4-Acetylbenzaldehyde

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Names

[ CAS No. ]:
3457-45-2

[ Name ]:
4-Acetylbenzaldehyde

[Synonym ]:
Benzaldehyde, 4-acetyl-
4-formyl acetophenone
methyl 4-acetylbenzaldehyde
4-ethanoylbenzaldehyde
4-acetyl-benzaldehyde
Benzaldehyde,4-acetyl
MFCD02093689
4-Acetylbenzaldehyde
4-acetylbenzealdehyde

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
286.4±23.0 °C at 760 mmHg

[ Melting Point ]:
33-36ºC(lit.)

[ Molecular Formula ]:
C9H8O2

[ Molecular Weight ]:
148.159

[ Flash Point ]:
106.6±19.6 °C

[ Exact Mass ]:
148.052429

[ PSA ]:
34.14000

[ LogP ]:
1.52

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.562

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2914400090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • carbon monoxide
  • 1-(4-Bromophenyl)ethanone
  • 1-(4-Iodophenyl)ethanone
  • 4-Acetylphenyl Trifluoromethanesulfonate
  • N-Butyl Vinyl Ether
  • 4-Bromobenzaldehyde
  • 1-(4-Hydroxymethylphenyl)ethanone
  • 4-Acetylbenzoic acid
  • Lithium formate
  • 1-(4-VINYL-PHENYL)-ETHANONE

DownStream

  • Methyl 4-acetylbenzoate
  • 1-(4-Hydroxymethylphenyl)ethanone
  • tetrahydroquinaldine
  • 3-(4-acetylphenyl)prop-2-enoic acid
  • Benzaldehyde, 4-(1-hydroxyethyl)- (9CI)
  • 4-Acetylbenzoic acid
  • P-CYANOACETOPHENONE
  • 1-(4-VINYL-PHENYL)-ETHANONE
  • 2-Phenylbenzofuran

Customs

[ HS Code ]: 2914400090

[ Summary ]:
2914400090 other ketone-alcohols and ketone-aldehydes。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Articles

Application of the combination of sodium bisulfite as a protective reagent and solid supports in the selective reduction of 4-acetylbenzaldehyde with diborane. Chihara T, et al.

Chem. Lett. 11 , 1657-1660, (1981)

Selective reduction of less reactive carbonyl groups in the presence of diborane and sodium bisulfite on silica gel. Chihara T, et al.

Can. J. Chem. 68(5) , 720-724, (1990)

Low-Pressure Hydrogenation of Arenecarboxylic Acids to Aryl Aldehydes. Gooßen LJ, et al.

Adv. Synth. Catal. 352(13) , 2166-2170, (2010)


More Articles

Related Compounds

  • 4-O-acetylbenzaldehyde oxime
  • 4-chlorooxolan-3-ol,formic acid
  • 4-Amino-2-chloro-5-(1H-tetrazol-5-yl)benzenesulfonamide
  • 4-(4-Chlorophenyl)-4-Bromopiperide
  • (4-acetyl-3,5-diacetyloxyphenyl) acetate
  • (4-chlorophenyl)-[1-(2-morpholin-4-ium-4-ylethyl)pyrrol-2-yl]methanone,chloride
  • 3-[5-Chloro-2-(difluoromethoxy)phenyl]-3-hydroxypropanenitrile
  • 1-[6-(Dimethylamino)pyridin-3-yl]-2,2-difluorocyclopropane-1-carboxylic acid
  • 3-Methyl-4-({[(prop-2-en-1-yloxy)carbonyl]amino}methyl)benzoic acid
  • 1-[2-(4-Chlorothiophen-2-yl)ethyl]cyclopropan-1-amine
  • [1-(6-Chloro-5-methylpyridin-3-yl)cyclohexyl]methanamine
  • 3-{4-chloro-7H-pyrrolo[2,3-d]pyrimidin-5-yl}butan-1-amine
  • 5-chloro-2-(3-chloroprop-1-en-2-yl)-1H-indole
  • 3-(2-Chloro-4-methylphenyl)-3-methylbutan-1-amine
  • rac-(1R,3R)-3-(4-chlorothiophen-2-yl)-2,2-dimethylcyclopropane-1-carboxylic acid
  • 4-Amino-3-(6-chloro-5-methylpyridin-3-yl)butanoic acid
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