(Diacetoxyiodo)benzene

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Names

[ CAS No. ]:
3240-34-4

[ Name ]:
(Diacetoxyiodo)benzene

[Synonym ]:
Iodosobenzene diacetate
bis-acetoxy iodobenzene
Phenyliodo diacetate
iodosobensene I,I-diacetate
Iodobenzene diacetate
Diacetoxy(phenyl)-λ-iodane
Iodine, bis(acetyloxy)phenyl-
phenyliodonium diacetate
Phenyliodine diacetate
iodobenzene 1,1-diacetate
EINECS 221-808-1
Iodobenzenediacetate
Phenyliodoso acetate
phenyliodine(iii) diacetate
Benzene, (diacetoxyiodo)-
iodosobenzene 1,1-diacetate
Phenyliodosodiacetate
MFCD00008692
(Diacetoxyiodo)benzene
bis(acetyloxy)(phenyl)-λ-iodane

Chemical & Physical Properties

[ Density]:
1.6865

[ Boiling Point ]:
456.8ºC at 760 mmHg

[ Melting Point ]:
161-165 ºC

[ Molecular Formula ]:
C10H11IO4

[ Molecular Weight ]:
322.096

[ Flash Point ]:
230.1ºC

[ Exact Mass ]:
321.970184

[ PSA ]:
52.60000

[ LogP ]:
2.31880

[ Storage condition ]:
-20°C

[ Water Solubility ]:
INSOLUBLE

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
DA3525000
CHEMICAL NAME :
Benzene, iodoso-, diacetate
CAS REGISTRY NUMBER :
3240-34-4
LAST UPDATED :
199712
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C10-H11-I-O4
MOLECULAR WEIGHT :
322.11
WISWESSER LINE NOTATION :
1VO-I-R &OV1 &5/10

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
56 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#02976

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S22-S24/25-S37/39-S26

[ RIDADR ]:
1479

[ WGK Germany ]:
3

[ RTECS ]:
DA3525000

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1(b)

[ HS Code ]:
29310095

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Iodobenzene
  • Ethanoic anhydride
  • acetic acid
  • benzene
  • Peracetic acid
  • Trimethylsilyl acetate
  • Iodosobenzene
  • Cyclopropylbenzene

DownStream

  • 5-chloro-2-phenyl-1,3-benzoxazole
  • Phenol, 2,5-dimethyl-,1-acetate
  • 2,2',5,5'-Tetramethylbiphenyl
  • Methyl 2-methoxybenzoate
  • Butyl iodide
  • Iodobenzene
  • Octane
  • 2-Hexanone
  • Lithium acetate
  • benzene

Customs

[ HS Code ]: 2916399090

[ Summary ]:
2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

An expedient procedure for the oxidative cleavage of olefinic bonds with PhI(OAc)2, NMO, and catalytic OsO4.

Org. Lett. 12(7) , 1552-5, (2010)

PhI(OAc)(2) in the presence of OsO(4) (cat.) and 2,6-lutidine cleaves olefinic bonds to yield the corresponding carbonyl compounds, albeit, in some cases, with alpha-hydroxy ketones as byproduct. A mo...

Palladium-catalyzed oxygenation of unactivated sp3 C-H bonds.

J. Am. Chem. Soc. 126 , 9542-9543, (2004)

This communication describes a new palladium-catalyzed method for the oxygenation of unactivated sp3 C-H bonds. A wide variety of alkane substrates containing readily available oxime and/or pyridine d...

Determination of vitamin C in tablets and fruits by titration with phenyliodosoacetate.

Il Farmaco 37(1) , 9-14, (1982)


More Articles

Related Compounds

  • 4-bromo(diacetoxyiodo)benzene
  • 2-nitro(diacetoxyiodo)benzene
  • 4-nitro(diacetoxyiodo)benzene
  • p-cyclopropyl(diacetoxyiodo)benzene
  • 1-(DIACETOXYIODO)-4-(1H,1H,2H,2H-PERFLUORODECYL)BENZENE
  • 1-(diacetoxyiodo)-3-nitrobenzene
  • 2-[2-(methoxymethyl)phenyl]-1H-pyrrolo[2,3-b]pyridine
  • Tert-butyl 1-(2-hydroxyethyl)-6-azaspiro[2.5]octane-6-carboxylate
  • L-Seryl-N~5~-(diaminomethylidene)-L-ornithyl-N~5~-(diaminomethylidene)-L-ornithyl-N~5~-(diaminomethylidene)-L-ornithyl-L-valyl-L-asparagine
  • 2-Cyclopropyl-5-{[(1,3-thiazol-4-yl)methyl]sulfanyl}-1,3,4-thiadiazole
  • 1-Acetyl-L-prolyl-L-alanyl-L-prolyl-L-phenylalanyl-L-alanyl-L-alaninamide
  • tert-butyl N-(hex-1-yn-3-yl)carbamate
  • 2-[3-Nitro-5-(trifluoromethyl)phenyl]ethanamine
  • 3-Bromo-4-(4-phenoxyphenoxy)pyridine
  • 2-(2-Fluorophenoxy)-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine
  • (4-((1-Methylpiperidin-4-yl)oxy)phenyl)boronic acid
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