L(-)-Camphorsulfonic acid

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Names

[ CAS No. ]:
35963-20-3

[ Name ]:
L(-)-Camphorsulfonic acid

[Synonym ]:
((1R,4S)-7,7-Dimethyl-2-oxobicyclo-[2.2.1]heptan-1-yl)methanesulfonic acid
(1R)-(-)-CAMPHOR-10-SULPHONIC ACIDCamphorSulfonic Acid
(-)-10-Camphorsulfonic Acid
L(-)-Camphorsulfonic acid
(−)-Camphor-10-sulfonic acid,(1R)-(−)-Camphor-10-sulfonic acid,(1R)-Camphor-10-sulfonic acid
(R)-(-)-Camphor-10-sulfonic Acid
EINECS 252-817-9
Camphorsulfonic acid
1R-(-)-10-Camphorsulfonic acid
(1R)-(-)-10-Camphorsulfonic acid
[(1R,4S)-7,7-Dimethyl-2-oxobicyclo[2.2.1]hept-1-yl]methanesulfonic acid
MFCD00064158
(1R)-(−)-10-Camphorsulfonic acid
Bicyclo[2.2.1]heptane-1-methanesulfonic acid, 7,7-dimethyl-2-oxo-, (1R,4S)-
(−)-Camphor-10-sulfonic acid
((1R,4S)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonic acid
(1R)-Camphor-10-sulfonic acid

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Melting Point ]:
198ºC

[ Molecular Formula ]:
C10H16O4S

[ Molecular Weight ]:
232.297

[ Exact Mass ]:
232.076935

[ PSA ]:
79.82000

[ LogP ]:
-0.57

[ Index of Refraction ]:
1.540

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C:Corrosive

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
26-36/37/39-45-24/25-27

[ RIDADR ]:
UN 3261 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
8.0

[ HS Code ]:
29147090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • (1-PHENYLCYCLOPENTYL)METHYLAMINE
  • DL-10-Camphorsulfonic Acid
  • [7,7-dimethyl-2-oxobicyclo[2.2.1]hept-1-yl]methanesulphonic acid
  • Hydrochloric acid
  • H-Phg-OH
  • Brucine

DownStream

  • (S)-(+)-(2-BUTENOYL)-2 10-CAMPHORSULTAM
  • (1-PHENYLCYCLOPENTYL)METHYLAMINE
  • 4,5-DIFLUORO-2-METHYLBROMOBENZENE
  • (1R)-(-)-(10-Camphorsulfonyl)oxaziridine
  • (2S)-Bornane-10,2-sultam

Customs

[ HS Code ]: 2914299000

[ Summary ]:
2914299000. other cyclanic, cyclenic or cyclotherpenic ketones without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

Analysis of deprotonated acids with silicon nanoparticle-assisted laser desorption/ ionization mass spectrometry.

J. Mass Spectrom. 45(12) , 1394-401, (2010)

Chemically modified silicon nanoparticles were applied for the laser desorption/negative ionization of small acids. A series of substituted sulfonic acids and fatty acids was studied. Compared to deso...

Camphorsulfonic acid catalysed facile tandem double Friedlander annulation protocol for the synthesis of phenoxy linked bisquinoline derivatives and discovery of antitubercular agents.

Bioorg. Med. Chem. Lett. 22 , 1643-8, (2012)

A series of phenoxy linked bisquinoline derivatives were synthesised from the Friedlander annulation of 2-(4-acetylphenoxy)-1-aryl-1-ethanones with 2-aminobenzophenone in good yields using (±)-camphor...

Design and construction of a compact end-station at NSRRC for circular-dichroism spectra in the vacuum-ultraviolet region.

J. Synchrotron Radiat. 17(6) , 761-8, (2010)

A synchrotron-radiation-based circular-dichroism end-station has been implemented at beamline BL04B at the National Synchrotron Radiation Research Center (NSRRC) in Taiwan for biological research. The...


More Articles

Related Compounds

  • l-10-camphorsulfonic acid ammonium salt
  • 10-camphorsulfonic acid sodium salt
  • (1S)-(+)-10-Camphorsulfonic acid
  • [7,7-dimethyl-2-oxobicyclo[2.2.1]hept-1-yl]methanesulphonic acid
  • BICYCLO[2.2.1]HEPTANE-1-METHANESULFONYL CHLORIDE, 7,7-DIMETHYL-2-OXO-
  • 1-Naphthol-5-sulfonic acid
  • 8-Methyl-2-[4-(trifluoromethoxy)phenyl]imidazo[1,2-a]pyridine
  • trans-4-(2-Carboxycyclopropyl)benzoic acid ethyl ester
  • 8-Methyl-2-(2-pyridyl)imidazo[1,2-a]pyridine
  • trans-2-(2-Bromo-4-fluorophenyl)cyclopropanecarboxylic acid
  • 2-Cyclopropyl-8-methylimidazo[1,2-a]pyridine
  • 8-Methyl-2-(5-methylfuran-2-yl)imidazo[1,2-a]pyridine
  • 8-Methyl-2-(2-nitrophenyl)imidazo[1,2-a]pyridine
  • 8-Methyl-2-(thiophen-3-yl)imidazo[1,2-a]pyridine
  • Methyl 4-(2-aminocyclopropyl)benzoate
  • rel-Methyl 4-((1R,2S)-2-aminocyclopropyl)benzoate