tert-Amyl hydroperoxide

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Names

[ Name ]:
tert-Amyl hydroperoxide

[Synonym ]:
Trigonox TAHP
1,1-Dimethylpropyl hydroperoxide
t-Amyl hydroperoxide
tert-Amylhydroperoxide
tertiary amyl hydroperoxide
2-methylbutane hydroperoxide
1,1-dimethyl-propylhydroperoxid
Hydroperoxide,1,1-dimethylpropyl
tert-pentyl hydroperoxide

Chemical & Physical Properties

[ Density]:
0.905 g/cm3

[ Boiling Point ]:
144.6ºC

[ Molecular Formula ]:
C₅H₁₂O₂

[ Molecular Weight ]:
104.14800

[ Exact Mass ]:
104.08400

[ PSA ]:
29.46000

[ LogP ]:
1.66460

[ Index of Refraction ]:
1.409

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: SC3067000

CHEMICAL NAME :: tert-Pentyl hydroperoxide

CAS REGISTRY NUMBER :: 3425-61-4

BEILSTEIN REFERENCE NO. :: 1731878

LAST UPDATED :: 199712

DATA ITEMS CITED :: 8

MOLECULAR FORMULA :: C5-H12-O2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 864 mg/kg

TOXIC EFFECTS :: Behavioral - general anesthetic Kidney, Ureter, Bladder - hematuria Blood - methemoglobinemia-carboxyhemoglobin

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 22(7),51,1978

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1510 mg/m3

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - changes in lung weight Blood - methemoglobinemia-carboxyhemoglobin Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - cytochrome oxidases (including oxidative phosphorylation)

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(5),53,1981

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 225 mg/kg

TOXIC EFFECTS :: Behavioral - general anesthetic Kidney, Ureter, Bladder - hematuria Blood - methemoglobinemia-carboxyhemoglobin

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 22(7),51,1978

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 450 mg/kg

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - changes in lung weight Blood - methemoglobinemia-carboxyhemoglobin Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - cytochrome oxidases (including oxidative phosphorylation)

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(5),53,1981

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1370 mg/m3

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - changes in lung weight Blood - methemoglobinemia-carboxyhemoglobin Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - cytochrome oxidases (including oxidative phosphorylation)

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(5),53,1981

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 275 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,21,1982 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 5 mg/m3;Skin JAN 1993

Safety Information

[ HS Code ]:
2909600000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

tert-Amyl Alcohol
isopentane
1,1-DIMETHYLPROPYLMAGNESIUM CHLORIDE
Pentane
tert-Butyl Hydroperoxide
2-Methylbut-2-ene
3-Pyridinecarboxamide,4-methyl-
3-Methyl-1-butanol
Hydrogen bromide

DownStream

Propaneperoxoic acid,2,2-dimethyl-, 1,1-dimethylpropyl ester
2-Vinyloxirane
7-Ethylcamptothecin
1,1-bis(2-methylbutan-2-ylperoxy)cyclohexane
Bis(1,1-dimethylpropyl) peroxide
2,3,4,4,5,6-hexamethyl-2,6-bis(2-methylbutan-2-ylperoxy)heptane
2-methylbutan-2-ylperoxymethanol
trimethyl-[3-methyl-3-(2-methylbutan-2-ylperoxy)but-1-ynyl]silane
2-methylbutan-2-yl ethaneperoxoate
acetic acid

Customs

[ HS Code ]: 2909600000

[ Summary ]:
2909600000 alcohol peroxides, ether peroxides, ketone peroxides and their halogenated, sulphonated, nitrated or nitrosated derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Related Compounds

tert-Amyl hydroperoxide
tert-Amyl methyl ether
tert-Amyl Alcohol
tert-Amyl Alcohol
TERT-AMYL-2-FURYLCARBAMATE
tert-amyl cation
5-[1-(2,2,2-Trifluoroacetamido)cyclobutyl]piperidine-2-carboxylic acid
3-{[(Benzyloxy)carbonyl]amino}-8-methylimidazo[1,2-a]pyridine-2-carboxylic acid
1-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)spiro[2.2]pentane-1-carboxylic acid
2-[2,5-Dimethoxy-4-(2,2,2-trifluoroacetamido)phenyl]acetic acid
2-(4-{[(Benzyloxy)carbonyl]amino}-2,5-dimethoxyphenyl)acetic acid
4-Acetamido-2-hydroxypyrimidine-5-carboxylic acid
4-(4-Nitrophenyl)-3-(2,2,2-trifluoroacetamido)butanoic acid
rac-2-[(1R,2R)-2-(methoxycarbonyl)cyclohexyl]acetic acid
6-{[(9H-fluoren-9-yl)methoxy]carbonyl}-1H,4H,5H,6H,7H-pyrrolo[2,3-c]pyridine-2-carboxylic acid
3-Chloro-4,6-dimethoxy-2-{[(prop-2-en-1-yloxy)carbonyl]amino}benzoic acid

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