Eschenmoser's reagent

Suppliers

Names

[ Name ]:
Eschenmoser's reagent

[Synonym ]:
Eschenmosers Salt
Eschenmoser's reagent
Eschenmoser's iodide salt
N,N-Dimethylmethaniminium iodide
Methanaminium, N-methyl-N-methylene-, iodide (1:1)
Eschenmoser's Salt
dimethylmethylammonium iodide
MFCD00011810
Eschenmoser
N,N-dimethylmethyleneiminium iodide
N,N-dimethylmethyleneammonium iodide
(N,N-Dimethyl)methyleneammonium iodide
EINECS 251-680-2
N-Methyl-N-methylenemethanaminium iodide
dimethylmethylenimminium iodide

Chemical & Physical Properties

[ Melting Point ]:
219 °C (dec.)(lit.)

[ Molecular Formula ]:
C₃H₈IN

[ Molecular Weight ]:
185.007

[ Exact Mass ]:
184.970139

[ PSA ]:
3.01000

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2923900090

Precursor & DownStream

Precursor

Bis(dimethylamino)methane
N,N-Dimethylmethyleneiminium chloride
Trimethylsilyl iodide
N,N-dimethyl-1-trimethylsilyloxymethanamine
dimethylaminomethanol
Chloroiodomethane
Formaldehyde
Chlorotrimethylsilane
N-(Trimethylsilyl)dimethylamine
methyl iodide

DownStream

3-(dimethylamino)-1-phenylpropan-1-one
(3S)-3,7-dimethyl-2-methylideneoct-6-enal
1-(4-chlorophenyl)-3-(dimethylamino)propan-1-one
2-Nonylacrylaldehyde
Sodium iodide
gamma-Butyrolactone
Tulipalin A
3-[(dimethylamino)methyl]oxolan-2-one
1-(5-Fluoro-1H-indol-3-yl)-N,N-dimethylmethanamine

Customs

[ HS Code ]: 2923900090

[ Summary ]:
2923900090 other quaternary ammonium salts and hydroxides。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

Total synthesis and bioactivity of an unnatural enantiomer of merrilactone a: development of an enantioselective desymmetrization strategy.

J. Org. Chem. 72 , 3065, (2007)

(-)-Merrilactone A [(-)-1], isolated from Illicium merrillianum in 2000, possesses neurite outgrowth activity in cultures of fetal rat cortical neurons, and, therefore, is expected to show therapeutic...

J. Prakt. Chem./Chem.-Ztg. 336 , 91, (1994)

Chem. Abstr. 120 , 190555b, (1994)