Methyl 2-bromobutyrate

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Names

[ CAS No. ]:
3196-15-4

[ Name ]:
Methyl 2-bromobutyrate

[Synonym ]:
methyl ester of 2-bromobutyric acid
Butanoic acid, 2-bromo-, methyl ester
Methyl 2-bromobutyrate
2-bromobutylic acid methyl ester
2-Bromo methyl butyrate
2-bromobutanoic acid methyl ester
EINECS 221-699-0
2-Bromobutyric Acid Methyl Ester
Methyl 2-bromobutanoate
methyl bromobutyrate
Butanoic acid,2-bromo-,methyl ester
MFCD00009666

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
171.0±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C5H9BrO2

[ Molecular Weight ]:
181.028

[ Flash Point ]:
68.3±0.0 °C

[ Exact Mass ]:
179.978592

[ PSA ]:
26.30000

[ LogP ]:
1.72

[ Vapour Pressure ]:
1.4±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.454

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H315

[ Precautionary Statements ]:
P210

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US)

[ Hazard Codes ]:
C:Corrosive

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S36/37/39-S45-S24-S16-S9

[ RIDADR ]:
UN 3265 8/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
2915600000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Butyryl chloride
  • Methanol
  • Butyric Acid
  • 2-bromobutyryl chloride

DownStream

  • 2-butene
  • 2-bromobutan-1-ol
  • Methanol
  • 2-Bromobutyric acid
  • 2-Phenoxybutyric acid
  • methyl 2-(4-phenylmethoxyphenoxy)butanoate
  • methyl 2-methyl-2-(4-phenylmethoxyphenoxy)butanoate
  • methyl 2-(4-hydroxyphenoxy)-2-methylbutanoate
  • methyl (2R)-2-(4-hydroxyphenoxy)-2-methylbutanoate
  • methyl (2S)-2-(4-hydroxyphenoxy)-2-methylbutanoate

Customs

[ HS Code ]: 2915900090

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

Articles

Copper(I) mediated cross-coupling of amino acid derived organozinc reagents with acid chlorides.

Org. Biomol. Chem. 4(9) , 1796-805, (2006)

This paper describes the development of a straightforward experimental protocol for copper-mediated cross-coupling of amino acid derived beta-amido-alkylzinc iodides 1 and 3 with a range of acid chlor...

An efficient enantioselective synthesis of an indane acetic acid derivative: methyl (2S)-2-[(1S)-5-hydroxy-2, 3-dihydro-1H-inden-1-yl] butanoate. Zhang M, et al.

Tetrahedron Asymmetry 14(22) , 3447-53, (2003)


More Articles

Related Compounds

  • methyl 2-bromobutyrate
  • methyl 2-bromobutyrate
  • methyl 2-amino-4-bromobutyrate hydrobromide
  • Methyl 2-Acetoxy-4-bromobutanoate
  • Methyl 2,3,3,4,4,4-hexafluoro-2-bromobutyrate
  • Methyl 2-chloro-5-hydroxyisonicotinate
  • 2-[(2R)-oxolane-2-amido]-1,3-thiazole-5-sulfonyl fluoride
  • Ethyl 3-isopropyl-4-((tetrahydro-2H-pyran-4-yl)methoxy)-1H-pyrazolo[3,4-b]pyridine-6-carboxylate
  • 2-([1,1':4',1''-Terphenyl]-4-yl)-4-chloro-6-phenyl-1,3,5-triazine
  • 9,10-Dihydro-9,10-dioxo-2-anthracenesulfenyl chloride
  • 5-Methyl-3,4-dihydro-2H-1-benzopyran-3-amine
  • 1-Chloro-3-(propan-2-yloxy)-5-(trifluoromethyl)benzene
  • Carbamic acid, N-[1-(3-chloro-2-cyanophenyl)-4-piperidinyl]-, 1,1-dimethylethyl ester
  • 3-(Azidomethyl)-N,N-dimethylpyridin-2-amine
  • 3-(Azidomethyl)-2-(pyrrolidin-1-YL)pyridine
  • 4-Chloro-2-isothiocyanato-6-methoxypyrimidine
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