(-)-Corey lactone diol

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Names

[ CAS No. ]:
32233-40-2

[ Name ]:
(-)-Corey lactone diol

[Synonym ]:
(-)-6beta-Hydroxymethyl-7alpha-hydroxy-cis-2-oxabicyclo[3.3.0]octan-3-one
(-)-Corey lactone
(-)-CoreyLactoneDiol
2H-Cyclopenta[b]furan-2-one, hexahydro-5-hydroxy-4-(hydroxymethyl)-, (3aR,4S,5R,6aS)-
MFCD00075234
(3aR,4S,5R,6aS)-5-Hydroxy-4-(hydroxymethyl)hexahydro-2H-cyclopenta[b]furan-2-one
(3aR,4S,5R,6aS)-(-)-Hexahydro-5-hydroxy-4-(hydroxymethyl)-2H-cyclopenta[b]furan-2-one

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
406.6±25.0 °C at 760 mmHg

[ Melting Point ]:
117-119 °C(lit.)

[ Molecular Formula ]:
C8H12O4

[ Molecular Weight ]:
172.178

[ Flash Point ]:
172.9±16.7 °C

[ Exact Mass ]:
172.073563

[ PSA ]:
66.76000

[ LogP ]:
-2.18

[ Vapour Pressure ]:
0.0±2.1 mmHg at 25°C

[ Index of Refraction ]:
1.546

[ Storage condition ]:
-20°C

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R24/25

[ Safety Phrases ]:
S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2932209090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • (-)-Corey lactone benzoate
  • ((3aR,4S,6aS)-5-acetoxy-2-oxohexahydro-2H-cyclopenta[b]furan-4-yl)Methyl acetate
  • (3aR,4S,5R,6aS)-4-((tert-butyldimethylsilyloxy)methyl)-5-hydroxyhexahydro-2H-cyclopenta[b]furan-2-one
  • (3aR,4S,5R,6aS)-4-[(Acetyloxy)methyl]hexahydro-5-hydroxy-2H-cyclopenta[b]furan-2-one
  • [(3aR,4S,5R,6aS)-4-(hydroxymethyl)-2-oxo-3,3a,4,5,6,6a-hexahydrocyclopenta[b]furan-5-yl] acetate
  • (4aS,4bR,7aS,8aR)-hexahydrofuro[3',2':3,4]cyclopenta[1,2-d][1,3]dioxin-6(7aH)-one
  • (-)-Corey lactone 4-phenylbenzoate alcohol

DownStream

  • Lubiprostone
  • (+)-Cloprostenol
  • LatanoprostAcid
  • Latanoprost Lactol
  • Latanoprost
  • (3AR,4S,5R,6AS)-4-(((TERT-BUTYLDIMETHYLSILYL)OXY)METHYL)-5-((TETRAHYDRO-2H-PYRAN-2-YL)OXY)HEXAHYDRO-2H-CYCLOPENTA[B]FURAN-2-ONE
  • Sulprostone
  • tromethamine
  • (-)-3-OXO-6-BETA-TRITYLOXYMETHYL-7-ALPHA-BENZOYL-OXY-2-OXABICYCLO[3.3.0!OCTANE
  • Lubiprostone

Customs

[ HS Code ]: 2932209090

[ Summary ]:
2932209090. other lactones. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Related Compounds

  • (-)-Corey lactone diol-heptyldioxolane-d15
  • (+/-)-Corey lactone diol
  • Corey PG-lactone diol
  • (-)-Corey lactone benzoate
  • (-)-Corey lactone 4-phenylbenzoate alcohol
  • (-)-Corey lactone-heptyldioxolane-d15
  • 2-(1H-Imidazol-5-yl)oxazole
  • 2-[(Bromotriphenylphosphoranyl)methyl]pyridine
  • Methyl 4-bromomethyl-2-(4-fluorophenyl)benzoate
  • 2-(2H-1,3-benzodioxol-5-yl)propanoic acid
  • 2-Bromo-3,4-dihydro-6,7-dimethoxy-1-naphthalenecarboxaldehyde
  • Ethyl 4-[[(hexylamino)thioxomethyl]amino]benzoate
  • N-(1,1-Dimethylethyl)-Na(2)-(4-methyl-2-oxo-2H-1-benzopyran-7-yl)thiourea
  • N-Cyclohexyl-Na(2)-(3-methylbutyl)thiourea
  • N-(5-Aminopyridin-2-yl)propionamide
  • N-Cyclopropyl-2,6-dimethyl-4-morpholinecarbothioamide
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