2',4'-Difluoroacetophenone

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Names

[ CAS No. ]:
364-83-0

[ Name ]:
2',4'-Difluoroacetophenone

[Synonym ]:
2′,4′-Difluoroacetophenone
2‘,4‘-Difluoroacetophenone
2,4-Difluoroacetophenone
1-(2,4-Difluorophenyl)ethanone
2’,4’-Difluoroacetophenone
2',4'-Difluoroacetophenone
FR CF DV1
EINECS 206-667-6
1-(2,4-Difluorophenyl)ethan-1-one
Ethanone, 1-(2,4-difluorophenyl)-
1-Acetyl-2,4-difluorobenzene
MFCD00151261
Acetophenone, 2',4'-difluoro-

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
177.4±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C8H6F2O

[ Molecular Weight ]:
156.129

[ Flash Point ]:
66.7±0.0 °C

[ Exact Mass ]:
156.038666

[ PSA ]:
17.07000

[ LogP ]:
1.39

[ Vapour Pressure ]:
1.0±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.473

[ Water Solubility ]:
INSOLUBLE

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2914391000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 1,3-Difluorobenzene
  • Acetyl chloride
  • 1-Bromo-2,4-difluorobenzene
  • Ethanoic anhydride

DownStream

  • 2,4-Difluorophenol
  • 2,4-Difluorophenyl acetate
  • 2-(2,4-Difluorophenyl)propan-2-ol
  • 1-(2,4-Difluorophenyl)ethanol
  • 4′-Fluoro-2′-hydroxyacetophenone
  • 2'-Fluoro-4'-hydroxyacetophenone
  • 2,4-Difluorophenylglyoxal hydrate
  • 2-Bromo-2',4'-difluoroacetophenone
  • 2,4-Difluorobenzoic acid
  • 2',4'-DIFLUORO-3-(4-FLUOROPHENYL)PROPIOPHENONE

Customs

[ HS Code ]: 2914700090

[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

Articles

Structural study, NCA, FT-IR, FT-Raman spectral investigations, NBO analysis and thermodynamic properties of 2',4'-difluoroacetophenone by HF and DFT calculations.

Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 110 , 269-84, (2013)

In this work, the vibrational spectral analysis was carried out by FT-IR and FT-Raman spectroscopy in the regions of 4000-400 cm(-1) and 3500-100 cm(-1), respectively for 2',4'-difluoroacetophenone (D...

Synthesis and anti-inflammatory activity of fluorinated propanedione derivatives. More AH and Ramaa CS.
1. More AH and Ramaa CS.

Indian J. Chem. B 49(3) , 364, (2010)


More Articles

Related Compounds

  • 2',4'-Difluoroacetophenone oxime
  • 2-Amino-2',4'-difluoroacetophenone
  • 2-Bromo-2',4'-difluoroacetophenone
  • 2-Chloro-2',4'-difluoroacetophenone
  • 5'-Bromo-2',4'-difluoroacetophenone
  • 3'-Ethoxy-2',4'-difluoroacetophenone
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-(tert-butyl) 2-methyl 4-bromo-1H-indole-1,2-dicarboxylate
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • tert-butyl N-methyl-N-[1-(6-propylpyrimidin-4-yl)azetidin-3-yl]carbamate
  • 1-(Cyclopropylmethyl)-2-oxo-1,2-dihydropyridine-4-carbonitrile
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde