2-Methyl-3,5-dinitroaniline

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Names

[ CAS No. ]:
35572-78-2

[ Name ]:
2-Methyl-3,5-dinitroaniline

[Synonym ]:
MFCD00024526
2-Amino-1-methyl-4,6-dinitrobenzene
3,5-Dinitro-o-toluidine
2-Methyl-3,5-dinitro-phenylamine
3,5-dinitro-2-methylaniline
Benzenamine, 2-methyl-3,5-dinitro-
2-Adnt
Benzenamine,2-methyl-3,5-dinitro
o-Toluidine,3,5-dinitro
2-Methyl-3,5-dinitroaniline
2-AMINO-4,6-DINITROTOLUENE
4-amino-2,6-dinitrotoluene
2-Methyl-3,5-dinitrobenzenamine
2-amino-dinitrotoluene

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
405.7±40.0 °C at 760 mmHg

[ Molecular Formula ]:
C7H7N3O4

[ Molecular Weight ]:
197.148

[ Flash Point ]:
199.2±27.3 °C

[ Exact Mass ]:
197.043655

[ PSA ]:
117.66000

[ LogP ]:
2.20

[ Vapour Pressure ]:
0.0±0.9 mmHg at 25°C

[ Index of Refraction ]:
1.656

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
XU6090000
CHEMICAL NAME :
o-Toluidine, 3,5-dinitro-
CAS REGISTRY NUMBER :
35572-78-2
BEILSTEIN REFERENCE NO. :
2377515
LAST UPDATED :
199707
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C7-H7-N3-O4
MOLECULAR WEIGHT :
197.17
WISWESSER LINE NOTATION :
WNR CZ B1 ENW

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1394 mg/kg
TOXIC EFFECTS :
Behavioral - excitement Behavioral - somnolence (general depressed activity)
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1522 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity)

MUTATION DATA

TYPE OF TEST :
Mutation in microorganisms
TEST SYSTEM :
Bacteria - Salmonella typhimurium
DOSE/DURATION :
10 ug/plate
REFERENCE :
ENMUDM Environmental Mutagenesis. (New York, NY) V.1-9, 1979-87. For publisher information, see EMMUEG. Volume(issue)/page/year: 4,163,1982

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H302 + H312 + H332-H319

[ Precautionary Statements ]:
P210-P280-P305 + P351 + P338

[ Hazard Codes ]:
Xi,T,F

[ Risk Phrases ]:
11-23/24/25-36/37/38

[ Safety Phrases ]:
16-27-45-36/37-26-61-28

[ RIDADR ]:
UN 1648 3/PG 2

[ HS Code ]:
2921430090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2,4,6-trinitrotoluene
  • Iron
  • Sulfuric acid
  • 3,5-Dinitro-2-methylbenzoic acid
  • Sulfur trioxide
  • 2-Methylbenzoic acid
  • 2-methyl-3,5-dinitrobenzoyl chloride
  • Dinitolmide
  • Ethyl 2-methyl-3,5-dinitrobenzoate

DownStream

  • Pentanitroaniline
  • Propanamide, 2-oxo-
  • Pyruvic acid
  • Glyoxylic acid
  • s-Triaminotrinitrobenzene
  • 2,4-Dinitrotoluene
  • N-ACETYL-2-METHYL-3,5-DINITROANILINE
  • 1-methyl-2,3,4,5,6-pentanitrobenzene
  • 3,5-Diamino-2,4,6-trinitrotoluene

Customs

[ HS Code ]: 2921430090

[ Summary ]:
HS:2921430090 toluidines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

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Related Compounds

  • N-ACETYL-2-METHYL-3,5-DINITROANILINE
  • 2-methyl-3,5-diphenylbenzene-1,4-diol
  • 2-methyl-3-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]methyl]quinazolin-4-one
  • 2-methyl-3,5-diphenyl-oxazolidin-4-one
  • 2-methyl-3,5,6,7-tetrahydro-2H-cyclopenta[b]pyran-4-one
  • 2-methyl-3,5-diphenyl-3,4-dihydropyrazol-4-ol