4-(methylthio)benzyl bromide 97

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Names

[ CAS No. ]:
38185-19-2

[ Name ]:
4-(methylthio)benzyl bromide 97

[Synonym ]:
(4-(bromomethyl)phenyl)(methyl)sulfane
Benzene,1-(bromomethyl)-4-(methylthio)
1-(bromomethyl)-4-(methylthio)benzene
4-(bromomethyl)phenyl methyl sulfide
MFCD05865196
p-methylthiobenzyl bromide
4-(Methylthio)benzyl bromide
1-bromo-methyl-4-methylsulfanylbenzene
<4-(methylthio)phenyl>methyl bromide

Chemical & Physical Properties

[ Density]:
1.44g/cm3

[ Boiling Point ]:
274.5ºC at 760 mmHg

[ Melting Point ]:
43-47ºC(lit.)

[ Molecular Formula ]:
C8H9BrS

[ Molecular Weight ]:
217.12600

[ Flash Point ]:
>230 °F

[ Exact Mass ]:
215.96100

[ PSA ]:
25.30000

[ LogP ]:
3.30340

[ Index of Refraction ]:
1.606

Safety Information

[ Symbol ]:

GHS05, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H314-H317

[ Precautionary Statements ]:
P280-P301 + P310-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C

[ Risk Phrases ]:
34-43

[ Safety Phrases ]:
26-36/37/39-45

[ RIDADR ]:
UN 2923 8/PG 2

[ WGK Germany ]:
3

[ HS Code ]:
2930909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 4-(methylthio)phenylmethanol
  • Tetrabromomethane
  • 4-Methylthio benzoic acid
  • METHYL 4-(METHYLTHIO)BENZOATE

DownStream

  • 4-(methylthio)phenylmethanol
  • 1-(bromomethyl)-4-methylsulfinylbenzene
  • 4-(Methylthio)benzaldehyde
  • 4-methylthioanisole
  • bromo-tris(trimethylsilyl)silane
  • Toluene
  • methyl 3-[(4-methylsulfanylphenyl)methyl]pyridine-4-carboxylate
  • 1-(dimethoxyphosphorylmethyl)-4-methylsulfanylbenzene

Customs

[ HS Code ]: 2930909090

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Related Compounds

  • 2-((4-(METHYLTHIO)BENZYL)AMINO)ETHANOL
  • N-(4-(METHYLTHIO)BENZYL)CYCLOPROPANAMINE
  • 1-((4-(methylthio)benzyl)amino)cyclohexane-1-carbonitrile
  • 1-[4-(METHYLTHIO)BENZYL]PIPERAZINE
  • 2-methyl-2-(methyl(4-(methylthio)benzyl)amino)propanenitrile
  • 4-(chloromethyl)phenyl methyl sulfide
  • N-(5-methylisoxazol-3-yl)-2-(3-(1-(methylsulfonyl)piperidin-4-yl)-5-oxo-4-(thiophen-2-yl)-4,5-dihydro-1H-1,2,4-triazol-1-yl)acetamide
  • N-[4-(1H-imidazol-1-yl)phenyl]-4-{[4-(1H-imidazol-1-yl)phenyl]sulfamoyl}-1H-pyrrole-2-carboxamide
  • N-(2,5-difluorophenyl)-2-(3-(1-(methylsulfonyl)piperidin-4-yl)-5-oxo-4-(thiophen-2-yl)-4,5-dihydro-1H-1,2,4-triazol-1-yl)acetamide
  • benzyl 2-(3-(1-(methylsulfonyl)piperidin-4-yl)-5-oxo-4-(thiophen-2-yl)-4,5-dihydro-1H-1,2,4-triazol-1-yl)acetate
  • 1-[6-(4-chlorophenyl)pyridazin-3-yl]-N-cycloheptylpiperidine-4-carboxamide
  • N-(benzo[d][1,3]dioxol-5-yl)-2-(4-methyl-3-(1-(methylsulfonyl)piperidin-4-yl)-5-oxo-4,5-dihydro-1H-1,2,4-triazol-1-yl)acetamide
  • 2-(4-methyl-3-(1-(methylsulfonyl)piperidin-4-yl)-5-oxo-4,5-dihydro-1H-1,2,4-triazol-1-yl)-N-(3-(trifluoromethyl)phenyl)acetamide
  • 2-phenyl-N-{[6-(pyrrolidin-1-yl)pyridin-3-yl]methyl}ethene-1-sulfonamide
  • N-cyclopropyl-2-phenyl-N-{[4-(trifluoromethyl)phenyl]methyl}ethene-1-sulfonamide
  • 4-methyl-3-(1-(methylsulfonyl)piperidin-4-yl)-1-(2-morpholino-2-oxoethyl)-1H-1,2,4-triazol-5(4H)-one
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