2-Bromo-5-picoline

Suppliers

Names

[ CAS No. ]:
3510-66-5

[ Name ]:
2-Bromo-5-picoline

[Synonym ]:
MFCD00209553
2-Bromo-5-methylpyridine
Pyridine,2-bromo-5-methyl
5-methyl-2-bromo-pyridine
2-bromopicoline
3-methyl-6-pyridyl bromide
2-Bromo-5-Methyl Pyridine
6-Bromo-3-picoline
2-Bromo-5-picoline
Pyridine, 2-bromo-5-methyl-
2-brom-5-methylpyridin

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
218.7±20.0 °C at 760 mmHg

[ Melting Point ]:
41-43 °C(lit.)

[ Molecular Formula ]:
C6H6BrN

[ Molecular Weight ]:
172.02

[ Flash Point ]:
86.1±21.8 °C

[ Exact Mass ]:
170.968353

[ PSA ]:
12.89000

[ LogP ]:
1.99

[ Vapour Pressure ]:
0.2±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.553

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn:Harmful

[ Risk Phrases ]:
R20/21/22;R36/37/38

[ Safety Phrases ]:
S26-S37/39-S36/37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2933399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2-Amino-5-methylpyridine
  • 3-Mepy
  • 2-Hydroxy-5-picoline
  • 3-picolinium-BF3 adduct
  • 2,5-Dibromopyridine
  • methyl iodide
  • 6-Hydroxy-3-methylpicolinic acid
  • 5-METHYL-2-OXO-2H-PYRAN-6-CARBOXYLIC ACID

DownStream

  • 5-METHYL-[2,4']-BIPYRIDINE
  • Xeglyze
  • 6,6'-Dimethyl-2,2'-bipyridine
  • 5,6'-dimethyl-2,2'-bipyridine
  • Ethyl 5-methylpicolinate
  • 6-Hydroxynicotinic acid
  • 5-Methylpicolinic acid
  • 5-Methylpicolinaldehyde
  • 5,5′-dicarboxy-2,2′-bipyridine
  • 2-BROMO-5-METHYLPYRIDINE 1-OXIDE

Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

High yield synthesis of 5, 5'-dimethyl-2, 2'-bipyridine and 5, 5 ?-dimethyl-2, 2': 6', 2 ?-terpyridine and some bisfunctionalization reactions using N-bromosuccinimide. Schubert US, et al.

Synthesis 1999(5) , 779-82, (1999)

Synthesis of two covalently linked bis (2, 2': 6', 2''-terpyridine)(terpy) chelating ligands with different length spacers, comparison of the crystal structures of their mononuclear nickel (II) complexes, and kinetic and mechanistic studies of the reaction of one ligand with [Fe (terpy) 2] 2+. Priimov GU, et al.

J. Chem. Soc., Dalton Trans. 4 , 445-49, (2000)

Synthesis of a novel ditopic ligand incorporating directly bonded 1, 10-phenanthroline and 2, 2': 6', 2 ?-terpyridine units. Gaviña P and Tatay S.

Tetrahedron Lett. 47(20) , 3471-73, (2006)


More Articles

Related Compounds

  • 2-Bromo-5-picoline
  • 2-Bromo-5-iodo-4-picoline
  • 2-Bromo-5-nitro-4-picoline
  • 2-Bromo-5-nitro-6-picoline
  • 2-Bromo-5-nitro-3-picoline
  • 2-Bromo-5-fluoro-3-picoline
  • [2-Methoxy-4-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-benzyl]-carbamic acid tert-butyl ester
  • 2-(2-Bromo-4-nitro-phenoxy)-ethylamine hydrochloride
  • 1-Ethoxy-2-ethynyl-4-trifluoromethyl-benzene
  • C-(3-Bromo-5-fluoro-phenyl)-C-phenyl-methylamine hydrochloride
  • 3-(3-Bromo-phenoxymethyl)-azetidine hydrochloride
  • 3-m-Tolyloxymethyl-azetidine hydrochloride
  • 4-(Azetidin-3-ylmethoxy)-3-chloro-phenylamine hydrochloride
  • 2-(2-Chloro-4-nitro-phenoxy)-ethylamine hydrochloride
  • (2-Bromo-5-nitro-benzyl)-cyclopropyl-amine
  • N,N-Diethyl-4-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-2-trifluoromethyl-benzamide
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