(-)-Dimethyl 2,3-O-isopropylidene-L-tartrate

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Names

[ Name ]:
(-)-Dimethyl 2,3-O-isopropylidene-L-tartrate

[Synonym ]:
(-)-Dimethyl-2,3-o-isopropylidene-l-tartrate
(-)-2,3-O-Isopropylidene-L-tartaric Acid Dimethyl Ester
(−)-Dimethyl 2,3-O-isopropylidene-L-tartrate
(4R,5R)-Dimethyl 2,2-dimethyl-1,3-dioxolane-4,5-dicarboxylate
(-)-Dimethyl 2,3-O-isopropylidene-L-tartrate
1,3-Dioxolane-4,5-dicarboxylic acid, 2,2-dimethyl-, dimethyl ester, (4R,5R)-
Dimethyl (-)-2,3-O-Isopropylidene-L-tartrate
(4R,5R)-2,2-Dimethyl-1,3-dioxolane-4,5-dicarboxylic acid dimethyl ester
Dimethyl (4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5-dicarboxylate
MFCD00066218

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
270.2±0.0 °C at 760 mmHg

[ Melting Point ]:
40-43℃

[ Molecular Formula ]:
C₉H₁₄O₆

[ Molecular Weight ]:
218.204

[ Flash Point ]:
103.0±26.0 °C

[ Exact Mass ]:
218.079041

[ PSA ]:
71.06000

[ LogP ]:
1.38

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.436

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves

[ Risk Phrases ]:
R23

[ Safety Phrases ]:
23-24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2932999099

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Tartaric acid
2,2-Dimethoxypropane
(+)-Dimethyl-L-tartrate
Acetone
1,1-Dimethoxypropane
Methanol
L(+)-Diethyl L-tartrate
2-methyoxypropene
diazomethane

DownStream

(+)-1,4-di-o-tosyl-2,3-o-isopropylidene-d-threitol
(-)-1,4-di-o-tosyl-2,3-o-isopropylidenethreitol
2,3-O-isopropylidene-L-threitol
(4R,5S)-methyl 5-hydroxymethyl-2,2-dimethyl-1,3-dioxolane-4-carboxylate
(-)-Taddol
METHYL(2R,3S)-2,3-O-ISOPROPYLIDENE-2,3-DIHYDROXYBUTYRATE
l-2,3-O-isopropylidenethreitol
(4s,5s)-4,5-di(aminomethyl)-2,2-dimethyldioxolane
[(4R,5R)-5-benzoyl-2,2-dimethyl-1,3-dioxolan-4-yl]-phenylmethanone
(+)-TERT-BUTYL(S)-3-HYDROXYBUTYRATE

Customs

[ HS Code ]: 2932999099

[ Summary ]:
2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

J. Org. Chem. 57 , 6825, (1992)

Angew. Chem. Int. Ed. Engl. 30 , 99, (1991)

Tetrahedron Lett. 31 , 7179, (1990)

(4R,5R)-5-(methoxycarbonyl)-2,2-dimethyl-1,3-dioxolane-4-carboxylic acid
(1R,2S)-1-[(3aS,4S,6R,6aS)-2,2-dimethyl-4-phenylmethoxy-3a,4,6,6a-tetrahydrofuro[3,4-d][1,3]dioxol-6-yl]propane-1,2,3-triol
(+)-2,3-O-ISOPROPYLIDENE-L-THREITOL
Thx
(-)-DIBUTYL-D-TARTRATE
(4R,5S)-methyl 5-hydroxymethyl-2,2-dimethyl-1,3-dioxolane-4-carboxylate
1-(3-ethyl-1-propyl-1H-pyrazol-5-yl)ethan-1-amine
1-(3-tert-butyl-1-propyl-1H-pyrazol-5-yl)ethan-1-amine
1-[1-(butan-2-yl)-3-tert-butyl-1H-pyrazol-5-yl]ethan-1-amine
3-[1-(Hydroxymethyl)cyclobutyl]-8-methyl-8-azabicyclo[3.2.1]octan-3-ol
1-[1-(Hydroxymethyl)cyclobutyl]-3,3,5,5-tetramethylcyclohexan-1-ol
2-(1-Methoxy-2-methylpropan-2-yl)-1-methylpyrrolidin-3-amine
4-[5-(bromomethyl)-1H-pyrazol-1-yl]benzonitrile
5-(bromomethyl)-1-(2,5-difluorophenyl)-1H-pyrazole
5-(bromomethyl)-1-(4-chloro-2-methylphenyl)-1H-pyrazole
5-(bromomethyl)-1-(2-chloro-4-methylphenyl)-1H-pyrazole

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