|S|-(+)-4,12-Bis[di(3,5-xylyl)phosphino]-[2.2]-paracyclophane

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Names

[ CAS No. ]:
325168-88-5

[ Name ]:
|S|-(+)-4,12-Bis[di(3,5-xylyl)phosphino]-[2.2]-paracyclophane

[Synonym ]:
MFCD03840578

Chemical & Physical Properties

[ Melting Point ]:
234-238ºC

[ Molecular Formula ]:
C48H50P2

[ Molecular Weight ]:
688.85800

[ Exact Mass ]:
688.33900

[ PSA ]:
27.18000

[ LogP ]:
9.55400

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319

[ Precautionary Statements ]:
P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
36/38

[ Safety Phrases ]:
26

[ RIDADR ]:
NONH for all modes of transport

Articles

A catalyst for efficient and highly enantioselective hydrogenation of aromatic, heteroaromatic, and alpha,beta-unsaturated ketones

Org. Lett. 2 , 4173, (2000)

PhanePhos-ruthenium-diamine complexes catalyze the asymmetric hydrogenation of a wide range of aromatic, heteroaromatic, and alpha, beta-unsaturated ketones with high activity and excellent enantiosel...

J. Am. Chem. Soc. 119 , 6207, (1997)


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