(R)-(+)-2-(FLUORODIPHENYLMETHYL)PYRROLI&

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Names

[ CAS No. ]:
352535-00-3

[ Name ]:
(R)-(+)-2-(FLUORODIPHENYLMETHYL)PYRROLI&

[Synonym ]:
Pyrrolidine,2-(fluorodiphenylmethyl)-,(2R)
(R)-2-(fluorodiphenylmethyl)pyrrolidine
I11-1028

Chemical & Physical Properties

[ Density]:
1.098g/cm3

[ Boiling Point ]:
366.7ºC at 760mmHg

[ Molecular Formula ]:
C17H18FN

[ Molecular Weight ]:
255.33000

[ Flash Point ]:
175.6ºC

[ Exact Mass ]:
255.14200

[ PSA ]:
12.03000

[ LogP ]:
3.98050

[ Index of Refraction ]:
n20/D 1.577(lit.)

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NA 1993 / PGIII

[ HS Code ]:
2933990090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • (R)-(+)-2-(Diphenylhydroxymethyl)pyrrolidine

DownStream

Customs

[ HS Code ]: 2933990090

[ Summary ]:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Fluorinated organocatalysts for the enantioselective epoxidation of enals: molecular preorganisation by the fluorine-iminium ion gauche effect.

Chemistry 36th ed., 18 , 11334-11342, (2012)

The fluorine-iminium ion gauche effect is triggered upon union of a secondary β-fluoroamine and an α,β-unsaturated aldehyde, providing a useful strategy for controlling the molecular topology of inter...

Zimmer, L. E.; et al.

Angew. Chem. Int. Ed. Engl. 123 , 12062-12074, (2011)

O'Hagan, D.; et al.

Tetrahedron Asymmetry 11 , 2033-2036, (2000)


More Articles

Related Compounds

  • (R)-(+)-2-hydroxy-2-phenylethyl p-tolyl sulfide
  • (R)-(+)-2-pentylsuccinic acid
  • R-(+)-2-chloropropionic acid
  • (R)-(+)-2-hydroxy-1-phenyl-1-pentan-1-one
  • (R)-(+)-2-BROMOPROPIONIC ACID
  • R(+)-2-CHLOROPROPIONIC ACID
  • 1-(4-methoxyphenyl)-2-[2-(4-methoxyphenyl)ethyl]-6,7-dimethyl-4a,5,6,7,8,8a-hexahydro-1H-chromeno[2,3-c]pyrrole-3,9-dione
  • (2-Chloro-4-(ethylcarbamoyl)phenyl)boronic acid
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  • (2-Fluoro-3-((2-fluorophenyl)carbamoyl)phenyl)boronic acid
  • 2-[2-(4-methoxyphenyl)ethyl]-6,7-dimethyl-1-phenyl-4a,5,6,7,8,8a-hexahydro-1H-chromeno[2,3-c]pyrrole-3,9-dione
  • (4-Oxo-6-propyl-3-pyridin-2-yl-4a,5,6,7,8,8a-hexahydrochromen-7-yl) 2-[(2-methylpropan-2-yl)oxycarbonylamino]acetate
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