Tert-butyl (triphenylphosphoranylidene)acetate

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Names

[ CAS No. ]:
35000-38-5

[ Name ]:
Tert-butyl (triphenylphosphoranylidene)acetate

[Synonym ]:
2-Methyl-2-propanyl (triphenylphosphoranylidene)acetate
tert-Butyl 2-(triphenylphosphoranylidene)acetate
1,1-Dimethylethyl 2-(triphenylphosphoranylidene)acetate
Triphenylphoranylidene
(tert-Butoxycarbonylmethylene)triphenylphosphorane
tert-Butyl (triphenyl-λ5-phosphanylidene)acetate
EINECS 412-880-7
Acetic acid, 2-(triphenylphosphoranylidene)-, 1,1-dimethylethyl ester
1X1&1&OV1UPR&R&R
MFCD00075545
Tert-butyl (triphenylphosphoranylidene)acetate

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
503.5±33.0 °C at 760 mmHg

[ Melting Point ]:
152-155 °C(lit.)

[ Molecular Formula ]:
C24H25O2P

[ Molecular Weight ]:
376.428

[ Flash Point ]:
271.4±45.7 °C

[ Exact Mass ]:
376.159210

[ PSA ]:
36.11000

[ LogP ]:
4.91

[ Vapour Pressure ]:
0.0±1.3 mmHg at 25°C

[ Index of Refraction ]:
1.588

[ Storage condition ]:
Refrigerator (+4°C)

MSDS

Safety Information

[ Symbol ]:

GHS06, GHS08, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H317-H319-H373-H411

[ Precautionary Statements ]:
P273-P280-P301 + P310-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges

[ Hazard Codes ]:
T:Toxic;N:Dangerousfortheenvironment;

[ Risk Phrases ]:
R25;R36;R43;R48/22;R51/53

[ Safety Phrases ]:
S26-S36/37/39-S45-S61

[ RIDADR ]:
UN 3464 6.1/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1

Articles

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Phosphorus. Sulfur. Silicon Relat. Elem. 67 , 311, (1992)

Elemental selenium generated by the photobleaching of selenomerocyanine dyes forms conjugates with serum albumin and serum lipoproteins that are toxic to leukemia and selected solid tumor cells but we...

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J. Med. Chem. 47 , 3615-3628, (2004)

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J. Med. Chem. 35 , 2155, (1992)

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Related Compounds

  • tert-butyl (triphenylphosphoranylidene)acetate
  • TERT-BUTYL(TRIPHENYLPHOSPHORANYLIDENE)ACETATE
  • tert-Butyl (triphenylphosphoranylidene)carbamate
  • tert-butyl acetate-d12
  • tert-Butyl acetate
  • 2-tert-Butoxy-2-oxoethylzinc chloride
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-{3-[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)ethoxy]propanoyl}-2-methylpiperidine-4-carboxylic acid
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-(But-3-yn-1-yl)-2-methyl-1,3-thiazole