.30000

[ LogP ]:
1.45810

[ Index of Refraction ]:
n20/D 1.481

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;Xn: Harmful;

[ Risk Phrases ]:
36/37/38-52/53-22

[ Safety Phrases ]:
26-36-61

[ RIDADR ]:
UN 3082 9/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ HS Code ]:
2916190090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2916190090

[ Summary ]:
2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

Articles

In vivo oxidative metabolism of a major peroxidation-derived DNA adduct, M1dG.

Proc. Natl. Acad. Sci. U. S. A. 103(17) , 6665-9, (2006)

3-(2-Deoxy-beta-D-erythro-pentofuranosyl)pyrimido[1,2-alpha]purin-10(3H)-one (M1dG) is a DNA adduct arising from the reaction of 2-deoxyguanosine with the lipid peroxidation product, malondialdehyde, ...

"One-pot" syntheses of malondialdehyde adducts of nucleosides.

Nucleosides Nucleotides Nucleic Acids 27(2) , 103-9, (2008)

Short, "one-pot" syntheses of malondialdehyde adducts of deoxyguanosine, deoxyadenosine, and deoxycytidine are described. These syntheses proceed in improved yield and easier purification than previou...

A.B. Smith, S.N. Kilényi

Tetrahedron Lett. 26 , 4419, (1985)

ethyl 3-(2-nitrophenyl)sulfonylprop-2-enoate
ethyl 3-bromo-2-(bromomethyl)prop-2-enoate
Ethyl (2Z)-3-(4-fluorophenyl)-3-hydroxyacrylate
ethyl 3-(4-fluorophenyl)-2-nitroprop-2-enoate
ethyl 3-(3-methylphenyl)-2-nitroprop-2-enoate
3-(Phenylsulfinyl)acrylic acid ethyl ester
(R)-tert-butyl 3-((4-cyanophenyl)methylsulfonamido)pyrrolidine-1-carboxylate
5-(Cyclohexylmethyl)-2-hydroxybenzoic acid
4,6-Dichloro-5-(4-fluorophenyl)-2-methylpyrimidine
4-[3-(3,5-Dimethylphenoxy)propanoyl]morpholine-3-carbonitrile
Benzeneacetamide, N-[(1R)-17-amino-1-[[[[4-[[(aminocarbonyl)amino]methyl]phenyl]methyl]amino]carbonyl]-6-imino-8-oxo-12,15-dioxa-5,7,9-triazaheptadec-1-yl]-I+/--phenyl-
N2-[2-Methoxy-4-(1-methyl-1H-pyrazol-4-yl)phenyl]-N8-(tetrahydro-3-furanyl)pyrido[3,4-d]pyrimidine-2,8-diamine
2-amino-3,3-dimethyl-N-[1-(2-methylphenyl)ethyl]butanamide
1-{Pyrazolo[1,5-a]pyrimidin-5-yl}piperidin-3-amine
1-(Fluoromethyl)cyclopropane-1-sulfonamide
(R)-tert-butyl 3-((3,4-dichlorophenyl)methylsulfonamido)pyrrolidine-1-carboxylate

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