4-Fluorotoluene

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Names

[ CAS No. ]:
352-32-9

[ Name ]:
4-Fluorotoluene

[Synonym ]:
Benzene, 1-fluoro-4-methyl-
4-fluoro-1-methylbenzene
MFCD00000358
p-tolyl fluoride
para-Fluorotoluene
PARA FLUORO TOLUENE
P-FLUOROTOLUENE
Toluene, p-fluoro-
1-Methyl-4-fluorobenzene
4-Fluorotoluene
1-Fluoro-4-methylbenzene
1-Fluoro-4-methyl-benzene
p-Fluortoluol
p-fluoro-toluen
Fluorotoluene3
toluene,p-fluoro
EINECS 206-520-6
4-methylfluorobenzene
TOLUENE, 4-FLUORO-

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
117.0±9.0 °C at 760 mmHg

[ Melting Point ]:
−56 °C(lit.)

[ Molecular Formula ]:
C7H7F

[ Molecular Weight ]:
110.129

[ Flash Point ]:
17.2±0.0 °C

[ Exact Mass ]:
110.053177

[ LogP ]:
2.73

[ Vapour Pressure ]:
21.1±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.477

[ Water Solubility ]:
immiscible

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
XT2580000
CHEMICAL NAME :
Toluene, p-fluoro-
CAS REGISTRY NUMBER :
352-32-9
BEILSTEIN REFERENCE NO. :
1362373
LAST UPDATED :
199710
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C7-H7-F
MOLECULAR WEIGHT :
110.14
WISWESSER LINE NOTATION :
FR D

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Parenteral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
11FYAN "Fluorine Chemistry, Volume III. Biological Effects of Organic Fluorides," Simons, J.H., ed., New York, Academic Press, Inc., 1963 Volume(issue)/page/year: 3,91,1963

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H302-H312-H315-H319-H332

[ Precautionary Statements ]:
P210-P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F:Flammable;Xi:Irritant;

[ Risk Phrases ]:
R11;R36/37/38

[ Safety Phrases ]:
S7-S16-S36/37-S37/39-S26

[ RIDADR ]:
UN 2388 3/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
XT2580000

[ Packaging Group ]:
II

[ Hazard Class ]:
3

[ HS Code ]:
2942000000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • p-Toluidine
  • Benzene,1-methyl-4-(trimethylsilyl)-
  • trimethyl-(4-methylphenyl)stannane
  • triethoxy-p-tolylsilane 97
  • 3,3-diethyl-1-(4-methylphenyl)-1-triazene
  • 4-Fluorobenzyl bromide
  • p-Fluorobenzotrifluoride
  • Diisobutylaluminium hydride
  • Benzaldehyde
  • 4-Fluorobenzyl chloride

DownStream

  • 2-Methoxy-5-(trifluoromethyl)aniline
  • 4-Fluoro-3-nitrobenzotrifluoride
  • 1,2-Bis(4-fluorophenyl)ethanone
  • 1-Methoxy-2-nitro-4-(trifluoromethyl)benzene
  • Benzenamine,4-(4-methylphenoxy)-
  • 2-Fluoro-5-(trifluoromethyl)aniline
  • 2-Fluoro-5-methylbenzoic acid
  • 4-(P-TOLYLOXY)BENZONITRILE
  • 4-Phenyltoluene
  • 4-Ethylbiphenyl

Preparation


Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Related Compounds

  • 4-Fluorotoluene-α-d1
  • 3-Cyano-4-fluorotoluene
  • 3-Amino-4-fluorotoluene
  • 2-cyano-4-fluorotoluene
  • 2-Amino-4-fluorotoluene
  • 2-Bromo-4-fluorotoluene
  • 3-O-I+/--D-Glucopyranuronosyl-D-xylose
  • 3-(3-Butoxyphenoxy)-1,2-propanediol
  • N-Cyclohexyl-L-leucine methyl ester
  • 1-(1-Ethylcyclobutyl)-2,2-dimethylcyclopropan-1-amine
  • 3-[[5-[[3-Bromo-5-ethoxy-4-(2-ethoxy-2-oxoethoxy)phenyl]methylene]-3-methyl-4-oxo-2-thiazolidinylidene]amino]benzoic acid
  • Carbamic acid, pentyl-, I+/--ester with 2,2-dichloro-N-[I(2)-hydroxy-I+/--(hydroxymethyl)-p-nitrophenethyl]acetamide, D-threo-(-)-
  • 1-Oxa-3,9-diazaspiro[5.5]undecan-2-one, 5-butyl-9-(4-methyl-4-piperidinyl)-3-[2-(tetrahydro-2H-pyran-4-yl)ethyl]-, (5S)-
  • Benzenesulfonic acid, 3,3a(2)-[(2-chloro-5-ethyl-3,6-dioxo-1,4-cyclohexadiene-1,4-diyl)diimino]bis[6-[(2-aminoethyl)amino]-
  • 1-[(2-Chloro-4-fluorophenyl)methyl]-4-piperidinecarboxylic acid 2-[[3-[(2-thienylcarbonyl)oxy]phenyl]methylene]hydrazide
  • Ethyl 2-[[(hexahydro-2,5-methanopentalen-3a(1H)-yl)carbonyl]amino]-4,5,6,7-tetrahydrothieno[3,2-c]pyridine-3-carboxylate
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