1-Methyl-L-histidine

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Names

[ CAS No. ]:
332-80-9

[ Name ]:
1-Methyl-L-histidine

[Synonym ]:
Histidine, N-tau-methyl-
(2S)-2-amino-3-(1-methylimidazol-4-yl)propanoic acid
Nτ-Methyl-His-OH
Histidine, 1-methyl-, L-
UNII-583O01BJ32
tau-methyl-L-histidine
1-Methyl-Histidine
Ntau-Methyl-L-histidine
(S)-2-Amino-3-(1-methyl-1H-imidazol-4-yl)propanoic acid
N1-Methyl-L-histidine
MFCD00005295
N(tele)-methyl-L-histidine
L-1-Methylhistidine
1-MHis
4-Methyl-Histidine
L-Histidine, 1-methyl-
1-Methyl-L-histidine
EINECS 206-368-0

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
415.0±35.0 °C at 760 mmHg

[ Melting Point ]:
~240 °C (dec.)(lit.)

[ Molecular Formula ]:
C7H11N3O2

[ Molecular Weight ]:
169.181

[ Flash Point ]:
204.8±25.9 °C

[ Exact Mass ]:
169.085129

[ PSA ]:
81.14000

[ LogP ]:
-1.31

[ Vapour Pressure ]:
0.0±1.0 mmHg at 25°C

[ Index of Refraction ]:
1.613

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
S26-S36-S24/25-S22

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2933290090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Nα-Trityl-Nτ-methyl-L-histidin
  • (S)-7-(methoxycarbonyl)-2-methyl-5-oxo-5,6,7,8-tetrahydroimidazo[1,5-c]pyrimidin-2-ium iodide
  • (2S)-2-amino-3-[5-[[5-[(2S)-2-amino-2-carboxyethyl]-3-methylimidazol-4-yl]disulfanyl]-1-methylimidazol-4-yl]propanoic acid
  • (2S)-2-amino-3-(1-methyl-5-sulfanylimidazol-4-yl)propanoic acid
  • Z-His-Ome
  • L-Histidine
  • methyl iodide
  • 1-methyl[2-(3)H]-L-histidine
  • Boc-His(Bom)-OH

DownStream

  • H-His(Nτ-Me)-OH·2HCl

Customs

[ HS Code ]: 2933290090

[ Summary ]:
2933290090. other compounds containing an unfused imidazole ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Development of High-purity Certified Reference Materials for 17 Proteinogenic Amino Acids by Traceable Titration Methods.

Anal. Sci. 31 , 805-14, (2015)

To ensure the reliability of amino acid analyses, the National Metrology Institute of Japan of the National Institute of Advanced Industrial Science and Technology (NMIJ/AIST) has developed high-purit...

Use of high-resolution proton nuclear magnetic resonance spectroscopy for rapid multi-component analysis of urine.

Clin. Chem. 30(3) , 426-32, (1984)

Numerous low-Mr metabolites--including creatinine, citrate, hippurate, glucose, ketone bodies, and various amino acids--have been identified in 400- and 500-MHz proton nuclear magnetic resonance (1H N...

1,5-anhydroglucitol and postprandial hyperglycemia as measured by continuous glucose monitoring system in moderately controlled patients with diabetes.

Diabetes Care 29(6) , 1214-9, (2006)

Postprandial hyperglycemia is often inadequately assessed in diabetes management. Serum 1,5-anhydroglucitol (1,5-AG) drops as serum glucose rises above the renal threshold for glucose and has been pro...


More Articles

Related Compounds

  • 1-methyl-L-histidine
  • 1-Methyl-L-histidine-d3
  • N-BOC-N-IM-1-METHYL-L-HISTIDINE
  • 1-methyl-L-histidine,hydrochloride
  • 1-methyl-l-histidine dihydrochloride
  • 1-Methyl-Nα-(trifluoroacetyl)-L-histidine butyl ester
  • 3-[(2S)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)hexanamido]heptanoic acid
  • 4-[3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)heptanamido]oxolane-3-carboxylic acid
  • 2-{[3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)cyclopentyl]formamido}-3,3-dimethylbutanoic acid
  • 4-Methyl-3-(3-methylpiperidin-2-yl)aniline
  • 1-[(2S)-3-cyclopropyl-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)propanoyl]-2-ethylpyrrolidine-2-carboxylic acid
  • 1-[3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)butanoyl]-6-methylpiperidine-3-carboxylic acid
  • 1-[3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)pentanoyl]-6-methylpiperidine-3-carboxylic acid
  • 4-[3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)pentanamido]-2,2-dimethylbutanoic acid
  • 3-bromo-2-[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)butanamido]benzoic acid
  • (3S)-3-[3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)heptanamido]pentanoic acid
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