Tosylmethyl isocyanide

Suppliers

Names

[ Name ]:
Tosylmethyl isocyanide

[Synonym ]:
TosMICTosylmethyl Isocyanide
4-toluene-sulfonylmethyl isocyanide
(p-Tolylsulfonyl)methyl isocyanide
Tosylmethy isocyanide
Tosylmethylisocyanide
Isocyanomethyl 4-methylphenyl sulfone
Benzene, 1-((isocyanomethyl)sulfonyl)-4-methyl-
p-Toluenesulfonylmethyl isocyanide
1-[(Isocyanomethyl)sulfonyl]-4-methylbenzene
4-Toluenesulfonylmethyl isocyanide
P-tolysulfonylmethylisocyanide
p-tosylmethyl isocyanide
4-Toluenesulfonylmethylisocyanide
TOSMIC
EINECS 253-140-1
p-Toluenesulfonyl Isocyanide
Tosylmethyl isocyani
MFCD00000005
Benzene, 1-[(isocyanomethyl)sulfonyl]-4-methyl-
IsocyanoMethyl p-Tolyl Sulfone
1-[(Isocyanmethyl)sulfonyl]-4-methylbenzol
4-Toluenesulphonylmethyl Isocyanide

Chemical & Physical Properties

[ Density]:
1.24 g/cm3

[ Boiling Point ]:
400.9ºC at 760 mmHg

[ Melting Point ]:
109-113 °C(lit.)

[ Molecular Formula ]:
C₉H₉NO₂S

[ Molecular Weight ]:
195.238

[ Flash Point ]:
196.3ºC

[ Exact Mass ]:
195.035400

[ PSA ]:
42.52000

[ LogP ]:
1.95700

[ Storage condition ]:
-20°C

[ Water Solubility ]:
insoluble

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301 + H311 + H331

[ Precautionary Statements ]:
P261-P280-P301 + P310-P311

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges

[ Hazard Codes ]:
T:Toxic

[ Risk Phrases ]:
R23/24/25

[ Safety Phrases ]:
S36/37-S45-S38-S36/37/39-S28A

[ RIDADR ]:
UN 2811 6.1/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1(b)

[ HS Code ]:
29299000

Customs

[ HS Code ]: 2926909090

[ Summary ]:
HS:2926909090 other nitrile-function compounds VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Microwave-assisted synthesis of imidazoles: reaction of p-toluenesulfonylmethyl isocyanide and polymer-bound imines.

Bioorg. Med. Chem. Lett. 15(16) , 3717-9, (2005)

A convenient method for the synthesis of 1,5-disubstituted imidazoles has been developed on a polymeric support using base-promoted 1,3-dipolar cycloaddition reaction of p-toluenesulfonylmethyl isocya...

Synthesis of novel triplet drugs with 1,3,5-trioxazatriquinane skeletons and their pharmacologies. Part 2: Synthesis of novel triplet drugs with the epoxymethano structure (capped homotriplet).

Bioorg. Med. Chem. Lett. 21(20) , 6198-202, (2011)

An improved synthetic method for triplet drugs with the 1,3,5-trioxazatriquinane skeleton was developed that used p-toluenesulfonylmethyl isocyanide (TosMIC) instead of 1,3-dithiane. Using the improve...

Alkyl and aromatic isocyanide binding to haem complexes.

Biochem. J. 262(3) , 959-63, (1989)

Equilibrium constants for the binding of ethyl (EIC), n-butyl (BIC), p-toluenesulphonylmethyl (TMIC) and 2,6-dimethylphenyl isocyanides (DIMPI) to an imidazole-haem complex in toluene and aqueous dete...

tosylmethyl isocyanide
Tosylmethyl Isocyanide-
1-allyl-1-tosylmethyl isocyanide
1-P-TOLYL-1-TOSYLMETHYL ISOCYANIDE
1-n-Butyl-1-tosylmethyl isocyanide
1-M-TOLYL-1-TOSYLMETHYL ISOCYANIDE
2-(Aminomethyl)-4-hydroxybenzonitrile
4-Cyclopropoxy-N,N-dimethyl-2-nitroaniline
5-Cyclopropoxy-2-isopropoxy-N-methylpyridin-3-amine
2-(Chloromethoxy)-1-fluoro-4-methylbenzene
2-Bromo-6-(cyclopropylmethoxy)phenol
4-Cyclopropoxy-5-ethylpicolinic acid
3-Cyclopropoxy-5-ethyl-N-methylpyridin-4-amine
2-Formyl-4-hydroxybenzamide
3,4-Dihydrospiro[1-benzopyran-2,1'-cyclopropane]-4-one
[4-(5,7-Dimethyl-4,6,17-trioxo-5,7,9-triazatetracyclo[8.7.0.03,8.011,16]heptadeca-1(10),11,13,15-tetraen-2-yl)phenyl] 4-methylbenzoate

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