4-Fluoro-3-nitroaniline

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Names

[ CAS No. ]:
364-76-1

[ Name ]:
4-Fluoro-3-nitroaniline

[Synonym ]:
4-Fluoro-3-nitro-phenylamine
4-Fluoro-3-nitrobenzenamine
3-nitro-4-fluoroaniline
4-Fluoro-3-nitroaniline
EINECS 206-665-5
3-nitro-4-fluoroanailine
4-amino-1-fluoro-2-nitrobenzene
4-fluoro-5-nitroaniline
Benzenamine,4-fluoro-3-nitro
5-amino-2-fluoronitrobenzene
MFCD00007833
Benzenamine, 4-fluoro-3-nitro-
4'-fluoro-3'-nitroaniline
ZR DF CNW
Aniline,4-fluoro-3-nitro
4-Amino-2-nitrofluorobenzene

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
331.3±22.0 °C at 760 mmHg

[ Melting Point ]:
94-96 °C(lit.)

[ Molecular Formula ]:
C6H5FN2O2

[ Molecular Weight ]:
156.115

[ Flash Point ]:
91.1±0.0 °C

[ Exact Mass ]:
156.033508

[ PSA ]:
71.84000

[ LogP ]:
1.27

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.603

[ Water Solubility ]:
Insoluble

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
BY1700000
CHEMICAL NAME :
Aniline, 4-fluoro-3-nitro-
CAS REGISTRY NUMBER :
364-76-1
BEILSTEIN REFERENCE NO. :
2210199
LAST UPDATED :
199710
DATA ITEMS CITED :
7
MOLECULAR FORMULA :
C6-H5-F-N2-O2
MOLECULAR WEIGHT :
156.13
WISWESSER LINE NOTATION :
ZR DF CNW

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1100 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 72,400,1984
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>200 gm/m3/1H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 72,400,1984
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>10 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 72,400,1984 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1080 mg/kg/90D-I
TOXIC EFFECTS :
Kidney, Ureter, Bladder - changes in bladder weight Blood - change in clotting factors Blood - changes in erythrocyte (RBC) count
REFERENCE :
TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 72,400,1984

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn:Harmful

[ Risk Phrases ]:
R22;R36/37/38

[ Safety Phrases ]:
S36/37-S37/39-S26

[ RIDADR ]:
UN 1325 4.1/PG 2

[ WGK Germany ]:
2

[ RTECS ]:
BY1700000

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1(b)

[ HS Code ]:
29214210

Synthetic Route

Precursor & DownStream

Precursor

  • 1-Fluoro-2,4-dinitrobenzene
  • 4-Fluoroaniline
  • 2-Fluoroaniline
  • 2-Fluoro-5-nitroaniline
  • Palladium chloride
  • Sulfuric acid
  • nitric acid

DownStream

  • 4-Methoxy-3-nitroaniline
  • 4-Iodo-2-nitroanisole
  • 4-Chloro-1-fluoro-2-nitrobenzene
  • 2-nitro-4-chlorophenol
  • 4-Bromo-1-methoxy-2-nitrobenzene
  • N-(4-fluoro-3-nitrophenyl)ethanesulfonamide
  • 2-(4-(TERT-BUTOXYCARBONYLAMINO)-2-NITROPHENYL)ACETIC ACID
  • N-(4-fluoro-3-nitrophenyl)cyclohexanecarboxamide
  • 4-Chloro-2-nitroaniline
  • p-Chloro-o-nitroanisole

Customs

[ HS Code ]: 2921420090

[ Summary ]:
HS:2921420090 aniline derivatives and their salts VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Inhibition of monoamine oxidase by phenyl azides.

J. Neurochem. 45(3) , 940-5, (1985)

We had previously shown that 4-fluoro-3-nitrophenyl azide (FNPA) is a competitive inhibitor of both types of monoamine oxidase (MAO) in the dark, but it is a preferential photoaffinity label for only ...

Subchronic oral toxicology of 4-fluoro-3-nitroaniline in the rat.

Toxicol. Appl. Pharmacol. 72(3) , 400-5, (1984)

4-Fluoro-3-nitroaniline (4-F-3-NA), an intermediate used in the production of commercial hair dyes, was administered daily for 90 days via po intubation to Charles River CD rats at doses of 40, 120, o...


More Articles


Related Compounds

  • N,N-Bis-(Hydroxyethyl)-4-Fluoro-3-Nitroaniline
  • N-(tert-butoxycarbonyl)-4-fluoro-3-nitroaniline
  • N-(1H-Benzotriazol-1-ylmethyl)-4-fluoro-3-nitroaniline
  • 4-fluoro-3-methyl-2-nitroaniline
  • 4-Fluoro-N-methyl-3-nitroaniline
  • 4-fluoro-3-(3-methylsulfonylphenyl)benzoic acid
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • 2-[6-(Oxan-4-yl)piperidin-3-yl]ethan-1-amine
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide