(+)-diop

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Names

[ CAS No. ]:
37002-48-5

[ Name ]:
(+)-diop

[Synonym ]:
(+)-(S,S)-2,3-O-isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphinobutane)
(S)-4-AMINO-3-HYDROXYBUTANOIC ACID
((anti-2,2-dimethyl-1,3-dioxolane-4,5-diyl)bis(methylene))bis(diphenylphosphine)
(S,S)-1,4-bis(diphenylphosphino)-1,4-dideoxy-2,3-O-isopropylidene-L-threitol
(4S,5S)-(+)-Bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxolane
(S)-(+)-GABOB
(+)-2,3-O,O'-isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphanyl)butane
acide (S)-amino-4 hydroxy-3 butanoique
(2S,3S)-(+)-1,4-Bis(diphenylphosphino)-2,3-O-isopropylidene-2,3-butanediol
(+)-2,3-O-Isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane
(S)-(+)-Amino-3-hydroxybutanoic acid
EINECS 253-307-9
(2S,3S)-(+)-2,3-O-Isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane
(S)-(+)-4-Amino-3-hydroxybutyric acid
(((4S,5S)-2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(methylene))bis(diphenylphosphine)
MFCD00009760
(4S,5S)-(+)-4,5-Bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxolane
(+)-2,3-O-Isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)

Chemical & Physical Properties

[ Boiling Point ]:
590.3ºC at 760 mmHg

[ Melting Point ]:
88 - 90ºC

[ Molecular Formula ]:
C31H32O2P2

[ Molecular Weight ]:
498.53200

[ Flash Point ]:
390.9ºC

[ Exact Mass ]:
498.18800

[ PSA ]:
45.64000

[ LogP ]:
5.77230

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
26

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
29319090

Articles

Morimoto, T. et al.

Tetrahedron Asymmetry 6 , 23, (1995)

Morimoto, T. at al.

Tetrahedron Asymmetry 6 , 75, (1995)

Matsumoto, Y. et al.

Tetrahedron 50 , 335, (1994)


More Articles


Related Compounds

  • (+)-MOD-DIOP
  • (+)-5-methylcyclohex-2-en-1-one
  • (+/-)-4-(2-furyl)-butan-2-ol acetate
  • (+)-(3R,4S)-4-hydroxy-3-methylnonan-2-one
  • (+)-(1R,3S,6S)-artemiseole
  • (+)-limousamine
  • 6-Chloro-n-cyclobutyl-2-cyclopropyl-5-methyl-4-pyrimidinamine
  • 6-chloro-2-cyclopropyl-5-methyl-N-(1-methylcyclopropyl)pyrimidin-4-amine
  • N-[3-[[2-[(2S)-2-Cyano-1-pyrrolidinyl]-2-oxoethyl]amino]tricyclo[3.3.1.13,7]dec-1-yl]-4-(methylsulfonyl)benzenesulfonamide
  • 1,10-Bis(2,5-dioxo-3-sulfo-1-pyrrolidinyl) decanedioate
  • L-Serine, O-(2-hydroxyethyl)-
  • 5-Methyl-6-phenylimidazo[2,1-b]-1,3,4-thiadiazole-2-sulfonamide
  • 5-Amino-6-(propan-2-yloxy)pyrimidin-4-ol
  • 1H-Isoindol-3-amine, 1-[[4-(2-phenyldiazenyl)phenyl]imino]-
  • 10-Bromo-7-thia-2,3,4,5-tetraazatricyclo[6.4.0.0,2,6]dodeca-1(12),3,5,8,10-pentaene
  • 5-Chloro-2-(methylsulfanyl)-N-{1,7,7-trimethylbicyclo[2.2.1]heptan-2-YL}pyrimidine-4-carboxamide
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