2,6-Di-tert-butyl-4-methylpyridine

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Names

[ CAS No. ]:
38222-83-2

[ Name ]:
2,6-Di-tert-butyl-4-methylpyridine

[Synonym ]:
2,6-di-tert-Bu-4-Me-pyridine
2,6-di-t-Bu-4-Me-pyridine
2,6-DITERT-BTUYL-4-METHYLPYRIDINE
2,6-di-tert-butyl-4-methyl-pyridine
2,6-Bis(tert-butyl)-4-methylpyridine
4-methyl-2,6-di-t-butylpyridine
EINECS 253-834-4
2,6-di-t-butyl-4-methyl-pyridine
Pyridine, 2,6-bis(1,1-dimethylethyl)-4-methyl-
DTBMP
4-Methyl-2,6-bis(2-methyl-2-propanyl)pyridine
4-Methyl-2,6-di-tert-butylpyridine
2,6-Di-tert-butyl-4-methylpyridin
MFCD00006305
2,6-di-t-Butyl-4-methylpyridine
2,6-Di-tert-butyl-4-methylpyridine
2,6-Bis(1,1-dimethylethyl)-4-methylpyridine
Dibutylmethylpyridine

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
233.0±0.0 °C at 760 mmHg

[ Melting Point ]:
33-36 °C(lit.)

[ Molecular Formula ]:
C14H23N

[ Molecular Weight ]:
205.34

[ Flash Point ]:
83.9±0.0 °C

[ Exact Mass ]:
205.183044

[ PSA ]:
12.89000

[ LogP ]:
4.56

[ Vapour Pressure ]:
0.1±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.480

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2942000000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • TRIMETHYLACETONITRILE
  • Li2(TMM)(TMEDA)2
  • Pivaloyl chloride
  • tert-Amyl Alcohol
  • TRIMETHYLACETIC ANHYDRIDE

DownStream

  • Acetamide, 2,2,2-trifluoro-N-(2-iodophenyl)-
  • Methanol
  • dimethyl ether
  • 2,6-di-tert-butyl-4-methylpyridinium tetrafluoroborate
  • Triphenylbismuth
  • 2-Methoxy Propane
  • Benzyl methyl ether
  • Ethyl methyl ether
  • (2,2-difluoro-2-pyridin-2-ylethyl) trifluoromethanesulfonate
  • 4-(Bromomethyl)-2,6-di-tert-butylpyridine

Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Cyclization reactions of homopropargyl azide derivatives catalyzed by PtCl4 in ethanol solution: synthesis of functionalized pyrrole derivatives.

Org. Lett. 8(23) , 5349-52, (2006)

[Structure: see text] PtCl4-catalyzed cyclization reactions of homopropargyl azide derivatives to pyrrole rings were investigated. Using ethanol as solvent with 2,6-di-tert-butyl-4-methylpyridine as t...

GaCl(3)-catalyzed ortho-ethynylation of phenols.

J. Am. Chem. Soc. 124(29) , 8528-9, (2002)

Phenols are ethynylated at the ortho position with silylated chloroethyne in the presence of a catalytic amount of GaCl3 and lithium phenoxide. The lithium salt is essential for the catalysis, and add...

2-Methoxybenzoyl phosphate: a new substrate for continuous fluorimetric and spectrophotometric acyl phosphatase assays.

J. Org. Chem. 65(3) , 801-5, (2000)

A new aromatic acyl phosphate, 2-methoxybenzoyl phosphate, has been synthesized. The compound shows an intrinsic fluorescence; it displays an intense emission band at 390 nm upon excitation in the nea...


More Articles

Related Compounds

  • 2,6-Di-tert-butyl-4--4-methyl-4H-pyran
  • 2,6-Di-tert-butyl-4-cyclohexylperoxy-4-methyl-cyclohexa-2,5-dienone
  • 2,6-di-tert-butyl-4-hydroperoxy-4-methyl-2,5-cyclohexadienone
  • 2,6-Di-tert-butyl-4-nonylphenol
  • 2,6-Di-tert-butyl-4-phenyl-1-p-tolyl-cyclohexa-2,5-diene-1,4-diol
  • 2,6-Di-tert-butyl-4-diphenylmethyl-phenyloxyl
  • N-(2-(3-(furan-2-yl)-6-oxopyridazin-1(6H)-yl)ethyl)-3-(pyrazin-2-yl)-1,2,4-oxadiazole-5-carboxamide
  • N-(2,4-difluorobenzyl)-3-(pyrazin-2-yl)-1,2,4-oxadiazole-5-carboxamide
  • N-benzyl-N-isopropyl-2-(pyrazin-2-yl)thiazole-4-carboxamide
  • 2-Piperidinecarboxylic acid, 1-(2-bromo-4-nitrophenyl)-, ethyl ester
  • 4-hydroxy-N'-[4-(5-methylthiophen-2-yl)-4-oxobutanoyl]-1-phenyl-1H-pyrazole-3-carbohydrazide
  • (4-Phenylpiperazin-1-yl)(2-(pyrazin-2-yl)thiazol-4-yl)methanone
  • N-(2,3-difluorophenyl)-5-methylpyrazine-2-carboxamide
  • 5-(Benzyloxy)-2-methyl-1,3-benzothiazol-6-amine
  • N-phenethyl-2-(pyrazin-2-yl)thiazole-4-carboxamide
  • N-(3-phenylpropyl)-2-(pyrazin-2-yl)thiazole-4-carboxamide