4-Fluorotoluene

Suppliers

Names

[ CAS No. ]:
352-32-9

[ Name ]:
4-Fluorotoluene

[Synonym ]:
Benzene, 1-fluoro-4-methyl-
4-fluoro-1-methylbenzene
MFCD00000358
p-tolyl fluoride
para-Fluorotoluene
PARA FLUORO TOLUENE
P-FLUOROTOLUENE
Toluene, p-fluoro-
1-Methyl-4-fluorobenzene
4-Fluorotoluene
1-Fluoro-4-methylbenzene
1-Fluoro-4-methyl-benzene
p-Fluortoluol
p-fluoro-toluen
Fluorotoluene3
toluene,p-fluoro
EINECS 206-520-6
4-methylfluorobenzene
TOLUENE, 4-FLUORO-

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
117.0±9.0 °C at 760 mmHg

[ Melting Point ]:
−56 °C(lit.)

[ Molecular Formula ]:
C₇H₇F

[ Molecular Weight ]:
110.129

[ Flash Point ]:
17.2±0.0 °C

[ Exact Mass ]:
110.053177

[ LogP ]:
2.73

[ Vapour Pressure ]:
21.1±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.477

[ Water Solubility ]:
immiscible

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: XT2580000

CHEMICAL NAME :: Toluene, p-fluoro-

CAS REGISTRY NUMBER :: 352-32-9

BEILSTEIN REFERENCE NO. :: 1362373

LAST UPDATED :: 199710

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C7-H7-F

MOLECULAR WEIGHT :: 110.14

WISWESSER LINE NOTATION :: FR D

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Parenteral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 11FYAN "Fluorine Chemistry, Volume III. Biological Effects of Organic Fluorides," Simons, J.H., ed., New York, Academic Press, Inc., 1963 Volume(issue)/page/year: 3,91,1963

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H302-H312-H315-H319-H332

[ Precautionary Statements ]:
P210-P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F:Flammable;Xi:Irritant;

[ Risk Phrases ]:
R11;R36/37/38

[ Safety Phrases ]:
S7-S16-S36/37-S37/39-S26

[ RIDADR ]:
UN 2388 3/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
XT2580000

[ Packaging Group ]:
II

[ Hazard Class ]:
3

[ HS Code ]:
2942000000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

p-Toluidine
Benzene,1-methyl-4-(trimethylsilyl)-
trimethyl-(4-methylphenyl)stannane
triethoxy-p-tolylsilane 97
3,3-diethyl-1-(4-methylphenyl)-1-triazene
4-Fluorobenzyl bromide
p-Fluorobenzotrifluoride
Diisobutylaluminium hydride
Benzaldehyde
4-Fluorobenzyl chloride

DownStream

2-Methoxy-5-(trifluoromethyl)aniline
4-Fluoro-3-nitrobenzotrifluoride
1,2-Bis(4-fluorophenyl)ethanone
1-Methoxy-2-nitro-4-(trifluoromethyl)benzene
Benzenamine,4-(4-methylphenoxy)-
2-Fluoro-5-(trifluoromethyl)aniline
2-Fluoro-5-methylbenzoic acid
4-(P-TOLYLOXY)BENZONITRILE
4-Phenyltoluene
4-Ethylbiphenyl

Preparation

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Related Compounds

4-Fluorotoluene-α-d1
3-Cyano-4-fluorotoluene
3-Amino-4-fluorotoluene
2-cyano-4-fluorotoluene
2-Amino-4-fluorotoluene
2-Bromo-4-fluorotoluene
2-[(2,4-Difluoro-6-methoxyphenoxy)methyl]oxirane
(S)-5-Fluoro-2-(oxiran-2-ylmethoxy)benzaldehyde
1-(4-Tert-butyl-3-hydroxy-phenyl)-ethanone
3-(3-Fluoro-4-trifluoromethoxy-phenyl)-propionaldehyde
1-(6-Azidomethylpyridin-2-yl)pyrrolidin-2-one
Methyl I(2)-amino-3-cyclohexene-1-propanoate
N-methoxy-N-methyl-3-(trifluoromethoxy)benzamide
1-[(1-Benzofuran-5-yl)methyl]cyclopropan-1-amine
Methyl 2-(2-oxoimidazolidin-1-yl)acetate
cis-1-[(Benzyloxy)carbonyl]-5-{[(tert-butoxy)carbonyl]amino}piperidine-3-carboxylic acid

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