METHYL 1-BROMOCYCLOHEXANECARBOXYLATE

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Names

[ CAS No. ]:
3196-23-4

[ Name ]:
METHYL 1-BROMOCYCLOHEXANECARBOXYLATE

[Synonym ]:
methyl 1-bromocyclohexanecarboxylic acid
methyl 1-bromocyclohexylcarboxylate
MFCD00134214
methyl 1-bromo-cyclohexane-1-carboxylate
Methyl 1-bromocyclohexanecarboxylate
methyl 1-bromocyclohex-1-yl-1-carboxylate
1-Bromcyclohexancarbonsaeure-methylester

Chemical & Physical Properties

[ Density]:
1.39 g/mL at 25ºC(lit.)

[ Boiling Point ]:
115-116ºC19 mm Hg(lit.)

[ Molecular Formula ]:
C8H13BrO2

[ Molecular Weight ]:
221.09200

[ Flash Point ]:
222 °F

[ Exact Mass ]:
220.01000

[ PSA ]:
26.30000

[ LogP ]:
2.25720

[ Index of Refraction ]:
n20/D 1.493(lit.)

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314-H335

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C: Corrosive;

[ Risk Phrases ]:
34-36/37

[ Safety Phrases ]:
26-27-28-36/37/39-45

[ RIDADR ]:
UN 3265 8/PG 2

[ Packaging Group ]:
III

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • dimethoxymethylene-cyclohexane
  • Cyclohexanecarbonitrile, 1-hydroxy-, acetate
  • TRIMETHOXYMETHYL-CYCLOHEXANE
  • Cyclohexanecarbonitrile
  • cyanocyclohexene
  • Methanol
  • chlorocarbonylcyclohexane
  • Cyclohexanecarboxylic acid

DownStream

  • Methyl 1-cyanocyclohexane-1-carboxylate
  • Methyl 1-cyclohexene-1-carboxylate
  • Methyl 3-oxo-1-cyclohexene-1-carboxylate
  • cyclohexylidenemethoxymethoxy(trimethyl)silane

Articles

Improved preparation of methyl 3-oxo-1-cyclohexene-1-carboxylate and its use in the synthesis of substituted 1, 5-cyclodecadienes. Lange GL and Otulakowski JA.

J. Org. Chem. 47(26) , 5093-96, (1982)

Reaction of Reformatsky reagent prepared from methyl 1-bromocyclohexanecarboxylate and zinc with substituted chalcones. Kirillov NF and Gavrilov AG.

Russ. J. Org. Chem. 44(7) , 963-4, (2008)

Reformatsky Synthesis of 16-Aryl-15-oxadispiro [5.1. 5.3] hexadecane-7, 14-diones. Kirillov NF and Shchepin VV.

Russ. J. Org. Chem. 37(9) , 1223-24, (2001)


More Articles

Related Compounds

  • methyl 1-methyl-3-phenylpyrazole-4-carboxylate
  • methyl 1-(2-nitropyridin-3-yl)piperidine-2-carboxylate
  • methyl 1-ethyl-9H-pyrido[3,4-b]indole-3-carboxylate
  • methyl 1-(2,2-dimethoxyethyl)azetidine-2-carboxylate
  • methyl 1-(2-nitrophenyl)piperidine-2-carboxylate
  • methyl 1-cyclooctylazetidine-2-carboxylate
  • 7-chloro-1-(tetrahydropyran-4-yl)methyl-1H-indole-3-carbonitrile
  • 3-[(Difluoromethyl)sulfanyl]benzene-1-sulfonyl chloride
  • Dimethyl 5-ethoxybenzene-1,3-dicarboxylate
  • 4-Methyl-5-nitronicotinic acid
  • (7-cyano-chroman-4-yl)-carbamic Acid tert-butyl Ester
  • 7-chloro-1-(oxan-4-ylmethyl)-1H-indole-3-carboximidamide
  • 4-(2-Methoxypyridin-4-yloxy)benzenamine
  • 4-Methoxy-7-[(4-methylphenyl)sulfonyl]-7H-pyrrolo[2,3-d]pyrimidine
  • 6-(3,4-Dichlorophenyl)-1,2-dihydro-2-oxo-3-pyridinecarboxylic acid
  • 6-(Butan-2-yl)-2-hydroxypyridine-3-carboxylic acid
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