lithium triflate

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Names

[ CAS No. ]:
33454-82-9

[ Name ]:
lithium triflate

[Synonym ]:
Trifluoromethanesulfonic acid,lithium salt
Trifluoromethanesulfonic acid, lithium salt
Trifluoromethanesulfonic acid lithium salt
anhydrous lithium triflate
LithoTab triflate
MFCD00013227
lithium trifluoromethanesulphonate
Lithium Trifluoromethanesulfonate (Lithium Triflate)
lithium triflate
Li triflate
Methanesulfonic acid, 1,1,1-trifluoro-, lithium salt (1:1)
Lithium trifluoromethanesulfonate
EINECS 251-528-5

Chemical & Physical Properties

[ Density]:
1,9 g/cm3

[ Boiling Point ]:
162ºC at 760mmHg

[ Melting Point ]:
>300 °C(lit.)

[ Molecular Formula ]:
CF3LiO3S

[ Molecular Weight ]:
156.01

[ Exact Mass ]:
155.968033

[ PSA ]:
65.58000

[ LogP ]:
1.13220

[ Water Solubility ]:
soluble

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2904909090

Synthetic Route

Precursor & DownStream

Precursor

  • bis(trifluoromethyl)sulfone
  • Barium bis(trifluoromethanesulfonate)
  • Lithium hydroxide
  • (methyldiphenylstannyl)lithium
  • Trifluoromethanesulfonic acid
  • Dimethylamine
  • diphenylstannanediyl bis(trifluoromethanesulfonate)
  • Lithium bis(trimethylsilyl)amide
  • lithium,ethynylbenzene

DownStream

  • 3,5-Dichloro-1-fluoropyridinium triflate
  • 1-Hexyl-3-methylimidazolium trifluoromethansulfonate
  • TETRA-N-BUTYLAMMONIUM TRIFLUOROMETHANESULFONATE
  • Ethyl triflate
  • trans-1,2-Dichlorocyclohexane
  • BMP-NTf2
  • 1-chloro-2-(trifluoromethylsulfonyloxy)ethane
  • dichloroethane
  • Cyclohexane, 1,2-dibromo-, (1R,2R)-rel-

Customs

[ HS Code ]: 2904909090

[ Summary ]:
HS:2904909090 sulphonated, nitrated or nitrosated derivatives of hydrocarbons, whether or not halogenated VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Effect of three trifluoromethanesulfonate ionic liquids on the activity, stability and conformation of laccase.

Int. J. Biol. Macromol. 56 , 62-8, (2013)

The activity, stability and conformation of laccase were first investigated in an aqueous solution of ionic liquids 1-butyl-3-methylimidazolium trifluoromethanesulfonate ([Bmim]TfO), 1-butyl-1-methylp...

Ultrathin Nanotube/Nanowire Electrodes by Spin-Spray Layer-by-Layer Assembly: A Concept for Transparent Energy Storage.

ACS Nano 9 , 10005-17, (2015)

Fully integrated transparent devices require versatile architectures for energy storage, yet typical battery electrodes are thick (20-100 μm) and composed of optically absorbent materials. Reducing th...

In(III)/PhCO2H binary acid catalyzed tandem [2 + 2] cycloaddition and Nazarov reaction between alkynes and acetals.

Org. Lett. 15(17) , 4496-9, (2013)

A facile tandem [2 + 2] cycloaddition and Nazarov reaction has been developed. The combination of In(OTf)3 and benzoic acid was found to synergistically promote the coupling of alkynes and acetals to ...


More Articles


Related Compounds

  • lithium triflate
  • lithium,scandium
  • lithium,trimethyl(prop-2-enyl)silane
  • lithium pyruvate
  • lithium,1,3,5-trimethylcyclopenta-1,3-diene
  • lithium,1-trityl-2H-imidazol-2-ide
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2,6-Dimethyl-4-[(3-methylazetidin-3-yl)oxy]phenol
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide