4-Fluoroiodobenzene

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Names

[ CAS No. ]:
352-34-1

[ Name ]:
4-Fluoroiodobenzene

[Synonym ]:
Benzene,1-fluoro-4-iodo
p-Iodofluorobenzene
p-Fluoroiodobenzene
1-iodo-4-fluorobenzene
4-fluoro iodobenzene
1-Fluoro-4-iodobenzene
4-fluoro-1-iodobenzene
Benzene, 1-fluoro-4-iodo-
4-Fluoroiodobenzene
MFCD00001052
4-Iodofluorobenzene
1-iodo-4-fluorophenyl
para-iodofluorobenzene
para-fluoroiodobenzene
EINECS 206-522-7

Chemical & Physical Properties

[ Density]:
1.9±0.1 g/cm3

[ Boiling Point ]:
183.7±13.0 °C at 760 mmHg

[ Melting Point ]:
−20 °C(lit.)

[ Molecular Formula ]:
C₆H₄FI

[ Molecular Weight ]:
221.999

[ Flash Point ]:
68.3±0.0 °C

[ Exact Mass ]:
221.934158

[ LogP ]:
3.23

[ Vapour Pressure ]:
1.0±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.592

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S37/39-S2637/39

[ RIDADR ]:
UN2810

[ WGK Germany ]:
3

[ HS Code ]:
2903999090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

4-Fluorobenzeneboronic acid
Fluorobenzene
N-ethyl-N-[(4-iodophenyl)diazenyl]ethanamine
1-Bromo-4-fluorobenzene
sodium chloride
4-IODOPHENYLBORONIC ACID PINACOL ESTER
4-Iodoaniline
p-Iodobenzeneboronic acid
4-Fluorophenylmagnesium bromide

DownStream

1-(4-fluorophenyl)-3-(1-methyl-3,6-dihydro-2H-pyridin-4-yl)-5-nitroindole
4'-Fluoro-3-biphenylol
4'-Fluoro-4-biphenylol
2-(4-fluorophenyl)phenol
3-(4-fluorophenyl)benzonitrile
6-(4-fluorophenyl)-pyridine-3-carboxylic acid methyl ester
methyl 2-(4-fluorophenyl)pyridine-3-carboxylate
4-Fluorophenyl methyl sulfone
1-Fluoro-4-phenoxybenzene
4-Bromo-4'-fluorobiphenyl

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Automated radiosynthesis of no-carrier-added 4-[18F]fluoroiodobenzene: a versatile building block in 18F radiochemistry.

J. Labelled Comp. Radiopharm. 57(2) , 104-9, (2014)

4-[18F]Fluoroiodobenzene ([18F]FIB) is a versatile building block in 18F radiochemistry used in various transition metal-mediated C-C and C-N cross-coupling reactions and [18F]fluoroarylation reaction...

Palladium-catalyzed carbopalladation and carbocyclization of arynes with aryl halides: a highly efficient route to functionalized triphenylenes.

Chem. Commun. (Camb.) (8) , 894-6, (2006)

Highly substituted triphenylene derivatives were prepared in good yields via the palladium-catalyzed carbocyclization of arynes with aryl iodides.

The effect of N-heterocyclic carbene ligands in the palladium-catalyzed cross-coupling reaction of K [C6F5BF3] with aryl iodides and aryl bromides. Adonin NY, et al.

Tetrahedron 64(25) , 5920-4, (2008)

2-Bromo-4-fluoroiodobenzene
3-Bromo-4-fluoroiodobenzene
3-chloro-4-fluoroiodobenzene
2-CHLORO-4-FLUOROIODOBENZENE
2,6-dibromo-4-fluoroiodobenzene
2,5-Dibromo-4-fluoroiodobenzene
3-((6-methylpyridazin-3-yl)oxy)-N-(4-(2-methylthiazol-4-yl)phenyl)benzamide
N-(4-carbamoylphenyl)pyrimidine-2-carboxamide
(4-(4-Methoxyphenyl)piperazin-1-yl)(pyrimidin-2-yl)methanone
N-phenethylpyrimidine-2-carboxamide
N-(4-sulfamoylphenethyl)pyrimidine-2-carboxamide
N-(3,4-dimethoxyphenethyl)pyrimidine-2-carboxamide
N-[2-(trifluoromethyl)phenyl]pyrimidine-2-carboxamide
4-(2-Bromopyridin-3-yl)-4,5-dihydropyrrolo[1,2-a]quinoxaline
N-(2,4-difluorophenyl)pyrimidine-2-carboxamide
N-(pyridin-4-yl)pyrimidine-2-carboxamide

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