2,3-Dimethoxy-1,3-butadiene

Names

[ Name ]:
2,3-Dimethoxy-1,3-butadiene

[Synonym ]:
2,3-Dimethoxy-1,3-butadiene
2,3-Dimethoxy-1,3-diene
MFCD00010229
2,3-Dimethoxybuta-1,3-Diene
1,3-Butadiene, 2,3-dimethoxy-
2,3-dimethoxybutadiene
2,3-Dimethoxybutadien

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
151.0±23.0 °C at 760 mmHg

[ Melting Point ]:
19ºC

[ Molecular Formula ]:
C₆H₁₀O₂

[ Molecular Weight ]:
114.142

[ Flash Point ]:
32.8±0.0 °C

[ Exact Mass ]:
114.068077

[ PSA ]:
18.46000

[ LogP ]:
1.05

[ Vapour Pressure ]:
4.8±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.413

MSDS

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Risk Phrases ]:
R10

[ Safety Phrases ]:
S16-S33

[ RIDADR ]:
UN 1993

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

[ HS Code ]:
2909199090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

5-hydroxy-2-methoxypent-1-en-3-one
3,4-Dimethoxythiophene
butane-2,3-dione
Dimethyl oxalate
METHYL 2-METHOXYACRYLATE
3-Methoxy-3-(1-methoxyethenyl)-1,2-dioxolane
hydroperoxy(methoxy)methane

Customs

[ HS Code ]: 2909199090

[ Summary ]:
2909199090. other acyclic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

Diels-Alder chemistry of graphite and graphene: graphene as diene and dienophile.

J. Am. Chem. Soc. 133(10) , 3324-7, (2011)

The zero-band-gap electronic structure of graphene enables it to function as either the diene or the dienophile in the Diels-Alder reaction, and this versatile synthetic method offers a powerful strat...

3-nitrocoumarins as dienophiles in the Diels-Alder reaction in water. An approach to the synthesis of nitrotetrahydrobenzo[c]chromenones and dihydrodibenzo[b,d]furans.

J. Org. Chem. 68(24) , 9263-8, (2003)

The [4 + 2] cycloadditions of 3-nitrocoumarin (1a), 6-chloro-3-nitrocoumarin (1b), and 6-, 7-, and 8-hydroxy-3-nitrocoumarins (1c, 5, and 6) with (E)-piperylene (7), isoprene (8), 2,3-dimethyl-1,3-but...

Organic chemistry of graphene: the Diels-Alder reaction.

Chemistry 19(46) , 15719-25, (2013)

Herein, by using dispersion-corrected density functional theory, we investigated the Diels-Alder chemistry of pristine and defective graphene. Three dienes were considered, namely 2,3-dimethoxy-1,3-bu...