DIETHYL (2-OXO-2-PHENYLETHYL)PHOSPHONATE

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Names

[ CAS No. ]:
3453-00-7

[ Name ]:
DIETHYL (2-OXO-2-PHENYLETHYL)PHOSPHONATE

[Synonym ]:
Diethyl Phenacylphosphonate
Diethyl Benzoylmethylphosphonate
Diethyl phenacyl phosphonate
MFCD00015342
diethyl 2-oxo-2-phenylethyl-phosphonate
diethyl 2-oxo-2-phenylethanephosphonate
Diethyl (2-oxo-2-phenylethyl)phosphonate
Diethyl benzoylmethylphosphonate Diethyl phenacylphosphonate
(2-Oxo-2-phenylethyl)phosphonic Acid Diethyl Ester

Chemical & Physical Properties

[ Density]:
1.179 g/mL at 25ºC(lit.)

[ Boiling Point ]:
192-193ºC11 mm Hg(lit.)

[ Molecular Formula ]:
C12H17O4P

[ Molecular Weight ]:
256.23500

[ Exact Mass ]:
256.08600

[ PSA ]:
62.41000

[ LogP ]:
3.13540

[ Index of Refraction ]:
n20/D 1.513(lit.)

MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
2931900090

Synthetic Route

Precursor & DownStream

Precursor

  • phenylethynyl-phosphonic acid diethyl ester
  • Diethyl methylphosphonate
  • Benzoyl chloride
  • Diethylphosphonoacetic acid
  • Methyl benzoate
  • diethyl iodomethylphosphonate
  • 1-phenyl(trimethylsiloxy)ethylene
  • Triethyl phosphite
  • phenylene-ethylene
  • Diethyl phosphite

DownStream

  • 2-(hydroxymethyl)-1-phenylprop-2-en-1-one
  • Acrylophenone
  • diethyl 4-benzoyl-1-oxo-1-phenylpent-4-en-2-yl phosphonate
  • 3,4-dibromo-2-phenacyl-2H-furan-5-one
  • 3-(2-bromophenyl)-1-phenylprop-2-en-1-one
  • 3-Phenyl-5-(phenylmethyl)-(1H)-pyrazole
  • Diethyl benzylphosphonate
  • 1,4-diphenylpent-2-en-1-one
  • 2-diethoxyphosphoryl-1-phenylethanol
  • 1-Boc-4-(3-oxo-3-phenylpropenyl)piperidine

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

A Convenient Reagent for Aldehyde to Alkyne Homologation.

Tetrahedron Lett. 49th ed.,, 6904, (2008)

An convenient reagent for the one-carbon homologation of an aldehyde to the corresponding alkyne is reported. This reagent allows this conversion to conveniently be carried out on a large scale under ...


More Articles


Related Compounds

  • Diethyl (CBZ-aminomethyl)phosphonate
  • diethyl (2-oxo-2-phenylethyl)(phenyl)phosphoramidate
  • bis(trimethylsilyl) (2-oxo-2-phenylethyl)phosphonate
  • diethyl [2-tert-butoxycarbonylamino-1-(diethoxyphosphoryl)-2-phenylethyl]phosphonate
  • diethyl-[2-oxo-2-(4-propan-2-ylanilino)ethyl]azanium,chloride
  • diethyl-[2-oxo-2-(2,4,6-trimethylanilino)ethyl]-prop-2-ynylazanium,chloride
  • 7,7''-Bis(3,5-diethenylphenyl)tetracosahydro-3,3'(2H,7'H):7',3''(2''H)-ter-3,5,1,7-[1,2,3,4]Butanetetraylnaphthalene
  • Dicyclohexyl(2'-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-[1,1'-biphenyl]-2-yl)phosphane
  • Methyl 2-cyclopropyloxazole-5-carboxylate
  • (11bR)-N-Isopropyl-N-methyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
  • (Difluoromethyl)(4-(trifluoromethyl)phenyl)sulfane
  • Copper, tris[|I-[4-(4-bromophenyl)-3,5-dimethyl-1H-pyrazolato-|EN1:|EN2]]tri-, cyclo
  • (11bR)-2,6-Bis(2,4-dimethylphenyl)-4-hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide
  • (1S,2R)-2-(3-Chloro-4-methylphenyl)cyclopropane-1-carboxylic acid
  • (R)-2-Hydroxy-2-((3aR,5R,6R,6aR)-6-hydroxy-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)ethyl 4-methylbenzenesulfonate
  • (SP-4-1)-[29H,31H-Phthalocyanine-2,3,9,10,16,17,23,24-octolato(2-)-|EN29,|EN30,|EN31,|EN32]cobalt
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