3-Bromothioanisole

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Names

[ CAS No. ]:
33733-73-2

[ Name ]:
3-Bromothioanisole

[Synonym ]:
3-Bromothioanisole
MFCD00041395
1-Bromo-2-(methylsulfanyl)benzene
3-Bromophenyl methyl sulphide
2-(methylthio)bromo benzene
Benzene, 1-bromo-3-(methylthio)-
Benzene, 1-bromo-2-(methylthio)-
3-methylthio-1-bromobenzene
3-Bromophenyl methyl sulfide
1-Bromo-3-(methylsulfanyl)benzene
1-bromo-3-methylsulfanyl-benzene
2-Bromophenyl methyl sulfide
3-bromo thioanisole
1-bromo-3-methylsulphanyl-benzene
1-Bromo-3-(methylthio)benzene
o-Bromo(methylthio)benzene

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
237.4±23.0 °C at 760 mmHg

[ Molecular Formula ]:
C7H7BrS

[ Molecular Weight ]:
203.100

[ Flash Point ]:
97.4±22.6 °C

[ Exact Mass ]:
201.945175

[ PSA ]:
25.30000

[ LogP ]:
3.46

[ Vapour Pressure ]:
0.1±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.624

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/38

[ Safety Phrases ]:
S23-S24/25

[ RIDADR ]:
UN 3334

[ WGK Germany ]:
3

[ HS Code ]:
2930909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 3-Bromothiophenol
  • methyl iodide
  • 1,3-Dibromobenzene
  • Sodium thiomethoxide
  • 3-(Methylmercapto)aniline
  • Dimethyl disulfide
  • 1-Bromo-3-iodobenzene
  • Dimethyl sulfate
  • 6,6-dibromobicyclo[3.1.0]hexane

DownStream

  • 3-Bromophenyl methyl sulfone
  • 1-bromo-3-methylsulfinylbenzene
  • 2-BROMOPHENYL METHYL SULFONE
  • 2-Bromophenyl Methyl Sulfoxide
  • 3-METHYLTHIOANISOLE
  • Benzene, 1-ethynyl-3-(methylthio)- (9CI)
  • acetic acid
  • 3-(methylthio) benzoic acid
  • 3-Bromophenyl trifluoromethyl sulfide
  • 3-Fluorothioanisole

Customs

[ HS Code ]: 2930909090

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Efficient photoacids based upon triarylamine dialkylsulfonium salts. Zhou W, et al.

J. Am. Chem. Soc. 124(9) , 1897-1901, (2002)

Enhancement of acid photogeneration through a para-to-meta substitution strategy in a sulfonium-based alkoxystilbene designed for two-photon polymerization. Xia R, et al.

Chem. Mater. 24(2) , 237-244, (2012)

Transition-Metal-Free Acid-Mediated Synthesis of Aryl Sulfides from Thiols and Thioethers. Wagner AM and Sanford MS.

J. Org. Chem. 79(5) , 2263-2267, (2014)


More Articles

Related Compounds

  • 3-(1-thiophen-3-ylpropyl)thiophene
  • 3-[(4-chloro-3-methyl-phenoxy)methyl]-5-(4-fluorophenyl)-4-(4-methylph enyl)-1,2,4-triazole
  • 3-CHLORO-4-(ISOPROPYLSULFONYL)THIOPHENE-2-CARBOXYLIC ACID
  • 3-[(4-chloro-3-methylphenoxy)methyl]-4,5-bis(4-methylphenyl)-1,2,4-triazole
  • 3-(4-chlorophenyl)-5-[(4-methylphenoxy)methyl]-4-(4-methylphenyl)-1,2,4-triazole
  • 3-[(4-methylphenoxy)methyl]-4,5-bis(4-methylphenyl)-1,2,4-triazole
  • 5-fluoro-2-[5-(1H-imidazole-4-sulfonyl)-octahydropyrrolo[3,4-c]pyrrol-2-yl]pyridine
  • N-(3-methoxyphenyl)-3-[(2-methylpyridin-4-yl)oxy]azetidine-1-carboxamide
  • 5-Chloro-2-[5-(4-phenyloxane-4-carbonyl)-octahydropyrrolo[3,4-c]pyrrol-2-yl]pyridine
  • 5-bromo-2-(5-{[1-(propan-2-yl)-1H-imidazol-4-yl]sulfonyl}-octahydropyrrolo[3,4-c]pyrrol-2-yl)pyridine
  • 5-chloro-2-{5-[(1-ethyl-2-methyl-1H-imidazol-4-yl)sulfonyl]-octahydropyrrolo[3,4-c]pyrrol-2-yl}pyridine
  • 3-{[2-(propan-2-yl)-1H-imidazol-1-yl]methyl}-N-[2-(trifluoromethyl)phenyl]azetidine-1-carboxamide
  • 3-{[(3-chloropyridin-2-yl)oxy]methyl}-N-(4-fluorophenyl)piperidine-1-carboxamide
  • 5-bromo-N-[(4-hydroxy-3,4-dihydro-1H-2-benzothiopyran-4-yl)methyl]thiophene-2-sulfonamide
  • N-(3,4-dimethylphenyl)-3-[(2-methylpyridin-4-yl)oxy]azetidine-1-carboxamide
  • N-[(4-chlorophenyl)methyl]-5-(5-fluoropyridin-2-yl)-octahydropyrrolo[3,4-c]pyrrole-2-carboxamide
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