Chloro(cyclopentadienyl)bis-(triphenylphosphine)ruthenium(II)

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Names

[ CAS No. ]:
32993-05-8

[ Name ]:
Chloro(cyclopentadienyl)bis-(triphenylphosphine)ruthenium(II)

[Synonym ]:
[Cp(PPh3)2RuCl]
Cyclopentadienylbis(triphenylphosphine)rutheniuM(II) Chloride
Phosphine, triphenyl-, compd. with chloro-1,3-cyclopentadien-1-ylruthenium (2:1)
CpRu(PPh3)2Cl
Chloro(1,3-cyclopentadien-1-yl)ruthenium - triphenylphosphine (1:2)
Chlorocyclopentadienylbis-(triphenylphosphino)-ruthenium
MFCD00075004
chlorocyclopentadienylbis(triphenylphosphine)ruthenium
Chlorocyclopentadienylbis(triphenylphosphine)rutenium(II)
Cyclopentadienyl
(Ph3P)2(cyclopentadienyl)RuCl
Chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium(II)
[ClRu(PPh3)2Cp]
Chlorocyclopentadienylbis(triphenylphosphine)rutheniuM(II) 5GR

Chemical & Physical Properties

[ Melting Point ]:
135 °C (dec.)(lit.)

[ Molecular Formula ]:
C41H35ClP2Ru

[ Molecular Weight ]:
726.187

[ Exact Mass ]:
726.094666

[ PSA ]:
27.18000

[ LogP ]:
8.60060

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H312-H315-H319-H332-H335

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn: Harmful;

[ Risk Phrases ]:
R20/21/22;R36/37/38

[ Safety Phrases ]:
26-37/39-36/37/39-22

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  •
  • (η5-cyclopentadienyl)methylbis(triphenylphosphine)ruthenium
  • Tris(triphenylphosphoranyl)ruthenium(V) chloride hydride
  • 1,4-Pentadiene
  • Tetraphenylphosphonium chloride
  • Hydrochloric acid
  • [(η5-C5H5)Ru(P(C6H5)2(2-CH3-C6H4))2Cl]

DownStream

  • Di-1,3-cyclopentadien-1-ylruthenium
  • [RuCl(CO)(PPh3)(η-C5H5)]
  • (η5-cyclopentadienyl)phenyl-d5-bis(triphenylphosphine)ruthenium
  • 2,2-dimethylpropane

Related Compounds

  • 5-Methyl-2-(thian-4-yl)pyrimidine-4-carboxylic acid
  • 2-(3-Methoxy-2-methylpropyl)-4-methylpyrimidine-5-carboxylic acid
  • 4-Ethyl-2-(thietan-3-yl)pyrimidine-5-carboxylic acid
  • 2-(Thian-4-yl)pyrimidine-4-carboxylic acid
  • 4-Methyl-2-[3-(methylsulfanyl)propyl]pyrimidine-5-carboxylic acid
  • 5-Methyl-2-(2-methyl-1,3-thiazol-4-yl)pyrimidine-4-carboxylic acid
  • 2-(1-Methylpiperidin-3-yl)pyrimidine-4-carboxylic acid
  • 5-Cyclobutyl-3-(1,3-thiazol-2-yl)-1,2-oxazole-4-carboxylic acid
  • 8-Methyl-2-propoxyquinoline-3-carboxylic acid
  • 6-Tert-butyl-2-propoxyquinoline-3-carboxylic acid
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