Benzenesulfonylfluoride

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Names

[ CAS No. ]:
368-43-4

[ Name ]:
Benzenesulfonylfluoride

[Synonym ]:
MFCD00007412
benzenesulphonic acid fluoride
phenylsulfonyl fluoride
fluorophenylsulfone
EINECS 206-707-2
Benzolsulfonylfluorid
Benzenesulfonyl fluoride
Benzenesulphonylfluoride

Chemical & Physical Properties

[ Density]:
1.333 g/mL at 25 °C(lit.)

[ Boiling Point ]:
207-208 °C(lit.)

[ Molecular Formula ]:
C6H5FO2S

[ Molecular Weight ]:
160.16600

[ Flash Point ]:
189 °F

[ Exact Mass ]:
159.99900

[ PSA ]:
42.52000

[ LogP ]:
2.42560

[ Index of Refraction ]:
n20/D 1.492(lit.)

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
DB8940000
CHEMICAL NAME :
Benzenesulfonyl fluoride
CAS REGISTRY NUMBER :
368-43-4
BEILSTEIN REFERENCE NO. :
2206835
LAST UPDATED :
199701
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C6-H5-F-O2-S
MOLECULAR WEIGHT :
160.17
WISWESSER LINE NOTATION :
WSFR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
100 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NATUAS Nature. (Nature Subscription Dept., POB 1018, Manasguan, NJ 08736) V.1- 1869- Volume(issue)/page/year: 173,33,1954

Safety Information

[ Symbol ]:

GHS05, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302 + H312-H314-H331

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338-P310

[ Hazard Codes ]:
C: Corrosive;

[ Risk Phrases ]:
R20/21/22

[ Safety Phrases ]:
S26-S27-S36/37/39-S45

[ RIDADR ]:
UN 3265 8/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
DB8940000

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
2942000000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Diphenyl disulfide
  • Phenyl phenylthio sulfone
  • chlorophenylsulfone
  • N-Benzyl-N,N-dimethylanilinium chloride
  • Sodium benzenesulfinate
  • tris(2,3,4,5,6-pentafluorophenyl)-phenylsilane
  • Benzolsulfinsaeurefluorid
  • Trichlorophenylsilane
  • Benzenesulfonamide

DownStream

  • Benzoyl Fluoride
  • Benzoic anhydride
  • BENZENESULFONIC ANHYDRIDE
  • Fluoro(trimethyl)silane
  • (1-tert-Butylvinyl)-benzolsulfonat
  • (1-Phenylvinyl)-benzolsulfonat
  • BENZENESULFONIC ACID 2-CHLOROETHYL ESTER
  • Benzenesulfonyl isocyanate
  • (2-Methyl-1-propenyl)-benzolsulfonat
  • (Cyclohexen-1-yl)-benzolsulfonat

Customs

[ HS Code ]: 2904909090

[ Summary ]:
HS:2904909090 sulphonated, nitrated or nitrosated derivatives of hydrocarbons, whether or not halogenated VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

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Related Compounds

  • Benzenesulfonylfluoride,2-amino
  • Benzenesulfonylfluoride,2-amino
  • Benzenesulfonylfluoride,4-ethyl
  • Benzenesulfonylfluoride,2-ethyl
  • Benzenesulfonylfluoride,3-ethyl
  • Benzenesulfonylfluoride,4-hydroxy
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 2-Bromo-3-(hydrazinylmethyl)phenol
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • Clethodim, (Z)-
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • N-[3-Chloro-2-(2-methoxyethoxy)phenyl]prop-2-enamide
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde