Methyl 3-butenoate

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Names

[ CAS No. ]:
3724-55-8

[ Name ]:
Methyl 3-butenoate

[Synonym ]:
Methyl 3-butenoate
Methyl vinylacetate
MFCD00082587
3-Butenoic acid, methyl ester
Methyl But-3-Enoate
but-3-enoic acid methyl ester
vinyl acetic acid methyl ester
methyl ester of 3-butenoic acid
EINECS 223-076-9
3-butenoic acid methyl ester

Chemical & Physical Properties

[ Density]:
0.939

[ Boiling Point ]:
112 ºC

[ Molecular Formula ]:
C5H8O2

[ Molecular Weight ]:
100.116

[ Flash Point ]:
20 ºC

[ Exact Mass ]:
100.052429

[ PSA ]:
26.30000

[ LogP ]:
1.00

[ Vapour Pressure ]:
57.3±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.402

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225

[ Precautionary Statements ]:
P210

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F: Flammable;

[ Risk Phrases ]:
R11

[ Safety Phrases ]:
16

[ RIDADR ]:
UN 3272

[ Packaging Group ]:
II

[ Hazard Class ]:
3.1

[ HS Code ]:
2916190090

Precursor & DownStream

Precursor

  • Allyl methyl carbonate
  • Methanol
  • 2-Crotonoyl chloride
  • 3-Butenoic acid
  • methyl iodide
  • carbon monoxide
  • Methyl (2E)-2-butenoate
  • ALLYL CHLORIDE
  • Methyl bromocrotonate

DownStream

  • methyl (E)-4-(1-triisopropylsilylpyrrolo[2,3-b]pyridin-4-yl)but-3 -enoate
  • methyl (E)-4-(1-triisopropylsilylpyrrolo[2,3-b]pyridin-4-yl)but-2 -enoate
  • 2-Methylindole
  • Methyl 3,4-epoxybutyrate
  • 3-Chlorobenzoic Acid
  • Cis-Dimethyl Cyclopropane-1,2-Dicarboxylate
  • Methyl 6-oxohexanoate
  • Methyl 4-methyl-5-oxopentanoate
  • methyl 8-methyl-8-azabicyclo[3.2.1]oct-3-ene-4-carboxylate
  • 2-diazonio-1-methoxybuta-1,3-dien-1-olate

Customs

[ HS Code ]: 2916190090

[ Summary ]:
2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

Articles

Iron Carbonyl-Promoted Isomerization of Olefin Esters to Their alpha,beta-Unsaturated Esters: Methyl Oleate and Other Examples.

J. Org. Chem. 61(22) , 7784-7792, (1996)

Ultraviolet photolysis of stoichiometric amounts of methyl oleate and Fe(CO)(5) in hexanes solvent at 0 degrees C gives Fe(CO)(3)(eta(4)-alpha,beta-ester) in which the alpha,beta-unsaturated ester iso...

Synthesis of the pro-gly dipeptide alkene isostere using olefin cross-metathesis.

J. Org. Chem. 67(17) , 6240-2, (2002)

An approach to the synthesis of dipeptide olefin isosteres using intermolecular olefin cross-metathesis is presented. In particular, a synthesis of the Pro-Gly isostere (1) is reported. Conversion of ...

The flash vacuum thermolysis of (-)-cocaine. Sisti NJ, et al.

Tetrahedron Lett. 30(44) , 5977-80, (1989)


More Articles

Related Compounds

  • (5-Fluoro-3-pyridinyl)methyl 3-butenoate
  • ethyl 2-isopropenyl-3-methyl-3-butenoate
  • Ethyl 2-chloro-3-methyl-3-butenoate
  • Methyl 2-ethyl-3-methyl-3-butenoate
  • methyl 4-p-biphenylyl-3-methyl-3-butenoate
  • ethyl 2-(1-hydroxy-1-phenylmethyl)-3-methyl-3-butenoate
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • Ethyl (1E)-2-(5-bromo-2-methoxyphenyl)ethenesulfonate
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • 3-[5-Ethoxy-1-(4-iodo-benzenesulfonyl)-1h-indol-3-yl]-propionic acid
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine