3-Bromothioanisole

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Names

[ CAS No. ]:
33733-73-2

[ Name ]:
3-Bromothioanisole

[Synonym ]:
3-Bromothioanisole
MFCD00041395
1-Bromo-2-(methylsulfanyl)benzene
3-Bromophenyl methyl sulphide
2-(methylthio)bromo benzene
Benzene, 1-bromo-3-(methylthio)-
Benzene, 1-bromo-2-(methylthio)-
3-methylthio-1-bromobenzene
3-Bromophenyl methyl sulfide
1-Bromo-3-(methylsulfanyl)benzene
1-bromo-3-methylsulfanyl-benzene
2-Bromophenyl methyl sulfide
3-bromo thioanisole
1-bromo-3-methylsulphanyl-benzene
1-Bromo-3-(methylthio)benzene
o-Bromo(methylthio)benzene

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
237.4±23.0 °C at 760 mmHg

[ Molecular Formula ]:
C7H7BrS

[ Molecular Weight ]:
203.100

[ Flash Point ]:
97.4±22.6 °C

[ Exact Mass ]:
201.945175

[ PSA ]:
25.30000

[ LogP ]:
3.46

[ Vapour Pressure ]:
0.1±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.624

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/38

[ Safety Phrases ]:
S23-S24/25

[ RIDADR ]:
UN 3334

[ WGK Germany ]:
3

[ HS Code ]:
2930909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 3-Bromothiophenol
  • methyl iodide
  • 1,3-Dibromobenzene
  • Sodium thiomethoxide
  • 3-(Methylmercapto)aniline
  • Dimethyl disulfide
  • 1-Bromo-3-iodobenzene
  • Dimethyl sulfate
  • 6,6-dibromobicyclo[3.1.0]hexane

DownStream

  • 3-Bromophenyl methyl sulfone
  • 1-bromo-3-methylsulfinylbenzene
  • 2-BROMOPHENYL METHYL SULFONE
  • 2-Bromophenyl Methyl Sulfoxide
  • 3-METHYLTHIOANISOLE
  • Benzene, 1-ethynyl-3-(methylthio)- (9CI)
  • acetic acid
  • 3-(methylthio) benzoic acid
  • 3-Bromophenyl trifluoromethyl sulfide
  • 3-Fluorothioanisole

Customs

[ HS Code ]: 2930909090

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Efficient photoacids based upon triarylamine dialkylsulfonium salts. Zhou W, et al.

J. Am. Chem. Soc. 124(9) , 1897-1901, (2002)

Enhancement of acid photogeneration through a para-to-meta substitution strategy in a sulfonium-based alkoxystilbene designed for two-photon polymerization. Xia R, et al.

Chem. Mater. 24(2) , 237-244, (2012)

Transition-Metal-Free Acid-Mediated Synthesis of Aryl Sulfides from Thiols and Thioethers. Wagner AM and Sanford MS.

J. Org. Chem. 79(5) , 2263-2267, (2014)


More Articles

Related Compounds

  • 3-(1-thiophen-3-ylpropyl)thiophene
  • 3-[(4-chloro-3-methyl-phenoxy)methyl]-5-(4-fluorophenyl)-4-(4-methylph enyl)-1,2,4-triazole
  • 3-CHLORO-4-(ISOPROPYLSULFONYL)THIOPHENE-2-CARBOXYLIC ACID
  • 3-[(4-chloro-3-methylphenoxy)methyl]-4,5-bis(4-methylphenyl)-1,2,4-triazole
  • 3-(4-chlorophenyl)-5-[(4-methylphenoxy)methyl]-4-(4-methylphenyl)-1,2,4-triazole
  • 3-[(4-methylphenoxy)methyl]-4,5-bis(4-methylphenyl)-1,2,4-triazole
  • N-{2-[4-(1-methyl-1H-pyrazol-5-yl)phenyl]ethyl}cyclopentanecarboxamide
  • 6-(4-{[4-(4-Acetylpiperazin-1-yl)but-2-yn-1-yl]oxy}piperidin-1-yl)-5-chloropyridine-3-carbonitrile
  • 2-{4-[4-(pyrrolidin-1-yl)pyrimidin-2-yl]piperazin-1-yl}-5H,7H,8H-pyrano[4,3-b]pyridine-3-carbonitrile
  • N-cyclohexyl-4-{[(3-methylpyridin-4-yl)oxy]methyl}piperidine-1-carboxamide
  • 2-(2-chlorophenyl)-1-{3-[(2-methyl-1H-imidazol-1-yl)methyl]azetidin-1-yl}ethan-1-one
  • 4-{1-[(2-Chloro-6-fluorophenyl)methyl]piperidine-3-carbonyl}thiomorpholine
  • 3,5-dimethyl-N-{2-[5-(1-methyl-1H-pyrazol-4-yl)thiophen-2-yl]ethyl}-1,2-oxazole-4-carboxamide
  • 1-(2-{[2,2'-Bithiophene]-5-yl}ethyl)-3-(2-methoxyethyl)urea
  • N'-[2-(cyclohex-1-en-1-yl)ethyl]-N-{2-[5-(1-methyl-1H-pyrazol-4-yl)thiophen-2-yl]ethyl}ethanediamide
  • 1-Cyclopropyl-2-({[1,3]thiazolo[4,5-c]pyridin-2-yl}amino)-1-(thiophen-2-yl)ethan-1-ol
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