1-Fluoro-2-iodobenzene

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Names

[ CAS No. ]:
348-52-7

[ Name ]:
1-Fluoro-2-iodobenzene

[Synonym ]:
2-Fluoroiodobenzene
1-fluor-2-oiodobenzene
O-IODO FLUOROBENZENE
O-FLUOROIODOBENZENE
2-Fluoro-1-iodobenzene
1-fluoro-2-iodo-benzen
EINECS 206-477-3
1-Fluoro-2-iodobenzene
1-Iodo-2-fluorobenzene
MFCD00001031
ortho-iodofluorobenzene
Benzene, 1-fluoro-2-iodo-
2-iodofluorobenzene

Chemical & Physical Properties

[ Density]:
1.9±0.1 g/cm3

[ Boiling Point ]:
189.3±13.0 °C at 760 mmHg

[ Melting Point ]:
−41-−40 °C(lit.)

[ Molecular Formula ]:
C6H4FI

[ Molecular Weight ]:
222.00

[ Flash Point ]:
71.1±0.0 °C

[ Exact Mass ]:
221.934158

[ LogP ]:
3.21

[ Vapour Pressure ]:
0.8±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.592

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302-H315-H318

[ Precautionary Statements ]:
P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S39-S61-S37/39

[ RIDADR ]:
UN3082 - class 9 - PG 3 - DOT NA1993 - Environmentally hazardous substances, liquid, n.o.s. HI: all (not BR)

[ WGK Germany ]:
2

[ HS Code ]:
2903999090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2-Fluoroaniline
  • o-potassiofluorobenzene
  • bis(2-fluorophenyl)iodonium tetrafluoroborate
  • Sodium trifluoromethanesulphinate
  • 1-Bromo-2-fluorobenzene
  • Fluorobenzene
  • Phenol
  • Hydrochloric acid
  • Carbon tetrachloride

DownStream

  • 2-Fluorophenol
  • 2-Fluorobenzophenone
  • Ethyl 2-fluorobenzoate
  • 2-Fluorostyrene
  • 1-(5,5-Dimethyl-1,3,2-dioxaborinan-2-yl)-2-fluorobenzene
  • 2-Fluoroaniline
  • METHYL 2-FLUOROBENZOATE
  • 2-Fluorobiphenyl
  • Biphenyl
  • ortho-terphenyl

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Design, synthesis and structure-activity relationship of novel RXR-selective modulators.

Bioorg. Med. Chem. Lett. 14(6) , 1593-8, (2004)

The synthesis and in vitro characterization of novel RXR-selective ligands possessing various substituted 1-benzofuran or 1-benzothiophene moieties are described.

Long-range proton-fluorine spin-spin coupling in bridged biphenyls. Compelling evidence for a" through-space"(" direct") mechanism. Gribble GW and Douglas Jr JR.

J. Am. Chem. Soc. 92(19) , 5764-65, (1970)

New chiral sulfoxide ligands possessing a phosphano or phosphanoamino functionality in palladium-catalyzed asymmetric allylic nucleophilic substitution reactions. Hiroi K, et al.

Tetrahedron 56(27) , 4701-10, (2000)


More Articles

Related Compounds

  • 4-Bromo-1-fluoro-2-iodobenzene
  • 4-Chloro-1-fluoro-2-iodobenzene
  • 4-(bromomethyl)-1-fluoro-2-iodobenzene
  • 4-(Chloromethyl)-1-fluoro-2-iodobenzene
  • 4-(Dimethoxymethyl)-1-fluoro-2-iodobenzene
  • 1-fluoro-2-iodo-4-nitrobenzene
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • 3-[2-(3-{[(6-tert-butylpyridazin-3-yl)oxy]methyl}pyrrolidin-1-yl)-2-oxoethyl]-7-methyl-2H,3H,5H-[1,3]thiazolo[3,2-a]pyrimidin-5-one
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • 2-methyl-4-{4-[(2-methyl-1,3-thiazol-4-yl)methyl]piperazin-1-yl}-6-(1H-pyrazol-1-yl)pyrimidine
  • tert-Butyl-DL-alanine