Titanium(IV) dimethylamide

Suppliers

Names

[ Name ]:
Titanium(IV) dimethylamide

[Synonym ]:
Tetrakis(dimethylamino)titanium
Octamethylstannanetetramine
Tetrakis(diMethylaMino)titaniuM(IV)
EINECS 221-904-3
Tetrakis(Dimethylamino)Titanium (Metals Basis)
Tetrakisdimethylaminotitan
Tetrakis(dimethylamido)titanium(IV)
Stannanetetramine,N,N,N',N',N'',N'',N''',N'''-octamethyl
Stannanetetramine,octamethyl
MFCD00014861

Chemical & Physical Properties

[ Density]:
0.947

[ Boiling Point ]:
50ºC (0.5 mmHg)

[ Melting Point ]:
<4ºC

[ Molecular Formula ]:
C₈H₂₄N₄Ti

[ Molecular Weight ]:
224.17000

[ Flash Point ]:
-5ºC

[ Exact Mass ]:
224.14800

[ PSA ]:
12.96000

[ LogP ]:
0.04920

[ Index of Refraction ]:
1.55

[ Storage condition ]:
Flammables area

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H260-H314

[ Supplemental HS ]:
Reacts violently with water.

[ Precautionary Statements ]:
P210-P223-P231 + P232-P280-P370 + P378-P422

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F:Flammable;C:Corrosive;

[ Risk Phrases ]:
R11;R14;R34

[ Safety Phrases ]:
S16-S26-S36/37/39-S43-S45

[ RIDADR ]:
UN 3398

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
4.3

[ HS Code ]:
2924199090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Tetra-tert-butyl orthotitanate
Tris(dimethylamino)methane
Methyl 3-(dimethylamino)propanoate
3-(dimethylamino)-N,N-dimethylpropanamide
n'-tert-butyl-n,n-dimethylformamidine
N-diethoxyphosphoryl-N-methylmethanamine
4-chloro-3-[5-[(ethylcarbamothioylhydrazinylidene)methyl]furan-2-yl]benzoic acid
N-dimethylsulfinamoyl-N-methylmethanamine

Customs

[ HS Code ]: 2924199090

[ Summary ]:
2924199090. other acyclic amides (including acyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

The influence of structure and processing on the behavior of TiO2 protective layers for stabilization of n-Si/TiO2/Ni photoanodes for water oxidation.

ACS Appl. Mater. Interfaces 7 , 15189-99, (2015)

Light absorbers with moderate band gaps (1-2 eV) are required for high-efficiency solar fuels devices, but most semiconducting photoanodes undergo photocorrosion or passivation in aqueous solution. Am...

J. Appl. Phys. 102 , 083521/1, (2007)

Chem. Mater. 8 , 2712, (1996)