2,4-Dichloro-6-methoxy-1,3,5-triazine

Names

[ Name ]:
2,4-Dichloro-6-methoxy-1,3,5-triazine

[Synonym ]:
2,6-dichloro-4-methoxy-1,3,5-triazine
MFCD00128159
2,4-dichloro-6-methoxy-s-triazine
2-methoxy-4,6-dichloro-1,3,5-triazine
EINECS 222-863-4

Chemical & Physical Properties

[ Density]:
1.538 g/cm3

[ Boiling Point ]:
132-134 °C49 mm Hg(lit.)

[ Melting Point ]:
86-88 °C(lit.)

[ Molecular Formula ]:
C₄H₃Cl₂N₃O

[ Molecular Weight ]:
179.99200

[ Flash Point ]:
157.2ºC

[ Exact Mass ]:
178.96500

[ PSA ]:
47.90000

[ LogP ]:
1.18700

[ Index of Refraction ]:
1.545

[ Storage condition ]:
2-8°C

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
UN 3335

[ WGK Germany ]:
3

[ HS Code ]:
2933699090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Methanol
Cyanuric chloride
Thiophenol
Sodium Methylate

DownStream

2-chloro-4-dimethoxyphosphoryl-6-methoxy-1,3,5-triazine
2-Chloro-4,6-dimethoxy-1,3,5-triazine
2,4-bis(3,5-dimethylpyrazol-1-yl)-6-methoxy-1,3,5-triazine
4-chloro-N-ethyl-6-methoxy-1,3,5-triazin-2-amine

Customs

[ HS Code ]: 2933699090

[ Summary ]:
2933699090 other compounds containing an unfused triazine ring (whether or not hydrogenated) in the structure。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:20.0%

Articles

An easy-to-use excimer fluorescence derivatization reagent, 2-chloro-4-methoxy-6-(4-(pyren-4-yl)butoxy)-1,3,5-triazine, for use in the highly sensitive and selective liquid chromatography analysis of histamine in Japanese soy sauces.

Anal. Chim. Acta 880 , 145-51, (2015)

In this study, a novel pre-column excimer fluorescence derivatization reagent, 2-chloro-4-methoxy-6-(4-(pyren-4-yl)butoxy)-1,3,5-triazine (CMPT), was developed for polyamines, specifically histamine. ...

Synthesis of alpha-cyclodextrin [2]-rotaxanes using chlorotriazine capping reagents.

Org. Biomol. Chem. 6(10) , 1814-21, (2008)

Ten alpha-cyclodextrin [2]-rotaxanes have been prepared with alkane-, stilbene- and azobenzene-based axles, capped through nucleophilic substitution of either 2-chloro-4,6-dimethoxy-1,3,5-triazine or ...

Design of chiral monochloro-s-triazine reagents for the liquid chromatographic separation of amino acid enantiomers.

J. Chromatogr. A. 998(1-2) , 73-82, (2003)

A series of chiral derivatizing reagents (CDRs) was synthesized by nucleophilic replacement of one chlorine atom in cyanuric chloride (2,4,6-trichloro-1,3,5-triazine; s-triazine) by alkoxy (methoxy, b...

2,4-Dichloro-6-cyclopropyl-1,3,5-triazine
2,4-dichloro-6-isocyanato-1,3,5-triazine
2,4-dichloro-6-diazomethyl-[1,3,5]triazine
2,4-Dichloro-6-ethoxy-1,3,5-triazine
2,4-Dichloro-6-phenoxy-1,3,5-triazine
2,4-dichloro-6-(trichloromethyl)-1,3,5-triazine
2,5-dimethyl-3-[(1-{2-methyl-5H,6H,7H-cyclopenta[d]pyrimidin-4-yl}piperidin-4-yl)oxy]pyrazine
2-[5-(2-Cyclopropyl-6-methylpyrimidin-4-yl)-octahydropyrrolo[3,4-c]pyrrol-2-yl]pyridine-3-carbonitrile
N-{1-[(2,4-difluorophenyl)methyl]piperidin-4-yl}-2,2-dimethylpropanamide
3-{[1-(3-Bromopyridin-4-yl)piperidin-4-yl]oxy}-2,5-dimethylpyrazine
7-[(2-methylphenyl)methyl]-3-(trifluoromethyl)-5H,6H,7H,8H-[1,2,4]triazolo[4,3-a]pyrazine
3-[4-(6-Hydroxypyridazin-3-yl)piperazin-1-yl]pyridine-2-carbonitrile
4-[(4-{[(6-Cyclopropyl-5-fluoropyrimidin-4-yl)(methyl)amino]methyl}piperidin-1-yl)methyl]-1-methyl-1,2-dihydropyridin-2-one
6-{[3-(Difluoromethoxy)phenyl]amino}pyridazine-3-carbonitrile
4-{4-[(3,6-Dimethylpyrazin-2-yl)oxy]piperidin-1-yl}-2-(methylsulfanyl)pyrimidine-5-carbonitrile
5-Chloro-6-{methyl[2-(pyridin-4-yl)ethyl]amino}pyridine-3-carbonitrile

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