fluorotribromomethane

Suppliers

Names

[ CAS No. ]:
353-54-8

[ Name ]:
fluorotribromomethane

[Synonym ]:
Methane,tribromofluoro
Tribrom-fluor-methan
EINECS 206-535-8
MFCD00000366
Fluorotribromomethane
TribroMofluoroMethane

Chemical & Physical Properties

[ Density]:
2.765 g/mL at 25 °C(lit.)

[ Boiling Point ]:
106-107 °C(lit.)

[ Melting Point ]:
−73.6 °C(lit.)

[ Molecular Formula ]:
CBr3F

[ Molecular Weight ]:
270.72100

[ Flash Point ]:
106-107°C

[ Exact Mass ]:
267.75300

[ LogP ]:
2.75190

[ Index of Refraction ]:
n20/D 1.525(lit.)

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
UN 3082 9 / PGIII

[ WGK Germany ]:
3

[ HS Code ]:
2903799090

Synthetic Route

Precursor & DownStream

Precursor

  • Tetrabromomethane
  • Trifluorostibine
  • Bromine trifluoride
  • [dibromo(fluoro)methyl]-triphenylphosphanium,bromide
  • iodide pentafluoride
  • Fluorotrichloromethane

DownStream

  • triflic anhydride
  • fluoroformyl trifluoromethanesulfonate
  • Bromine
  • carbonyl bromide fluoride
  • bromofluorocarbene
  • dibromo(fluoro)methane
  • SULFUR DIOXIDE
  • (1,3,3-tribromo-3-fluoropropyl)benzene
  • 1,1,3-tribromo-1-fluoroheptane

Customs

[ HS Code ]: 2903799090

[ Summary ]:
2903799090 halogenated derivatives of acyclic hydrocarbons containing two or more different halogens。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Articles

Generation and carbonyl addition reactions of dibromofluoromethyllithium derived from tribromofluoromethane as applied to the stereoselective synthesis of fluoro olefins and 2-bromo-2-fluoro-1, 3-alkanediols. Shimizu M, et al.

Bull. Chem. Soc. Jpn. 71 , 2903-2921, (1998)


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