(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine
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Names
[ CAS No. ]:
380230-02-4
[ Name ]:
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine
[Synonym ]:
(S,S,S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS(1-PHENYLETHYL)AMINE
3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine
Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, N,N-bis[(1S)-1-phenylethyl]-
(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE,(11BR)
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1S)-1-PHENYLETHYL]AMINE
N,N-Bis[(1S)-1-phenylethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
MFCD04117688
(S,S,S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHE
Chemical & Physical Properties
[ Boiling Point ]:
710.7±63.0 °C at 760 mmHg
[ Melting Point ]:
88-89ºC
[ Molecular Formula ]:
C36H30NO2P
[ Molecular Weight ]:
539.603
[ Flash Point ]:
383.6±33.7 °C
[ Exact Mass ]:
539.201416
[ PSA ]:
29.52000
[ LogP ]:
10.33
[ Vapour Pressure ]:
0.0±2.3 mmHg at 25°C
MSDS
Safety Information
[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
[ Risk Phrases ]:
36/37/38
[ Safety Phrases ]:
26-36/37/39
[ RIDADR ]:
NONH for all modes of transport
Articles
Org. Lett. 4 , 3835, (2002)
[formula: see text] The zinc enolates, resulting from the copper-catalyzed enantioselective conjugate addition of dialkyl zinc reagents to cyclic and acyclic enones, could be trapped, quantitatively, ...
J. Org. Chem. 70 , 7451, (2005)
[reaction: see text] The enantioselective catalytic 1,4-addition to alpha,beta-unsaturated ketimines is an unprecedented process. Herein, we document the copper-catalyzed addition of dialkylzinc reage...
Synlett , 1375, (2001)