Tris[N,N-bis(trimethylsilyl)amide]gadolinium(III)
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Names
[ CAS No. ]:
35789-03-8
[ Name ]:
Tris[N,N-bis(trimethylsilyl)amide]gadolinium(III)
[Synonym ]:
MFCD03427091
Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, gadolinium salt (3:1)
Gadolinium tris(1,1,1,3,3,3-hexamethyldisilazan-2-ide)
Chemical & Physical Properties
[ Boiling Point ]:
126ºC at 760 mmHg
[ Melting Point ]:
67-90ºC(lit.)
[ Molecular Formula ]:
C18H54GdN3Si6
[ Molecular Weight ]:
638.404
[ Flash Point ]:
36 °F
[ Exact Mass ]:
638.217407
[ PSA ]:
9.72000
[ LogP ]:
7.26750
Safety Information
[ Symbol ]:
GHS02, GHS05
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H228-H261-H314
[ Supplemental HS ]:
Reacts violently with water.
[ Precautionary Statements ]:
P210-P231 + P232-P280-P305 + P351 + P338-P310-P422
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
[ Hazard Codes ]:
F: Flammable;C: Corrosive;
[ Risk Phrases ]:
11-14/15-34
[ Safety Phrases ]:
16-26-36/37/39-43-45-7/8
[ RIDADR ]:
UN 3396 4.3/PG 2
[ Packaging Group ]:
III
[ Hazard Class ]:
4.1
Articles
J. Colloid. Interface Sci. 356(1) , 298-302, (2011)
The surface free energy of a solid determines its surface and interfacial behavior in processes like wetting and adhesion which is crucial for silica aerogels in case of organic liquid absorption and ...
Chem. Commun. (Camb.) 47(38) , 10761-3, (2011)
A silica microsphere suspension and a silica sol are employed in a two-step dipping process for the preparation of a superhydrophobic surface. It's not only a facile way to achieve the lotus effect, b...
Macromol. Biosci. 9(4) , 369-75, (2009)
Trimethylsilylation of cellulose in different 1,3-dialkylimidazolium ionic liquids (IL) with hexamethyldisilazane (HMDS) as a silylating agent was investigated. Trimethylsilyl (TMSi) cellulose with a ...