Palladium diacetate

Suppliers

Names

[ Name ]:
Palladium diacetate

[Synonym ]:
Pd(OAc)2
palladousacetate
diacetatopalladium
Palladium(2+) diacetate
MFCD00012453
Acetic Acid Palladium(II) Salt
PaladiumAcetate
palladiym acetate
Palladium(II) acetate
palladium(II)-acetate
palladium(II)acetate
bisacetylpalladium
Acetic acid, palladium(2+) salt (2:1)
palladium acetate
palladium(II) diacetate
Palladium (II) Acetate
EINECS 222-164-4
palladium(II) ethanoate
Palladium(II)acetat
PALLADIUM DIACETATE
diacetoxypalladium

Chemical & Physical Properties

[ Boiling Point ]:
117.1ºC at 760mmHg

[ Melting Point ]:
205ºC

[ Molecular Formula ]:
C₄H₆O₄Pd

[ Molecular Weight ]:
224.51

[ Flash Point ]:
40ºC

[ Exact Mass ]:
223.930099

[ PSA ]:
80.26000

[ Storage condition ]:
Store at R.T.

[ Water Solubility ]:
insoluble

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: AJ1900000

CHEMICAL NAME :: Acetic acid, palladium(2+) salt

CAS REGISTRY NUMBER :: 3375-31-3

LAST UPDATED :: 199701

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C4-H8-O4.Pd

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 2100 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - dyspnea Gastrointestinal - ulceration or bleeding from stomach

REFERENCE :: GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 51(12),88,1986

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H318

[ Precautionary Statements ]:
P280-P305 + P351 + P338 + P310

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R41

[ Safety Phrases ]:
S26-S39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
2

[ RTECS ]:
AJ1900000

[ HS Code ]:
28439090

Precursor & DownStream

Precursor

DownStream

acetic acid,cyclohex-3-en-1-ol
cyclohex-2-en-1-yl acetate
acetic acid,dicyclohexyl-[2-(1-methyl-3H-indol-3-id-2-yl)phenyl]phosphane,palladium
3,3'-Bithienyl
2 3'-BITHIOPHENE
2,2'-Bithiophene
4-METHYLENE-3,4-DIHYDRO-2H-PYRANO[3,2-B]PYRIDINE
Ethyl benzoate
bis(acetato-O)(2,2'-bipyridine-N,N')palladium
2,6,6-trimethyl-2-cyclohexen-1-one

Customs

[ HS Code ]: 2915299090

[ Summary ]:
2915299090 salts of acetic acid。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:5.5%。general tariff:50.0%

Articles

A sulfoxide-promoted, catalytic method for the regioselective synthesis of allylic acetates from monosubstituted olefins via C-H oxidation.

J. Am. Chem. Soc. 126 , 1346, (2004)

Sulfoxide ligation to Pd(II) salts is shown to selectively promote C-H oxidation versus Wacker oxidation chemistry and to control the regioselectivity in the C-H oxidation products. A catalytic method...

Efficient access to cyclic ureas via Pd-catalyzed cyclization.

Org. Lett. 8 , 3311, (2006)

[Structure: see text] An efficient regioselective method for the preparation of structurally diverse imidazopyridinones and benzoimidazolones starting from readily available and economical starting ma...

Palladium(II) acetate in pyridine as an effective catalyst for highly regioselective hydroselenation of alkynes.

J. Org. Chem. 70 , 696, (2005)

A highly regioselective hydroselenation of terminal alkynes with benzeneselenol can be achieved by the combination of palladium acetate and pyridine, providing the corresponding terminal alkenes, (i.e...