Methyl 2-bromobutyrate

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Names

[ Name ]:
Methyl 2-bromobutyrate

[Synonym ]:
methyl ester of 2-bromobutyric acid
Butanoic acid, 2-bromo-, methyl ester
Methyl 2-bromobutyrate
2-bromobutylic acid methyl ester
2-Bromo methyl butyrate
2-bromobutanoic acid methyl ester
EINECS 221-699-0
2-Bromobutyric Acid Methyl Ester
Methyl 2-bromobutanoate
methyl bromobutyrate
Butanoic acid,2-bromo-,methyl ester
MFCD00009666

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
171.0±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C₅H₉BrO₂

[ Molecular Weight ]:
181.028

[ Flash Point ]:
68.3±0.0 °C

[ Exact Mass ]:
179.978592

[ PSA ]:
26.30000

[ LogP ]:
1.72

[ Vapour Pressure ]:
1.4±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.454

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H315

[ Precautionary Statements ]:
P210

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US)

[ Hazard Codes ]:
C:Corrosive

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S36/37/39-S45-S24-S16-S9

[ RIDADR ]:
UN 3265 8/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
2915600000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

2-butene
2-bromobutan-1-ol
Methanol
2-Bromobutyric acid
2-Phenoxybutyric acid
methyl 2-(4-phenylmethoxyphenoxy)butanoate
methyl 2-methyl-2-(4-phenylmethoxyphenoxy)butanoate
methyl 2-(4-hydroxyphenoxy)-2-methylbutanoate
methyl (2R)-2-(4-hydroxyphenoxy)-2-methylbutanoate
methyl (2S)-2-(4-hydroxyphenoxy)-2-methylbutanoate

Customs

[ HS Code ]: 2915900090

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

Articles

Copper(I) mediated cross-coupling of amino acid derived organozinc reagents with acid chlorides.

Org. Biomol. Chem. 4(9) , 1796-805, (2006)

This paper describes the development of a straightforward experimental protocol for copper-mediated cross-coupling of amino acid derived beta-amido-alkylzinc iodides 1 and 3 with a range of acid chlor...

An efficient enantioselective synthesis of an indane acetic acid derivative: methyl (2S)-2-[(1S)-5-hydroxy-2, 3-dihydro-1H-inden-1-yl] butanoate. Zhang M, et al.

Tetrahedron Asymmetry 14(22) , 3447-53, (2003)